Cover Pictures and Inside Front Covers
Cover Pictures and Inside Front Covers

 

  • 2024

    485) F. Schäfer, L. Lückemeier, F. Glorius,
    Improving reproducibility through condition-based, sensitivity assessments: application, advancement, and prospect,
    Chem. Sci. 2024, 15, 14548-14555. DOI

    484) F.-P. Wu, M. Lenz, A. Suresh,§ A. R. Gogoi,§ J. L. Tyler, C. G. Daniliuc, O. Gutierrez,* F. Glorius*,
    Nitrogen-to-functionalized carbon atom transmutation of pyridine,
    Chem. Sci. 2024, 15, 15205-15211. DOI
    § These authors contributed equally.

    483) F.-P. Wu, J. L. Tyler, C. G. Daniliuc, F. Glorius,
    Atomic Carbon Equivalent: Design and Application to Diversity- Generating Skeletal Editing from Indoles to 3‑Functionalized Quinolines,
    ACS Catal. 2024, 14, 13343-13351. DOI

    482) S. P. Schmid,§ L. Schlosser,§ F. Glorius,* K. Jorner,*
    Catalysing (organo-) catalysis: Trends in the application of machine learning to enantioselective organocatalysis,
    Beilstein J. Org. Chem. 2024, 20, 2280-2304. DOI
    § These authors contributed equally.

    481) J. Gemen,§ B. Stövesand,§ F. Glorius,* B. J. Ravoo,*
    Surface Tension Manipulation with Visible Light through Sensitized Disequilibration of Photoswitchable Amphiphiles,
    Angew. Chem. Int. Ed. 2024, 63,
    e202413209, Accepted Article. DOI
    § These authors contributed equally.

    480) C. Schultz,§ T. Wegner,§ C. Heusel, Tim Gallagher, Y. Zheng, M. Werner, S. V. Wegner, T. Meyer-Zedler, O. Werz, M. Schmitt, J. Popp,* F. Glorius,*
    Alkyne-tagged imidazolium-based membrane cholesterol analogs for Raman imaging applications,
    Chem. Sci. 2024, 15, 14323-14335. DOI
    § These authors contributed equally.

    479) F. Zhang, H. Sekhar Sasmal,§ D. Rana,§ F. Glorius,
    Switchable and Chemoselective Arene Hydrogenation for Efficient Late Stage Applications,
    J. Am. Chem. Soc. 2024, 146, 18682-18688. DOI
    § These authors contributed equally.

    478) J. L. Tyler,§ F. Schäfer,§ H. Shao, C. Stein, A. Wong, C. G. Daniliuc, K. N. Houk*, F. Glorius,*
    Bicyclo[1.1.0]butyl Radical Cations: Synthesis and Application to [2π + 2σ] Cycloaddition Reactions,
    J. Am. Chem. Soc. 2024
    146, 16237-16247.  DOI
    § These authors contributed equally.

     

    477) F. Landwehr,§ M. Das,§ S. Tosoni,§,* J. J. Navarro, A. Das, M. Koy, M. Heyde,* G. Pacchioni, F. Glorius,* B. Roldan Cuenya,
    N-Heterocyclic Olefins on a Metallic Surface – Adsorption, Orientation and Electronic Influence,
    Adv. Mater. Interfaces 2024, 2400378, Early View. DOI
    § These authors contributed equally.

    476) L. Schlosser, D. Rana, P. Pflüger, F. Katzenburg, F. Glorius,
    EnTdecker – A machine learning-based platform for guiding substrate discovery in energy transfer catalysis,
    J. Am. Chem. Soc. 2024, 146, 13266-13275. DOI

    475) D.-H. Liu,§ P. M. Pflüger,§ A. Outlaw,§ L. Lückemeier, F. Zhang, C. Regan, H. Rashidi Nodeh, T. Cernak,* J. Ma,* F. Glorius,*
    Late-Stage Saturation of Drug Molecules,
    J. Am. Chem. Soc. 2024, 146, 11866-11875. DOI
    § These authors contributed equally.
    Highlighted by Synfacts 2024, 20, 0752. DOI

    Highlighted by Shanghai Jiao Tong University (SJTU; chinese);
    Highlighted in Chemistry World (“'Late-state saturation' could boost drug discovery”).

    474) F. Strieth-Kalthoff,§ S. Szymkuc,§ K. Molga,§ A. Aspuru-Guzik, F. Glorius,* B. A. Grzybowski,*
    Artificial Intelligence for Retrosynthetic Planning Needs Both Data and Expert Knowledge,
    J. Am. Chem. Soc. 2024, 146, 11005-11017. DOI
    § These authors contributed equally.

    Highlighted by ChemistryViews;
    Highlighted by Derek Lowe (IN THE PIPELINE);
    highlighted by press release of Chemistry World (“Are we rushing ahead with AI in the lab?”).

    473) D. Rana, P. M. Pflüger, N. P. Hölter, G. Tan, F. Glorius,
    Standardizing Substrate Selection: A Strategy toward Unbiased Evaluation of Reaction Generality,
    ACS Cent. Sci. 2024, 10, 899-906. DOI

    Highlighted by press release of Uni MS (english),
    highlighted by press release of Uni MS (german);
    highlighted by press releases of Chemeurope.com, ScienceDaily, Eurekalert, Chemie.de (german), Analytik.de (german), Analytik.news (german), Chemiextra (german), Chemeurope (french), Quimica.es (spanish).
    Highlighted in C&E News (“Free tool uses machine learning to pick better molecules for testing new reactions”).

    472) M. L. Schrader,§ F. R. Schäfer,§ F. Schäfers,§ F. Glorius,
    Bridging the information gap in organic chemical reactions,
    Nat. Chem. 2024, 16, 491-498. DOI
    § These authors contributed equally.
    SharedIt link

    471) R. Laskar,§ S. Dutta,§ J. C. Spies, P. Mukherjee, A. Renteria-Gomez, R. E. Thielemann, C. G. Daniliuc, O. Gutierrez,* F. Glorius,*
    γ-Amino Alcohols via Energy Transfer Enabled Brook Rearrangement,
    J. Am. Chem. Soc. 2024, 146, 10899-10907. DOI
    § These authors contributed equally.

    470) Y. Liang, R. Nematswerani, C. G. Daniliuc, F. Glorius,
    Silver-Enabled Cycloaddition of Bicyclobutanes with Isocyanides for the Synthesis of Polysubstituted 3-Azabicyclo[3.1.1]heptanes,
    Angew. Chem. Int. Ed. 2024, 63, e202402730; Angew. Chem. 2024, 136, e202402730. DOI

    Dedicated to Professor Helmut Schwarz on the occasion of his 80th birthday

    469) P. M. Pflüger,§ M. Kühnemund,§ F. Katzenburg,§ H. Kuchen, F. Glorius,
    An evolutionary algorithm for interpretable molecular representations,
    Chem 2024, 10, 1391-1405. DOI
    § These authors contributed equally; selected for cover image.

    Highlighted by press release of Uni MS (english),
    highlighted by press release of Uni MS (german);
    highlighted by press releases of  Computational Chemistry Highlights, chemeurope.com, idw-online.de,  Research-in-Germany.org, Phys.org, msn.com, Chemie.de (german), Analytik.de (german)Quimica.es (spanish).

    468) S. Dutta, Y.-L. Lu,§ J. E. Erchinger,§ H. Shao, E. Studer, F. Schäfer, H. Wang, D. Rana, C. G. Daniliuc, K. N. Houk,* F. Glorius,*
    Double Strain-Release [2π+2σ]-Photocycloaddition,
    J. Am. Chem. Soc. 2024, 146, 5232-5241. DOI
    § These authors contributed equally.

      

    467) J. Ren,*§ M. Das,§ H. Osthues, M. Nyenhuis, B. Schulze Lammers, E. Kolodzeiski, H. Mönig, S. Amirjalayer,* H. Fuchs,* N. L. Doltsinis,* F. Glorius,*
    The electron-rich and nucleophilic N-heterocyclic imines on metal surfaces: binding modes and interfacial charge transfer,
    J. Am. Chem. Soc. 2024, 146, 7288-7294. DOI
    § These authors contributed equally.

    466) L. Lückemeier,§ T. De Vos,§ L. Schlichter, C. Gutheil, C. G. Daniliuc, F. Glorius,
    Chemoselective Heterogeneous Hydrogenation of Sulphur Containing Quinolines Under Mild Conditions,
    J. Am. Chem. Soc. 2024, 146, 5864-5871. DOI
    § These authors contributed equally.

    Highlighted by Synfacts 2024, 20, 0622. DOI

      

    465) C. Gutheil, G. Ross, S. Amirjalayer, B. Mo, A. H. Schäfer, N. L. Doltsinis, B. Braunschweig,* F. Glorius,*
    Tailored Monolayers of N-Heterocyclic Carbenes by Kinetic Control,
    ACS Nano 2024, 18, 3043-3052. DOI

     

    464) S. Dutta,§ D. Lee,§ K. Ozols,§ C. Daniliuc, R. Shintani, F. Glorius,
    Photoredox-Enabled Dearomative [2π+2σ] Cycloaddition of Phenols,
    J. Am. Chem. Soc. 2024, 146, 2789-2797. DOI

    § These authors contributed equally.

    Highlighted in Synfacts 2024, 20, 0409. DOI

     

    463) F.-P. Wu, C. C. Chintawar, R. Lalisse, P. Mukherjee, S. Dutta, J. Tyler, C. G. Daniliuc, O. Gutierrez,* F. Glorius,*
    Ring expansion of indene by photoredox-enabled functionalized carbon-atom insertion,
    Nat. Catal. 2024, 7, 242-251. DOI

    Highlighted by press release of Uni MS (english),
    highlighted by press release of Uni MS (german);
    highlighted by press releases of  Advanced_Science_News,
    Phys.org, Industr.com, Chemeurope.com, Vervetimes.com, Sciencedaily.com, Myscience.org, TheDailyScience, Bnn.breaking.com,
    CHEManager (german), Innovations-Report.de (german), Chemie.de (german), Laborpraxis.vogel.de (german), Analytik.news (german), Process.vogel.de (german), Chemeurope.com (french), Quimica.es (spanish)

     

    462) S. Dutta, J. E. Erchinger, F. Strieth-Kalthoff, R. Kleinmans, F. Glorius,
    Energy transfer photocatalysis: exciting modes of reactivity,
    Chem. Soc. Rev. 2024, 53, 1068-1089. DOI

  • 2023

    461) J. Goretzko, I. Pauels, N. Heitzig, K. Thomas, M. Kardell, J. Naß, E. Kleinhans Krogsaeter, S. Schloer, B. Spix, A. L. L. Matos, C. Leser, T. Wegner, F. Glorius, F. Bracher, V. Gerke, J. Rossaint, C. Grimm, U. Rescher,*
    P-selectin-dependent leukocyte adhesion is governed by endolysosomal two-pore channel 2,
    Cell Rep. 2023, 42, 113501. DOI

    460) M. Das,§ C. Hogan,§ R. Zielinski, M. Kubicki, M. Koy, C. Kosbab, S. Brozzesi, A. Das, M. T. Nehring, V. Balfanz, J. Brühne, M. Dähne, M. Franz,* N. Esser,* F. Glorius,*
    N-Heterocyclic Olefins on a Silicon Surface,
    Angew. Chem. Int. Ed. 2023, 62, e202314663; Angew. Chem. 2023, 135, e202314663. DOI
    § These authors contributed equally.

    459) H. Wang,§ J. E. Erchinger,§ M. Lenz,§ S. Dutta, C. G. Daniliuc, F. Glorius,
    syn-Selective Difunctionalization of Bicyclobutanes Enabled by Photoredox-Mediated C–S σ-Bond Scission,
    J. Am. Chem. Soc. 2023, 145, 23771-23780. DOI
    § These authors contributed equally

    Highlighted in Synfacts 2024, 20, 0078. DOI 

    458) T. Wegner,§ A. Dombovski,§ K. Gesing, A. Köhrer, M. Elinkmann, U. Karst, F. Glorius* J. Jose,*
    Combining lipid-mimicking-enabled transition metal and enzyme-mediated catalysis at the cell surface of E. coli,
    Chem. Sci. 2023, 14, 11896-11906. DOI
    § These authors contributed equally

    457) F. Paulus, C. Stein, C. Heusel, T. J. Stoffels, C. G. Daniliuc, F. Glorius,
    Three-Component Photochemical 1,2,5-Trifunctionalizations of Alkenes towards Densely Functionalized Lynchpins,
    J. Am. Chem. Soc. 2023, 145, 23814-23823. DOI

    456) F. Buß, M. Das, D. Janssen-Müller, A. Sietmann, A. Das, L. F. B. Wilm, M. Freitag, M. Seidl, F. Glorius* F. Dielmann*,
    Photoswitchable Electron-rich Phosphines: Using Light to Modulate the Electron-Donating Ability of Phosphines,
    Chem. Commun. 2023, 59, 12019-12022. DOI

    Dedicated to Holger Braunschweig on the occasion of his 60th birthday.

    455) P. Bellotti,* F. Glorius,*
    Strain-Release Photocatalysis,
    J. Am. Chem. Soc. 2023, 145, 20716-20732. DOI

    454) J. Ren, M. Koy, H. Osthues, B. Schulze Lammers, C. Gutheil, M. Nyenhuis, Q. Zheng, Y. Xiao, L. Huang, A. Nalop, Q. Dai, H.-J. Gao,* H. Mönig,* N. L. Doltsinis,* H. Fuchs,* F. Glorius,*
    On-surface synthesis of ballbot-type N-heterocyclic carbene polymers,
    Nat. Chem. 2023, 15, 1737-1744. DOI

    Highlighted by press release of Uni MS (english),
    highlighted by press release of Uni MS (deutsch);
    highlighted by press releases of Research-in-Germany, EurekAlert, Behind the paper (by Prof. Jindong Ren), Phys.org, myScience.de, chemEurope.com, Headtopics.com, Chemie.de (german), Laborpraxis.vogel.de (german), Jot-oberflaeche.de (german), Pro-physik.de (german), Chinese Academy of Science (chinese), Quimica.es (spanish), Chemeurope.com/fr (french).

    453) L. Quach, E. Adhitama,§ V. Göldner,§ A. Das, F. Demelash, M. Winter,* U. Karst,* T. Placke,* F. Glorius,*
    Molecular Design of Film-Forming Additives for Lithium-Ion Batteries – Impact of Molecular Substrate Parameters on Cell Performance,
    ACS Appl. Energy Mater. 2023, 6, 9837-9850. DOI
    § These authors contributed equally

    452) M. Das, M. Kohlstädt,* M. Enders, S. Burger, H. S. Sasmal, B. Zimmermann, A. Schäfer, B. J. Tyler, H. F. Arlinghaus, I. Krossing, U. Würfel, F. Glorius,*
    Surface Modification of ITO with N-Heterocyclic Carbene Precursors Results in Electron Selective Contacts in Organic Photovoltaic Devices,
    Chem. Eur. J. 2023, 29, e202301482. DOI

    451) V. Göldner, L. Quach, E. Adhitama, A. Behrens, L. Junk, M. Winter, T. Placke, F. Glorius, U. Karst,*
    Laser desorption/ionization-mass spectrometry for the analysis of interphases in lithium ion batteries,
    iScience 2023, 26, 107517. DOI

    450) F. Bosse, C. Gutheil, D. T. Nguyen, M. Freitag, M. Das, B. J. Tyler, T. Adolphs, A. H. Schäfer, H. F. Arlinghaus, F. Glorius,* B. J. Ravoo,*
    Selective Removal of Gold: N-Heterocyclic Carbenes as Positive Etch Resists on Planar Gold Surfaces,
    ACS Appl. Mater. Interfaces 2023, 15, 36831-36838. DOI

    449) H. Wang, H. Shao,§ A. Das,§ S. Dutta, H. T. Chan, C. Daniliuc, K. N. Houk,* F. Glorius,*
    Dearomative ring expansion of thiophenes by bicyclobutane insertion,
    Science 2023, 381, 75-81. DOI
    § These authors contributed equally

    Free-access electronic reprint

    Highlighted by press release of WWU (german),
    highlighted by press release of WWU (english),
    highlighted by press releases of Chemistry World, ChemEurope.com, MyScience.org, Technologynetworks.com, Enenews.co.kr, TheDailyScience.com, Newsbeezer.com, Phys.org, Chemie.de (german), Idw-online.de (german), Analytik.News (german), Laborpraxis.Vogel.de (german), Industr.com (german), Quimica.es (spanish), ChemEurope.com (french).

    448) L. Lückemeier,§ M. Pierau,§ F. Glorius,
    Asymmetric arene hydrogenation: towards sustainability and application,
    Chem. Soc. Rev. 2023, 52, 4996-5012. DOI
    § These authors contributed equally

    Highlighted as Highlights from the literature by Org. Process Res. Dev. 2023, 27, 1535-1545. DOI

    447) F. Zhang, H. S. Sasmal, C. G. Daniliuc, F. Glorius,
    Ru-NHC-Catalyzed Asymmetric, Complete Hydrogenation of Indoles and Benzofurans: One Catalyst with Dual Function,
    J. Am. Chem. Soc. 2023, 145, 15695-15701. DOI

    Highlighted by ACS as editor’s choice.
    Highlighted as Highlights from the literature by Org. Process Res. Dev. 2023, 27,  1827-1840. DOI

    446) Y. Liang, F. Paulus, C. G. Daniliuc, F. Glorius,
    Catalytic Formal [2π+2σ] Cycloaddition of Aldehydes with Bicyclobutanes: Expedient Access to Polysubstituted 2-Oxabicyclo[2.1.1]hexanes,
    Angew. Chem. Int. Ed. 2023, 62, e202305043; Angew. Chem. 2023, 135, e202305043. DOI

    Dedicated to Professor Keiji Maruoka on the occasion of his 70th birthday.

    445)  J. L. Tyler,§ F. Katzenburg,§ F. Glorius,
    A focus on sustainable method development for greener synthesis,
    Chem. Sci. 2023, 14, 7408-7410. DOI
    § These authors contributed equally

    444) H. Wang, Z. Liu, A. Das, P. Bellotti, S. Megow, F. Temps,* X. Qi,* F. Glorius,*
    Radical thioesterification via nickel-catalyzed sensitized electron transfer,
    Nature Synth. 2023, 2, 1116-1126. DOI

    443) T. Wegner,§ A. L. L. Matos,§ K. Porte,§ K. Mehring,§ M. Pierau,§ H. Horstmeier, V. Gerke,* F. Glorius,*
    A bifunctional imidazolium-based cholesterol analog for the tracking of cellular cholesterol distributions and cholesterol–protein interactions,
    Org. Biomol. Chem. 2023, 21, 4817-4822. DOI
    § These authors contributed equally

    442) Y. Lee,§ X. Liu,§ Y. Tong,§ J. L. Childs-Disney,§ B. M. Suresh, R. I. Benhamou, C. Yang, W. Li, M. G. Costales, H. S. Haniff, S. Sievers, D. Abegg, T. Wegner, T. O. Paulisch, E. Lekah, M. Grefe, G. Crynenf, M. Van Meter, J. L. Cleveland, A. Adibekian, F. Glorius,*, H. Waldmann,* M. D. Disney*,
    Programming inactive RNA-binding small molecules into bioactive degraders,
    Nature 2023, 618, 169-179. DOI
    § These authors contributed equally

    Highlighted by press release of WWU (german),
    highlighted by press release of WWU (english),
    highlighted by press releases of MPG.de, Myscience.de, University of Florida,
    Genengnews.com, Technologynetworks.com, Technology.org, TU Dortmund, ScienceMag.com, MedicalXpress.com, Miragenews.com, Newatlas.com, Bioengineer.org, Ruhrbarone (german), Westfalenspiegel (german), TU Dortmund (german), Agenciasinc.es (spanish), Madrimasd.org (spanish), Theobjective.com, Infosalus.com (spanish).

    441) R. Kleinmans,§ S. Dutta,§ K. Ozols, H. Shao, F. Schäfer, R. E. Thielemann, H. T. Chan, C. G. Daniliuc, K. N. Houk,* F. Glorius,*
    ortho-Selective Dearomative [2π + 2σ]-Photocycloadditions of Bicyclic Aza-Arenes,
    J. Am. Chem. Soc. 2023, 145, 12324-12332.DOI
    § These authors contributed equally

    Highlighted by Synfacts 2023, 19(08), 0775. DOI

    440) R. Zielinski, M. Das, C. Kosbab, M. T. Nehring, M. Dähne, N. Esser,* M. Franz*, F. Glorius,*
    Influence of the defect density on the ordering of an NHC monolayer on a silicon surface,
    J. Mater. Chem. C 2023, 11, 7377-7382.DOI

    439) Y. Zheng,§ T. Wegner,§ D. Di Iorio, M. Pierau, F. Glorius,* S. V. Wegner,*
    NTA-Cholesterol Analogue for the Nongenetic Liquid-Ordered Phase-Specific Functionalization of Lipid Membranes with Proteins,
    ACS Chem. Biol. 2023, 18, 1435-1443. DOI   
    § These authors contributed equally

    438) G. Tan,§ F. Paulus,§ A. Petti, M.-A. Wiethoff, A. Lauer, C. Daniliuc, F. Glorius,
    Metal-free photosensitized radical relay 1,4-carboimination across two distinct olefins,
    Chem. Sci. 2023, 14, 2447-2454.DOI
    § These authors contributed equally

    437) A. Kaithal, H. Sekhar Sasmal, S. Dutta, F. Schäfer, L. Schlichter, F. Glorius,
    cis-Selective Hydrogenation of Aryl Germanes: A Direct Approach to Access Saturated Carbo- and Heterocyclic Germanes,
    J. Am. Chem. Soc. 2023, 145, 4109-4118.DOI

    436) M. Dellin, I. Rohrbeck, P. Asrani, J. A. Schreiber, N. Ritter, F. Glorius, B. Wünsch, T. Budde, L. Temme, T. Strünker, B. Stallmeyer, F. Tüttelmann, S. G. Meuth, M. Spehr, J. Matschke, A. Steinbicker, C. Gatsogiannis, R. Stoll, N. Strutz-Seebohm, G. Seebohm,
    The second PI(3,5)P2 binding site in the S0 helix of KCNQ1 stabilizes PIP2-at the primary PI1 site with potential consequences on intermediate-to-open state transition,
    Biol. Chem. 2023, 404, 241-254.DOI

    435) P. Bellotti,§ H.-M. Huang*,§ T. Faber, F. Glorius*,
    Photocatalytic Late-Stage C–H Functionalization,
    Chem. Rev. 2023, 123, 4237-4352.DOI
    § These authors contributed equally

    434) J. E. Erchinger, R. Hoogesteger,§ R. Laskar,§ S. Dutta, C. Hümpel, D. Rana, C. G. Daniliuc, F. Glorius,
    EnT-Mediated N–S Bond Homolysis of a Bifunctional Reagent Leading to Aliphatic Sulfonyl Fluorides,
    J. Am. Chem. Soc. 2023, 145, 2364-2374. DOI
    § These authors contributed equally

    433) G. Tan, F. Glorius,
    Stereochemical Editing,
    Angew. Chem. Int. Ed. 2023, 62 (11), e202217840; Angew. Chem. 2023, 135 (11), e202217840. DOI

    432) S. Ikemoto, S. Muratsugu,* T. Koitaya, Y. Tsuj, M. Das, K. Yoshizawa, F. Glorius, M. Tada,*
    Coordination-Induced Trigger for Activity: N‑Heterocyclic Carbene-Decorated Ceria Catalysts Incorporating Cr and Rh with Activity Induction by Surface Adsorption Site Control,
    J. Am. Chem. Soc. 2023, 145, 1497-1504. DOI

  • 2022

    431) G. Tan, M. Das, R. Kleinmans, F. Katzenburg, C. Daniliuc, F. Glorius,
    Energy Transfer-Enabled Unsymmetrical Diamination Using Bifunctional Nitrogen-Radical Precursors,
    Nat. Catal. 2022, 5, 1120-1130. DOI

    Highlighted by press release of WWU Münster (english),
    highlighted by press release of WWU Münster (german),
    highlighted by press releases of Phys.org, Idw-online.de
    VerveTimes.com, radioQ.de (german), Crumpe.com (french), Innovations-Report.com, ChemEurope.com, ChemEurope.com (french), Citizenside.fr (french), Quimica.es (spanish), Process.Vogel.de (german), Labmanager.com, Scienmag.com.

    430) G. Tan, F. Paulus, Á. Rentería-Gómez,§ R. F. Lalisse,§ C. G. Daniliuc, O. Gutierrez*, F. Glorius*,
    Highly Selective Radical Relay 1,4-Oxyimination of Two Electronically Differentiated Olefins,
    J. Am. Chem. Soc. 2022, 144, 21664-21673. DOI
    § These authors contributed equally

    Highlighted in this VIDEO “Five Important Papers in Organic Synthesis (November 2022)”;
    Highlighted in Synfacts 2023, 19, 0292, DOI;
    Highlighted by press release of  nanoer.net.

    429) Y. Liang, R. Kleinmans, C. G. Daniliuc, F. Glorius,
    Synthesis of Polysubstituted 2-Oxabicyclo[2.1.1]hexanes via Visible-Light-Induced Energy Transfer,
    J. Am. Chem. Soc. 2022, 144, 20207-20213. DOI

    Highlighted by press release of  chemrss.com.

    428) D. A. Evans , J. J. Beiger*, J. D. Burch, P. H. Fuller, F. Glorius, E. Kattnig, D. A. Thaisrivongs, W. C. Trenkle, J. M. Young, J. Zhang,
    Total Synthesis of Aflastatin A,
    J. Am. Chem. Soc. 2022, 144, 19953-19972. DOI

    Dedicated to the memory of David A. Evans (1941−2022).

    427) J. J. Navarro, M. Das, S. Tosoni*, F. Landwehr, M. Heyde*, G. Pacchioni, F. Glorius*, B. Roldan Cuenya,
    Promoted Thermal Reduction of Copper Oxide Surfaces by N-Heterocyclic Carbenes,
    J. Phys. Chem. C 2022, 126, 17528-17535. DOI

    426) S. Dutta,§ J. E. Erchinger,§ F. Schäfers, A. Das, C. G Daniliuc, F. Glorius,
    Chromium/Photoredox Dual-Catalyzed Synthesis of α-Benzylic Alcohols, Isochromanones, 1,2-Oxy Alcohols and 1,2-Thio Alcohols,
    Angew. Chem. Int. Ed. 2022, 61 (49), e202212136; Angew. Chem. 2022, 134 (49), e202212136. DOI
    § These authors contributed equally

    Dedicated to Professor Alois Fürstner on the occasion of his 60th birthday.

    425) F. Schäfers,§ S. Dutta,§ R. Kleinmans, C. Mück-Lichtenfeld, F. Glorius,
    Asymmetric Addition of Allylsilanes to Aldehydes – A Cr/Photoredox Dual Catalytic Approach Complementing the Hosomi–Sakurai Reaction,
    ACS Catal. 2022, 12, 12281-12290. DOI
    § These authors contributed equally

    Highlighted by Org. Chem. Highlights

    424) T. Wegner, R. Laskar, F. Glorius,
    Lipid mimetics: A versatile toolbox for lipid biology and beyond,
    Curr. Opin. Chem. Biol. 2022, 71, 102209. DOI

    423) R. Guo, S. Adak, P. Bellotti, X. Gao, W. W. Smith, S. N. Le, J. Ma, K. N. Houk*, F. Glorius*, S. Chen*, M. K. Brown*,
    Photochemical Dearomative Cycloadditions of Quinolines and Alkenes: Scope and Mechanism Studies,
    J. Am. Chem. Soc. 2022, 144, 17680-17691. DOI

    422) J. J. Navarro, M. Das, S. Tosoni*, F. Landwehr, J. P. Bruce, M. Heyde*, G. Pacchioni, F. Glorius*, B. Roldan Cuenya,
    Covalent Adsorption of N-Heterocyclic Carbenes on a Copper Oxide Surface,
    J. Am. Chem. Soc. 2022, 144, 16267-16271. DOI

    Highlighted in ChemistryViews

    421) T. Wegner,§ R. Elias,§ L. Roling, N. Raj, V. Gerke, M. Fridman*, F. Glorius*,
    Cationic, steroid-based imidazolium amphiphiles show tunable backbone-dependent membrane selectivity in fungi,
    ACS Infect. Dis.2022, 8, 1815-1822. DOI
    § These authors contributed equally

    420) P. Bellotti,§ T. Rogge,§ F. Paulus,§ R. Laskar, N. Rendel, J. Ma, K. N. Houk*, F. Glorius*,
    Visible-Light Photocatalyzed peri-(3 + 2) Cycloadditions of Quinolines,
    J. Am. Chem. Soc. 2022, 144, 15662-15671. DOI
    § These authors contributed equally

    419) R. J. Lewis,§ M. Koy,§ M. Macino, M. Das, J. H. Carter, D. J. Morgan, T. E. Davies, J. B. Ernst, S. J. Freakley, F. Glorius*, G. J. Hutchings*,
    N-Heterocyclic Carbene Modified Palladium Catalysts for the Direct Synthesis of Hydrogen Peroxide,
    J. Am. Chem. Soc. 2022, 144, 15431-15436. DOI
    § These authors contributed equally

    This paper is dedicated to Guy Bertrand on the occasion of his 70th birthday.

    418) M. Korff, T. O. Paulisch, F. Glorius, N. L. Doltsinis, B. Wünsch*,
    Photocatalytic Isomerization of (E)-Anethole to (Z)-Anethole,
    Molecules 2022, 27, 5342. DOI

    417) G. Tan, M. Das, H. Keum, P. Bellotti, C. Daniliuc, F. Glorius,
    Photochemical single-step synthesis of β-amino acid derivatives from alkenes and (hetero)arenes,
    Nature Chem. 2022, 14, 1174-1184. DOI
    Free SharedIt-Link

    Highlighted by press release of WWU Münster (german);
    highlighted by press release of WWU Münster (english);
    highlighted by press releases of  Phys.org, ScienceDaily.com, EurekAlert!, Idw-online.de, Idw-online.de (german), Innovations-report.de (german), Chemie.de (german), Labo.de (german), Analytik.news (german), Scinexx.de (german), Miragenews.com, Bioengineer.com, Newscontinue.com, Seniorngr.com, Newswise.com, Vervetimes.com, Mydroll.com, Flipboard.com, Technocharger.com, Newsliveflorida.com, Chemeurope.com, Quimica.es (spanish), Chemeurope.com (french), Citizenside.fr (french).

    416) P. Bellotti,§ H.-M. Huang,§ T. Faber, R. Laskar, F. Glorius,
    Catalytic Defluorinative Ketyl-Olefin Coupling by Halogen-Atom Transfer,
    Chem. Sci. 2022, 13, 7855-7862. DOI
    § These authors contributed equally

    415) T. Wagener, M. Pierau, A. Heusler, F. Glorius,
    Synthesis of Saturated N-Heterocycles via a Catalytic Hydrogenation Cascade,
    Adv. Synth. Catal. 2022, 364, 3366-3371. DOI

    This manuscript is part of a special issue dedicated to Andreas Pfaltz. For the editorial, see:
    https://onlinelibrary.wiley.com/doi/10.1002/adsc.20220097

    414) H.-M. Huang,§* P. Bellotti,§ S. Kim, X. Zhang, F. Glorius,*
    Catalytic multicomponent reaction involving a ketyl-type radical,
    Nature Synth. 2022, 1, 464-474. DOI
    Free SharedIt-Link

    § These authors contributed equally

    Highlighted by press release of WWU Münster (german);
    highlighted by press release of WWU Münster (english);
    highlighted by press releases of idwOnline (german), Wissenschaftler.de (german), Prozess.Vogel.de (german)EurekAlert!, NewsKnowledia.com, myScience.de, Face-port.com, ChemEurope.com, AnalyticalScience.wiley.com, Nouvells-du-monde.com (french)Phys.org, Fr.postsus.com (french), Jaituss.com, Evanstips.com, Newsbeezer.com, Innovations-Report.de (german), Analytik.news (german).
    Highlighted by Research Briefing by Nature Synthesis.

    413)  J. Ma,§ S. Chen,§ P. Bellotti,§ T. Wagener, C. Daniliuc, K. N. Houk,* F. Glorius,*
    Facile access to fused 2D/3D rings via intermolecular cascade dearomative [2+2] cycloaddition/rearrangement reactions of quinolines with alkenes,
    Nature Catal. 2022, 5, 405-413. DOI
    Free SharedIt-Link

     § These authors contributed equally

    Highlighted by press release of WWU Münster (german);
    highlighted by press release of WWU Münster (english);
    highlighted by press releases of
    Idw-online, EurekAlert!, Phys.org, ChemEurope.com, Azom.com, TechnologyNetworks.com, MyScience, PostUSnews, UpJobsNews, NewsBeezer.com, NewsFounded.com, Trueviralnews.com, 123HindiNews.com, Chemie.de (german), Krebs-Nachrichten (german), ChemEurope.com/fr (french), Quimica.es (spanish), ProzessVogel.de (german), Deporticos.co.cr (spanish).  

    412) A. Kaithal, T. Wagener, P. Bellotti, C. G. Daniliuc, L. Schlichter, F. Glorius,
    Access to Unexplored 3D Chemical Space: cis-Selective AreneHydrogenation for the Synthesis of Saturated Cyclic Boronic Acids,
    Angew. Chem. Int. Ed. 2022, 61 (32), e202206687; Angew. Chem. 2022, 134 (32), e202206687.  DOI

    Dedicated to Prof. David Milstein on the occasion of his 75th birthday

    411) Z. Wang, M. Das, C. Gutheil, H. Osthues, F. Strieth-Kalthoff, A. Timmer, N. L. Doltsinis,* W. Wang,* L. Chi,* F. Glorius,*
    Surface Modification with a Fluorinated N-Heterocyclic Carbene on Au: Effect on Contact Resistance in Organic Field Effect Transistors,
    J. Mater. Chem. C 2022, 10, 8589-8595. DOI

     

    410) R. Kleinmans,§ T. Pinkert,§ S. Dutta, T. O. Paulisch, H. Keum, C. G. Daniliuc, F. Glorius,
    Intermolecular [2π+2σ]-photocycloaddition enabled by triplet energy transfer,
    Nature 2022, 605, 477-482. DOI

    § These authors contributed equally

    Highlighted by press release of WWU Münster (german);
    highlighted by press release of WWU Münster (english);
    highlighted by press releases of myscience.org, phys.org, azom.com, newsbreak.com, trueviralnews.com, LaboratoryEquipment, ChemEurope, The Galaxa Positor News (French), News.Sciencenet.cn, Idw online (german), Analytik.News (german).

     

    409) F. Strieth-Kalthoff,§ F. Sandfort,§ M. Kühnemund, F. R. Schäfer, H. Kuchen, F. Glorius,
    Machine Learning for Chemical Reactivity: The Importance of Failed Experiments,
    Angew. Chem. Int. Ed. 2022, 61 (29),
    e202204647; Angew. Chem. 2022, 134 (29), e202204647. DOI
    § These authors contributed equally
    Dedicated to the late Professor David A. Evans

    Highlighted by Nature Chem. 2022, 14, 973-975: Jacqueline M. Cole, The chemistry of errors;
    highlighted by Nature 2024: Rachel Brazil, "Illuminating ‘the ugly side of science’: fresh incentives for reporting negative results". DOI
    Chemistry World (Yield-predicting AI needs chemists to stop ignoring failed experiments);
    ChemistryViews (More Data in Chemistry).

    Highlighted by press releases of  Angew. Chem. Int. Ed., ChemEurope.com, EurekAlert!, DagoldNews, Idw (german), Solarify.eu (german), Chemie.de (german), Analytik.news (german), Process.Vogel (german), AusderWelt.de (german), Laborpraxis.vogel.de (german), Fr.Postsus.com (French), Quimica.es (spanish).

     

    408) J. J. Navarro, M. Das, S. Tosoni,* F. Landwehr, M. Koy, M. Heyde,* G. Pacchioni, F. Glorius,* B. Roldan Cuenya,
    Growth of N-Heterocyclic Carbene Assemblies on Cu(100) and Cu(111): from Single Molecules to Magic-Number Islands,
    Angew. Chem. Int. Ed. 2022,
    61 (30), e202202127; Angew. Chem. 2022, 134 (30), e202202127. DOI

     

    407) K. Kajiwara,§ H. Osaki,§ S. Greßies, K. Kuwata, J. H. Kim, T. Gensch, Y. Sato, F. Glorius,* S. Yamaguchi,* M. Taki,*
    A negative-solvatochromic fluorescent probe for visualizing intracellular distributions of fatty acid metabolites,
    Nature Commun. 2022, 13, 2533. DOI
    § These authors contributed equally

    406) H.-M. Huang,* P. Bellotti, F. Glorius*,
    Merging Carbonyl Addition with Photocatalysis,
    Acc. Chem. Res. 2022, 55, 1135-1147. DOI

     

    405) L. Quach, S. Dutta, P. M. Pflüger, F. Sandfort, P. Bellotti, F. Glorius,
    Visible-Light-Initiated Hydrooxygenation of Unactivated Alkenes - A Strategy for Anti-Markovnikov Hydrofunctionalization,
    ACS Catal. 2022, 12, 2499-2504. DOI

    404) B. J. Tyler,* R. Kassenböhmer, R. E. Peterson, D. T. Nguyen, M. Freitag, F. Glorius, B. J. Ravoo, H. F. Arlinghaus,
    Denoising of Mass Spectrometry Images via Inverse Maximum Signal Factors Analysis,
    Anal. Chem. 2022, 94, 2835-2843. DOI

    403) H.-M. Huang,§ P. Bellotti,§ P.-P. Chen,§ K. N. Houk,* F. Glorius,*
    Allylic C(sp3)―H Arylation of Olefins via Ternary Catalysis,
    Nature Synth. 2022, 1, 59-68. DOI
    § These authors contributed equally

    Highlighted in Nat. Synth. by Prof. Gabriel dos Passos Gomes (“Three catalysts tango with olefins”);
    Highlighted by press release of WWU Münster (english);
    Highlighted by press release of WWU Münster (german);
    Highlighted by press releases of Idw-online, EurekAlert!,
    ScienceDaily, Chemanager-online.com (German), DailyAdvent.com, Research-in-Germany.org, Azom.com, Chemie.de (German), Process.Vogel.de (German)Innovations-report.de (German), Solarify.eu (German), Citizenside.fr (French), Quimica.es (Spanish).

    402) H.-M. Huang,§ P. Bellotti,§ J. E. Erchinger, T. O. Paulisch, F. Glorius,
    Radical Carbonyl Umpolung Arylation via Dual Nickel Catalysis,
    J. Am. Chem. Soc. 2022, 144, 1899-1909. DOI
    § These authors contributed equally

    Dedicated to the late Prof. Robert H. Grubbs

    401) J. Ren,§ M. Freitag,§ Y. Gao,§ P. Bellotti, M. Das, B. Schulze Lammers, H. Mönig, Y. Zhang, C. G. Daniliuc, S. Du*, H. Fuchs*, F. Glorius,*
    Reversible Self-Assembly of an N-Heterocyclic Carbene on Metal Surfaces,
    Angew. Chem. Int. Ed. 2022, 61 (13),
    e202115104; Angew. Chem. 2022, 134 (13), e202115104. DOI
    § These authors contributed equally

    400) S. Cembellín,* I. Maisuls, C. G. Daniliuc, H. Osthues, N. L. Doltsinis, C. A. Strassert, F. Glorius,
    One-step synthesis of indolizino[3,4,5-ab]isoindoles by manganese(i)-catalyzed C–H activation: structural studies and photophysical properties,
    Org. Biomol. Chem. 2022, 20, 796-800. DOI

    399) A. Hamza,* D. Moock, C. Schlepphorst, J. Schneidewind, W. Baumann, F. Glorius*,
    Unveiling a key catalytic pocket for the ruthenium NHC-catalysed asymmetric heteroarene hydrogenation,
    Chem. Sci. 2022, 13, 985-995. DOI

    398) J.-H. Ye, P. Bellotti, C. Heusel, F. Glorius,
    Photoredox-Catalyzed Defluorinative Functionalizations of Polyfluorinated Aliphatic Amides and Esters,
    Angew. Chem. Int. Ed. 2022, 61 (9), e202115456; Angew. Chem. 2022, 134 (9), e202115456. DOI

    Highlighted in Synfacts 2022, 18, 0199. DOI

    Dedicated to Professor Qi-Lin Zhou on the occasion of his 65th birthday

    397) T. O. Paulisch, L. A. Mai, F. Strieth-Kalthoff, M. J. James, C. Henkel, D. M. Guldi,* F. Glorius,*
    Dynamic kinetic sensitization of β-dicarbonyl compounds – Access to medium-sized rings via a De Mayo-type ring expansion,
    Angew. Chem. Int. Ed. 2022, 61 (5), e202112695; Angew. Chem. 2022, 134 (5), e202112695. DOI

    Featured in Organic Chemistry Highlights

    396) L. F. B. Wilm, M. Das, D. Janssen-Müller, C. Mück-Lichtenfeld, F. Glorius,* F. Dielmann,*
    Photoswitchable Nitrogen Superbases: Using Light for Reversible Carbon Dioxide Capture,
    Angew. Chem. Int. Ed. 2022, 61 (3), e202112344; Angew. Chem. 2022, 134 (3), e202112344. DOI

    Highlighted on ChemistryView

    Dedicated to Professor Gerhard Erker on the occasion of his 75th birthday

  • 2021

    395) Y. Liang,§ F. Strieth-Kalthoff,§ P. Bellotti, F. Glorius,
    Catalytic one-carbon homologation of α-amino acids to α-amino aldehydes,
    Chem Catal. 2021, 1, 1427-1436. DOI

    Highlighted in Chem Catal. 2021, 1, 1354 by Prof. Stephen G. Newman (“Rapid access to β-amino aldehydes by a Ni/Ir dual-catalyzed homologation reaction”)

    § These authors contributed equally

    394) H. Wang, P. Bellotti, X. Zhang, T. O. Paulisch, F. Glorius,
    A base-controlled switch of SO2 reincorporation in photocatalyzed radical difunctionalization of alkenes,
    Chem 2021, 7, 3412-3424.  DOI

    393) S. Kriegler, T. O Paulisch, T. Wegner, F. Glorius,* R. Winter,*
    Bipolar Imidazolium-Based Lipid Analogues for Artificial Archaeosomes,
    Langmuir 2021, 37, 11996-12006. DOI

     

    392) T. Hu, L. Lückemeier, C. Daniliuc, F. Glorius,
    Ru-NHC-Catalyzed Asymmetric Hydrogenation of 2-Quinolones to Chiral 3,4-Dihydro-2-Quinolones,
    Angew. Chem. Int. Ed. 2021, 60, 23193-23196; Angew. Chem. 2021, 133, 23377-23381. DOI

    Dedicated to Professor Dieter Hoppe on the occasion of his 80th birthday

    391) S. Dery, P. Bellotti, T. Ben-Tzvi, M. Freitag, T. Shahar, A. Cossaro, A. Verdini, L. Floreano, F. Glorius*, E. Gross,*
    Influence of N-Substituents on the Adsorption Geometry of OH-Functionalized Chiral N-Heterocyclic Carbenes,
    Langmuir 2021, 37, 10029-10035. DOI

    390) P. Bellotti, M. Koy, M. N. Hopkinson,* F. Glorius,*
    Recent advances in the chemistry and applications of N-heterocyclic carbenes,
    Nat. Rev. Chem. 2021, 5, 711-725. DOI
    Free SharedIt-Link

    389) M. Franz, S. Chandola, M. Koy, R. Zielinski, H. Aldahhak, M. Das, M. Freitag, U. Gerstmann, D. Liebig, A. K.Hoffmann, M. Rosin, W. G. Schmidt, C. Hogan, F. Glorius,* N. Esser,* M. Dähne,*
    Controlled growth of ordered monolayers of N-heterocyclic carbenes on silicon,
    Nature Chem. 2021, 13, 828-835. DOI
    Free SharedIt-Link

    Highlighted by press release of WWU Münster (english);
    Highlighted by press release of WWU Münster (german);
    Highlighted by press releases of  idw-online, ScienceDaily.com, Phys.org, Hitech.glitz.com, Azom.com, Computational chemistry daily, PennyNews.com, Analytiknews (german), CitizenSide.com (french), Science-things.com (spanish), CNR.it (italian).

    388) A. L. L. Matos, F. Keller, T. Wegner, C. E. Cadena del Castillo, D. Grill, S. Kudruk, A. Spang, F. Glorius*, A. Heuer*, V. Gerke*,
    CHIMs are versatile cholesterol analogs mimicking and visualizing cholesterol behavior in lipid bilayers and cells,
    Commun. Biol. 2021, 4, Article number 720. DOI, OA Link (Springer Nature SharedIt)

    387) G. Tan,§ I. Maisuls,§ F. Strieth-Kalthoff, X. Zhang, C. Daniliuc, C. A. Strassert*, F. Glorius,*
    AIE-Active Difluoroboron Complexes with N,O-Bidentate Ligands: Rapid Construction by Copper-Catalyzed C−H Activation,
    Adv. Sci. 2021, 8, 202101814 (open access). DOI

    § These authors contributed equally.

    386) K. I. Burton, I. Elser, A. E. Waked, T. Wagener, R. J. Andrews, F. Glorius,* D. W. Stephan,*
    Bipyridinium and Phenanthrolinium Dications for Metal-Free Hydrodefluorination: Distinctive Carbon-Based Reactivity,
    Chem. Eur. J. 2021, 27, 11730-11737. DOI

    385) T. Pinkert, M. Das, M. L. Schrader, F. Glorius,
    The Use of Strain-Release for the Diastereoselective Construction of Quaternary Carbon Centers,
    J. Am. Chem. Soc. 2021, 143, 7648-7654. DOI

    384) G. Tan, M. Das, I. Maisuls, C. A. Strassert, Frank Glorius,
    Rhodium-Catalyzed Dealkenylative Arylation of Alkenes with Arylboronic Compounds,
    Angew. Chem. Int. Ed. 2021, 60, 15650-15655; Angew. Chem. 2021, 133, 15780-15785. DOI

    Dedicated to Prof. Christian Bruneau

    383) M. Koy, P. Bellotti, M. Das, F. Glorius,
    N-Heterocyclic carbenes as tunable ligands for catalytic metal surfaces,
    Nature Catal. 2021, 4, 352-363. DOI
    Free SharedIt link (view only)

    382) H.-M. Huang,§ P. Bellotti,§ J. Ma, T. Dalton, F. Glorius,
    Bifunctional Reagents in Organic Synthesis,
    Nature Rev. Chem. 2021, 5, 301-321. DOI
    Free SharedIt link (view only)
    § These authors contributed equally.

    381) D. Moock, T. Wagener, T. Hu, T. Gallagher, F. Glorius,
    Enantio- and Diastereoselective, Complete Hydrogenation of Benzofurans by Cascade Catalysis,
    Angew. Chem. Int. Ed. 2021, 60, 13677-13681; Angew. Chem. 2021, 133, 13791-13796. DOI

    Selected as Hot Paper by publisher.

    Dedicated to Prof. Pierre H. Dixneuf

    380) A. Heusler,§ J. Fliege,§ T. Wagener, F. Glorius,
    Substituted Dihydropyridine Synthesis by Dearomatization of Pyridines,
    Angew. Chem. Int. Ed. 2021, 60, 13793-13797; Angew. Chem. 2021, 133, 13912-13916. DOI
    § These authors contributed equally.
    Selected as Hot Paper by publisher;
    Highlighted by Organic Process Research & Development

    Dedicated to Prof. Robert H. Morris

     

    379) A. Theodoridis, G. Papamokos, M. P. Wiesenfeldt, M. Wollenburg, K. Müllen, F. Glorius,* G. Floudas*,
    Polarity Matters: Dielectric Relaxation in All-cis-Multifluorinated Cycloalkanes,
    J. Chem. Phys. B 2021, 125, 3700-3709. DOI

    378) J. Ma,§ S. Chen,§ P. Bellotti,§ R. Guo, F. Schäfer, A. Heusler, X. Zhang, C. Daniliuc, M. K. Brown,* K. N. Houk,* F. Glorius,*
    Photochemical Intermolecular Dearomative Cycloaddition of Bicyclic Azaarenes with Alkenes,
    Science 2021, 371, 1338-1345. DOI
    § These authors contributed equally.

    Perspective by Prof. Valerie Schmidt (UCSD): Getting excited about cycloadditions, Science 2021, 371, 1313;
    Highlighted
    by ChemieXtra 2021, (6), 12, LINK;
    Highlighted by press release of WWU Münster (english);
    Highlighted by press release of WWU Münster (german);
    Highlighted by Organic Chemistry Portal;
    Highlighted by press releases of ScienceMag.orgEurekalert!, Jioforme.com, Teknodate.com, Technologynetworks.com, Scienceboard.net, Scitechdaily.com, C&EN,
    LosAngelesDailyNewswire.com, Phys.org, Sciencesprings.wordpress.com, Ministere des Finances Laos,
    Idw-online (german), Process.Vogel.de (german), Chemie.de (german), Chemiepharma-innovation-ch (german), News-medical.net (Spanish),
    Technoguide.fr (French), Finance.sina.com (Chinese), Paper.science.net (Chinese).

    377) J.-H. Ye, P. Bellotti, T. O. Paulisch, C. G. Daniliuc, F. Glorius,
    Visible-Light-Induced Cycloaddition of α-Ketoacylsilanes with Imines: Facile Access to β-Lactams,
    Angew. Chem. Int. Ed. 2021, 60, 13671-13676; Angew. Chem. 2021, 133, 13785-13790. DOI

    Selected as Hot Paper by publisher

    Dedicated to Professor Peter Kündig on the occasion of his 75th birthday.

    376) M. P. Wiesenfeldt,§ D. Moock,§ D. Paul,§ F. Glorius,
    Enantioselective Hydrogenation of Annulated Arenes: Controlled Formation of Multiple Stereocenters in Adjacent Rings,
    Chem. Sci. 2021, 12, 5611-5615. DOI
    § These authors contributed equally.

    375) T. Dalton,§ S. Greßies,§ M. Das, M. Niehues,§§ M. L. Schrader,§§ C. Gutheil,§§ B. J. Ravoo, F. Glorius,
    Silver-Catalysed Hydroarylation of Highly Substituted Styrenes,
    Angew. Chem. Int. Ed. 2021, 60, 8537-8541; Angew. Chem. 2021, 133, 8616-8623. DOI
    §,§§ These authors contributed equally.

    Selected as Hot Paper by publisher.

    In memoriam: Dr. Steven Cooper (1971-2019)

    374) T. Wagener,§ L. Lückemeier,§ C. G. Daniliuc, F. Glorius,
    Interrupted Pyridine Hydrogenation: Asymmetric Synthesis of δ-Lactams,
    Angew. Chem. Int. Ed. 2021, 60, 6425-6429; Angew. Chem. 2021, 133, 6496-6500. DOI
    § These authors contributed equally.

    Dedicated to Professor David A. Evans on the occasion of his 80th birthday.

    Highlighted by X-Mol, Org. Process Res. Dev.

    373) R. Kleinmans, L. E. Will, J. L. Schwarz, F. Glorius,
    Photoredox-enabled 1,2-dialkylation of α-substituted acrylates via Ireland–Claisen rearrangement,
    Chem. Sci. 2021, 12, 2816-2822. DOI
    Selected as Hot Paper.
    Highlighted by Synfacts 2021, 17, 0305. DOI

    372) J.-P. Schmiegel, R. Nölle, J. Henschel, L. Quach, S. Nowak, M. Winter, F. Glorius,* T. Placke,*
    Case study of N-carboxyanhydrides in silicon-based lithium ion cells as a guideline for systematic electrolyte additive research,
    Cell Rep. Phys Sci. 2021, 2, Article 100327. DOI

    371) S. Mondal, T. Pinkert, C. G. Daniliuc, F. Glorius,
    Regioselective and Redox-Neutral Cp*IrIII-Catalyzed Allylic C–H Alkynylation,
    Angew. Chem. Int. Ed. 2021, 60, 5688-5672; Angew. Chem. 2021, 133, 5752-5756. DOI

    370) T. Dalton, T. Faber, F. Glorius,
    C-H Activation: towards sustainability and applications,
    ACS Cent. Sci. 2021, 7, 245-261. DOI

    369) P. Bellotti, M. Koy, C. Gutheil, S. Heuvel, F. Glorius,
    Three-component three-bond forming cascade via palladium photoredox catalysis,
    Chem. Sci. 2021, 12, 1810-1817. DOI

    368) T. Patra, M. Das, C. G. Daniliuc, F. Glorius,
    Metal-free, photosensitized oxyimination of unactivated alkenes with bifunctional oxime carbonates,
    Nature Catal. 2021, 4, 54-61. DOI

    Highlighted by Synfacts 2021, 17, 0319 (by Nobel laureate List), DOI;
    Highlighted by press release of WWU Münster (english);
    Highlighted by press release of WWU Münster (german);
    Highlighted by Organic Chemistry Portal;
    Highlighted by press releases of Phys.org, Eurekalert, Azom.com, SciTechDaily, Myscience.de, Techcodex.com,
    ScienceDaily, Bioengineer.org, ScienMag, Pressaggregate.com, 15minutenews.com, Idw-online (german),
    Lebensmittel-Biotechnologie (german), Innovations-Report (german), Genius-Science.fr (french).

    367) S. Greßies,§ M. Ito,§ M. Sakai, H. Osaki, J. H. Kim, T. Gensch, C. Daniliuc, N. Ando, S. Yamaguchi,* F. Glorius,*
    Twofold C–H Activation Enables Synthesis of a Diazacoronene‐type Fluorophore with Near Infrared Emission through Isosteric Replacement,
    Chem. Eur. J. 2021, 27, 2753-2759. DOI
    § These authors contributed equally.
    Highlighted by Synfacts 2021, 17, 0035. DOI

    366) H.-M. Huang, P. Bellotti, C. Daniliuc, F. Glorius,
    Radical Carbonyl Propargylation by Dual Catalysis,
    Angew. Chem. Int. Ed. 2021, 60, 2464-2471; Angew. Chem. 2021, 133, 2494-2501. DOI

    This is our 100th publication in Angewandte Chemie and we are happy to dedicate it to Prof. Carsten Bolm.

  • 2020

    365) F. Schäfers, L. Quach, J. L. Schwarz, M. Saladrigas, C. G. Daniliuc, F. Glorius,
    Direct Access to Monoprotected Homoallylic 1,2-Diols via Dual Chromium/Photoredox Catalysis,
    ACS Catal. 2020, 10, 11841-11847. DOI

    364) T. Wagener, A. Heusler, Z. Nairoukh, K. Bergander, C. G. Daniliuc, F. Glorius,
    Accessing (Multi)Fluorinated Piperidines Using Heterogeneous Hydrogenation,
    ACS Catal. 2020, 10, 12052-12057. DOI
    Highlighted in Synfacts 2020, 16, 1439. DOI
    Highlighted in Org. Process Res. Dev. 2020, 24, 2383-2393. DOI

     

    363) M. Wollenburg, A. Heusler, K. Bergander, F. Glorius,
    trans-Selective and Switchable Arene Hydrogenation of Phenol Derivatives,
    ACS Catal. 2020, 10, 11365-11370. DOI

    Highlighted by Synfacts 2021, 17, 0048. DOI
     

    362) S. Amirjalayer,* A. Bakker, M. Freitag, F. Glorius, H. Fuchs,
    Cooperation of N‐Heterocyclic Carbenes on a Gold Surface,
    Angew. Chem. Int. Ed. 2020, 59, 21230-21235; Angew. Chem. 2020, 132, 21416-21422. DOI

    Highlighted by press release of WWU Münster (english);
    Highlighted by press release of WWU Münster (german);
    Highlighted by press releases of
    ChemEurope.com, ScienceDaily.com, Myscience.org, Pro-Physik.de (german), Quimica.es (spanish).

     

    361) P. M. Pflüger, F. Glorius,
    Molecular Machine Learning: The Future of Synthetic Chemistry?,
    Angew. Chem. Int. Ed. 2020, 59, 18860-18865; Angew. Chem. 2020, 132, 19020-19025. DOI

    360) T. O. Paulisch, S. Bornemann, M. Herzog, S. Kudruk, L. Roling, A. L. Linard Matos, H.-J. Galla, V. Gerke,* R. Winter,* F. Glorius,*
    An Imidazolium‐based Lipid Analogue as Gene Transfer Agent,
    Chem. Eur. J. 2020, 26, 17176-17182
    . DOI

    359) F. Strieth-Kalthoff, F. Glorius,
    Triplet Energy Transfer Photocatalysis – Unlocking the Next Level,
    Chem 2020, 6, 1888-1903. DOI

    358) G. Tan, M. L. Schrader, C. Daniliuc, F. Strieth-Kalthoff, F. Glorius,
    C-H Activation Based Copper-Catalyzed One-Shot Synthesis of Organic Difluoroboron Complexes,
    Angew. Chem. Int. Ed. 2020, 59,
    21541-21545; Angew. Chem. 2020, 132, 21725-21729. DOI

    357) F. Strieth-Kalthoff, F. Sandfort, M. H. S. Segler, F. Glorius,
    Machine Learning the Ropes: Principles, Applications and Directions in Synthetic Chemistry,
    Chem. Soc. Rev. 2020, 49, 6154-6168. DOI

    356) H.-M. Huang, P. Bellotti, F. Glorius,
    Transition metal-catalysed allylic functionalization reactions involving radicals,
    Chem. Soc. Rev. 2020, 49, 6186-6197. DOI

    355) C. Gelis, A. Heusler, Z. Nairoukh, F. Glorius,
    Catalytic transfer hydrogenation of arenes and heteroarenes,
    Chem. Eur. J. 2020, 26, 14090-14094. DOI

    354) J. Ren, M. Freitag, C. Schwermann, A. Bakker, S. Amirjalayer, A. Rühling, H.-Y. Gao, N. L. Doltsinis*, F. Glorius*, H. Fuchs*,
    A Unidirectional Surface-Anchored N-Heterocyclic Carbene Rotor,
    Nano Lett. 2020, 20, 5922-5928. DOI

    353) H.-M. Huang, P. Bellotti, P. M. Pflüger, J. L. Schwarz, B. Heidrich, F. Glorius,
    A Three-Component, Interrupted Radical Heck/Allylic Substitution Cascade Involving Unactivated Alkyl Bromides,
    J. Am. Chem. Soc. 2020, 142, 10173-10183. DOI
    Highlighted twice in Organic Chemistry Portal (Abstracts and Highlights 2021)

    352) D. Moock, M. P. Wiesenfeldt, M. Freitag, S. Muratsugu, S. Ikemoto, R. Knitsch, J. Schneidewind, W. Baumann, A. H. Schäfer, A. Timmer, M. Tada, M. R. Hansen, F. Glorius,
    Mechanistic Understanding of the Heterogeneous, Rhodium-Cyclic (Alkyl)(Amino)Carbene-Catalyzed (Fluoro-)Arene Hydrogenation,
    ACS Catal. 2020, 10, 6309-6317. DOI

    351) S. Bornemann, M. Herzog, L. Roling, T. Paulisch, D. Brandis, S. Kriegler, H.-J. Galla, F. Glorius,* R. Winter,*
    lnteraction of imidazolium-based lipids with phospholipid bilayer membranes of different complexity,
    Phys. Chem. Chem. Phys. 2020, 22, 9775-9788. DOI

    350) M. Wollenburg, J. Bajohr, A. D. Marchese, A. Whyte, F. Glorius,* M. Lautens,*
    Palladium-Catalyzed Disilylation and Digermanylation of Alkene Tethered Aryl Halides: Direct Access to Versatile Silylated and Germanylated Heterocycles,
    Org. Lett. 2020, 22, 3679-3683. DOI

    349) D. T. Nguyen,§ M. Freitag,§ C. Gutheil, K. Sotthewes, B. J. Tyler, M. Böckmann, M. Das, F. Schlüter, N. L. Doltsinis, H. F. Arlinghaus, B. J. Ravoo,* F. Glorius,*
    An Arylazopyrazole Based N-Heterocyclic Carbene as Photoswitch on Gold Surfaces: Light-Switchable Wettability, Work Function and Conductance,
    Angew. Chem. Int. Ed. 2020,59, 13651-13656; Angew. Chem. 2020,132, 13754-13759. DOI
    § These authors contributed equally.

    Dedicated to Prof. F. Ekkehardt Hahn on the occasion of his 65th birthday.

    348) A. Bakker,§ M. Freitag,§ E. Kolodzeiski, P. Bellotti, A. Timmer, J. Ren, B. Schulze Lammers, D. Moock, H. W. Roesky, H. Mönig, S. Amirjalayer, H. Fuchs,* F. Glorius,*
    An Electron-rich Cyclic (Alkyl)(Amino) Carbene on Au(111), Ag(111) and Cu(111) Surfaces,
    Angew. Chem. Int. Ed. 2020, 59, 13643-13646; Angew. Chem. 2020, 132, 13745-13749 (selected as VIP). DOI
    § These authors contributed equally.

    Dedicated to Prof. Albert Eschenmoser on the occasion of his 95th birthday.

    347) Z. Nairoukh,§* F. Strieth-Kalthoff,§ K. Bergander, F. Glorius,*
    Understanding the Conformational Behavior of Fluorinated Piperidines: The Origin of the Axial‐F Preference,
    Chem. Eur. J. 2020, 26, 6141-6146. DOI
    § These authors contributed equally.

    Dedicated to Prof. Bernd Giese on the occasion of his 80th birthday.

    346) F. Sandfort, T. Knecht, T. Pinkert, C. G. Daniliuc, F. Glorius,
    Site-Selective Thiolation of (Multi)halogenated Heteroarenes,
    J. Am. Chem. Soc. 2020, 142, 6913-6919. DOI
    Highlighted by ChemistryViews.
    Highlighted in Synfacts 2020, 16, 0869. DOI

    345) W. Li,* T. Wagener, L. Hellmann, C. G. Daniliuc, C. Mück-Lichtenfeld, J. Neugebauer,* F. Glorius,*
    Design of Ru(II)-NHC-Diamine Precatalysts Directed by Ligand Cooperation: Applications and Mechanistic Investigations for Asymmetric Hydrogenation,
    J. Am. Chem. Soc. 2020, 142, 7100-7107. DOI
    Highlighted in Synfacts 2020, 16, 0809. DOI

    344) A. D. Marchese, M. Wollenburg, B. Mirabi, X. Abel-Snape, A. Whyte, F. Glorius,* M. Lautens*,
    Nickel-Catalyzed Enantioselective Carbamoyl Iodination: A Surrogate for Carbamoyl Iodides,
    ACS Catal. 2020, 10, 4780-4785. DOI

    343) F. Sandfort,§ F. Strieth-Kalthoff,§ M. Kühnemund,§ C. Beecks, F. Glorius,*
    A Structure-Based Platform for Predicting Chemical Reactivity,
    Chem 2020, 6, 1379-1390. DOI
    ChemRxiv (Preprint) 2019DOI
    § All three authors contributed equally.

    Highlighted by press release of WWU Münster (english);
    Highlighted by press release of WWU Münster (german);
    Highlighted by press releases of Chemistryworld.com, EurekAlert.orgChemEurope.com, Sciencedaily.com, Phys.org, Rasayanika.com, Myscience.org, X-mol.com, Scienmag.com, Spektrum.de (German), Chemie.de (German), Git-labor.de (German), Process.Vogel.de (German), Nouvelles du monde (French), BigData-Insider.de (German), Diário Carioca (Portugese);

    Highlighted by Spektrum der Wissenschaft 2020, (4), 32-34 (CHEMIE
    REAKTIONSVORHERSAGE MIT KI)
    ;
    Highlighted by Nature Reviews Chemistry 2020 (Gabriella Graziano)

    342) J. Ma, F. Schäfers, C. Daniliuc, K. Bergander, C. A. Strassert, F. Glorius,
    Gadolinium Photocatalysis: Dearomative [2+2] Cycloaddition/Ring-Expansion Sequence with Indoles,
    Angew. Chem. Int. Ed. 2020, 59, 9639-9645; Angew. Chem. 2020, 132, 9726-9735. DOI
    Highlighted by ChemistryViews.

    341) H.-M. Huang , M. Koy, E. Serrano, P. M. Pflüger, J. L. Schwarz, F. Glorius,
    Catalytic radical generation of π-allylpalladium complexes,
    Nature Catalysis 2020, 3, 393-400. DOI SharedIt link

    Highlighted by press release of WWU Münster (english);
    Highlighted by press release of WWU Münster (german);
    Highlighted by press releases of Sciencedaily.com, phys.org, EurekAlert.org, Innovations-Report.de (German), Technologik.fr (French), enciclopediavirtual.com.br (Portugese), Chemie.de (German), Chemeurope.com, Analytik.News (German).   

    340) M. A. Stoffels, F. J. R. Klauck, T. Hamadi, F. Glorius,* J. Leker,*
    Technology Trends of Catalysts in Hydrogenation Reactions: A Patent Landscape Analysis,
    Adv. Synth. Catal. 2020, 362, 1258-1274. DOI

    339) J. L. Schwarz,§ R. Kleinmans,§ T. O. Paulisch, F. Glorius,
    1,2-Amino Alcohols via Cr/Photoredox Dual-Catalyzed Addition of α‑Amino Carbanion Equivalents to Carbonyls,
    J. Am. Chem. Soc. 2020, 142, 2168-2174. DOI

    § Both authors contributed equally.
     

    338) J. L. Schwarz, H.-M. Huang, T. O. Paulisch, F. Glorius,
    Dialkylation of 1,3-Dienes by Dual Photoredox and Chromium Catalysis,
    ACS Catal. 2020, 10, 1621-1627. DOI

    337) S. Singha,§ E. Serrano,§ S. Mondal, C. G. Daniliuc, F. Glorius,
    Diastereodivergent synthesis of enantioenriched α,β-disubstituted-γ-butyrolactones via cooperative N-heterocyclic carbene/Ir catalysis,
    Nature Catalysis 2020, 3, 48-54. DOI
    § Both authors contributed equally.

    Highlighted by press release of WWU Münster (english)
    Highlighted by press release of WWU Münster (german);
    Highlighted by press releases of Phys.org, EurekAlert,
    Science Daily, myscience.de, chemeurope.com, Process, chemie.de (german), Innovations-Report (german), and Quimica.es (spanish);
    Featured in Org. Chem. Highlights: Arrays of Stereogenic Centers.

     

    336) T. Patra, P. Bellotti, F. Glorius,
    Photosensitized intermolecular carboimination of alkenes through persistent radical effect,
    Angew. Chem. Int. Ed. 2020, 59, 3172-3177; Angew. Chem. 2020, 132, 3198-3203. DOI
    Highlighted in Synform by Dr. Matteo Zanda: Synform 2020, 06, A86-A87.

     

    335) M. Koy,§ P. Bellotti,§ F. Katzenburg, C. Daniliuc, F. Glorius,
    Synthesis of All‐Carbon Quaternary Centers by Palladium‐Catalyzed Olefin Dicarbofunctionalization,
    Angew. Chem. Int. Ed. 2020, 59, 2375-2379; Angew. Chem. 2020, 132, 2395-2399. DOI
    § Both authors contributed equally.

    Dedicated to Roland Winter on the occasion of his 65th birthday

    334) T. O. Paulisch,§ F. Strieth-Kalthoff,§ C. Henkel, L. Pitzer, D. M. Guldi, F. Glorius,
    Chain propagation determines the chemo- and regioselectivity of alkyl radical additions to C–O vs. C–C double bonds,
    Chem. Sci. 2020, 11, 731-736. DOI
    § Both authors contributed equally.

    333) S. Cembellín, T. Dalton, T. Pinkert, F. Schäfers, F. Glorius,
    Highly Selective Synthesis of 1,3-Enynes, Pyrroles, and Furans by Manganese(I)-Catalyzed C–H Activation,
    ACS Catalysis 2020, 10, 197-202. DOI

  • 2019

    332) J. Ma, F. Strieth-Kalthoff, T. Dalton, M. Freitag, J. L. Schwarz, K. Bergander, C. Daniliuc, F. Glorius,
    Direct Dearomatization of Pyridines via an Energy-Transfer-Catalyzed Intramolecular [4+2] Cycloaddition,
    Chem 2019, 5, 2854-2864 (free featured article).  DOI

    Highlighted by L. Chang, Y. Chen, Z. Zuo,* Chem 2019, 5, 2744-2746. DOI
    Highlighted by press release of WWU Münster (english)
    Highlighted by press release of WWU Münster (german);
    Highlighted by press releases of Phys.org, EurekAlert,
    Science Daily, PhysicsNews, LABO (german),
    Innovations-Report, myscience.de, chemeurope.com, chemie.de (german), and GIT Laborportal (german).
     

    331) K. Goossens,* L. Rakers, B. Heinrich, G. Ahumada, T. Ichikawa, B. Donnio, T.J. Shin, C. W. Bielawski,* F. Glorius,*
    1,2,3,4,5-Pentaalkylimidazolium salts: synthesis, thermal behavior and induction of supramolecular, anisotropic, organic ionic plastic crystal mesophases,
    Chem. Mater. 2019, 31, 9593-9603. DOI

    330) M. Teders, S. Bernard, K. Gottschalk, L. J. Schwarz, E. Standley, E. Decuypere, C. Daniliuc, D. Audisio, F. Taran,* F. Glorius,*
    Accelerated Discovery in Photocatalysis by a Combined Screening Approach Involving MS-Tags,
    Org. Lett. 2019, 21, 9747-9752. DOI

    329) J.-H. Ye, L. Quach, T. Paulisch, F. Glorius,
    Visible-Light-Induced, Metal-Free Carbene Insertion into B–H Bonds between Acylsilanes and Pinacolborane,
    J. Am. Chem. Soc. 2019, 141, 16227-16231. DOI

    328) P. Bunse, C. Schlepphorst, F. Glorius, M. Kitamura, B. Wünsch,*
    Short and Atom-Economic Enantioselective Synthesis of the σ1-Receptor Ligands (S)- and (R)-Fluspidine—Important Tools for Positron Emission Tomography Studies,
    J. Org. Chem. 2019, 84, 13744-13754. DOI

    327) L. Pitzer,§ J. L. Schwarz,§ F. Glorius,
    Reductive radical-polar crossover: Traditional electrophiles in modern radical reactions,
    Chem. Sci. 2019, 10, 8285-8291. DOI
    § Both authors contributed equally.

    326) T. Pinkert, T. Wegner, S. Mondal, F. Glorius,
    Intermolecular 1,4–Carboamination of Conjugated Dienes Enabled by Cp*RhIII‐Catalyzed C–H Activation,
    Angew. Chem. Int. Ed. 2019, 58, 15041-15045; Angew. Chem. 2019, 131, 15183-15187. DOI

    325) L. Anhäuser, M. Teders, A. Rentmeister,* F. Glorius,*
    Bio-additive-based screening: toward evaluation of the biocompatibility of chemical reactions,
    Nature Protoc. 2019, 14, 2599-2626. DOI

    324) F. Strieth-Kalthoff, C. Henkel, M. Teders, A. Kahnt, W. Knolle, A. Gómez-Suárez, K. Dirian, W. Alex, K. Bergander, C. G. Daniliuc, B. Abel, D. M. Guldi,* F. Glorius,*
    Discovery of Unforeseen Energy-Transfer-Based Transformations Using a Combined Screening Approach,
    Chem 2019, 5, 2183-2194. DOI
    Highlighted by press release of WWU Münster (english);
    Highlighted by press release of WWU Münster (german)
    Highlighted by ChemieXtra 2019, (12), 12-14;
    Highlighted by press releases of
    Informationsdienst Wissenschaft idw, ScienceDaily, EurekAlert!, Phys.org, ScienceWorldReport, Myscience.de.

    323) Q. Lu, S. Mondal, S. Cembellín, S. Greßies, F. Glorius,
    Site-selective C–H Activation and Regiospecific Annulation Using Propargylic Carbonates,
    Chem. Sci. 2019, 10, 6560-6564. DOI

    322) C. Mühlen, J. Linde, L. Rakers, T. T. Y. Tan, F. Kampert, F. Glorius,* F. E. Hahn,*
    Synthesis of Iron(0) Complexes Bearing Protic NHC Ligands: Synthesis and Catalytic Activity,
    Organometallics 2019, 38, 2417-2421. DOI

    321) T. Patra, S. Mukherjee, J. Ma, F. Strieth-Kalthoff, F. Glorius,
    Visible-light photosensitized aryl and alkyl decarboxylative carbon-heteroatom and carbon-carbon bond formations,
    Angew. Chem. Int. Ed. 2019, 58, 10514-10520; Angew. Chem. 2019, 131, 10624-10630. DOI
    (ChemRxiv 2019, DOI).

    320) M. J. James, F. Strieth-Kalthoff, F. Sandfort, F. J. R. Klauck, F. Wagener, F. Glorius,
    Visible-Light-Mediated Charge Transfer Enables C–C Bond Formation with Traceless Acceptor Groups,
    Chem. Eur. J. 2019, 25, 8240-8244. DOI
    Dedicated to Richard J. K. Taylor on the occasion of his 70th birthday

    Please, see also: Varinder Aggarwal et al., Angew. Chem. Int. Ed. 2019, early view: Catalyst‐Free Deaminative Functionalizations of Primary Amines by Photoinduced Single‐Electron Transfer. DOI

    319) M. N. Hopkinson,* F. Glorius,*
    An Overview of NHCs,
    in N-Heterocyclic Carbenes in Organocatalysis (Ed. A. T. Biju); Wiley-VCH, Weinheim, 2019, Chapter 1, p. 1-36.

    318) L. Pitzer,§ F. Schäfers,§ F. Glorius,
    Rapid Assessment of the Reaction Condition-Based Sensitivity of Chemical Transformations,
    Angew. Chem. Int. Ed. 2019, 58, 8572-8576; Angew. Chem. 2019, 131, 8660-8664. DOI
    § Both authors contributed equally.
    Dedicated to Prof. K. Barry Sharpless

    Please, kindly check it out. This conditions-based sensitivity screen nicely complements the additive-based robustness screen. For a free-to-use template of the radar diagram, see this link.

    Highlighted by Nature Chemistry. DOI

    317) T. Knecht,§ S. Mondal,§ J.-H. Ye, M. Das, F. Glorius,
    Intermolecular, Branch-Selective and Redox-Neutral Cp*IrIII-Catalyzed Allylic C–H Amidation,
    Angew. Chem. Int. Ed. 2019, 58, 7117-7121; Angew. Chem. 2019, 131, 7191-7195. DOI
    § Both authors contributed equally.
    Dedicated to Prof. Yitzhak Apeloig on the occasion of his 75th birthday

    Please, see also: H. Lei, T. Rovis, J. Am. Chem. Soc. 2019, 141, 2268. DOI

    316) E. E. Lin, J.-Q. Wu, F. Schäfers, X.-X. Su, K.-F. Wang, J.-L. Li, Y. Chen, X. Zhao, H. Ti, Q. Li, T.-M. Ou, F. Glorius, H. Wang,*
    Regio- and stereoselective synthesis of tetra- and triarylethenes by N-methylimidodiacetyl boron-directed palladium-catalysed three-component coupling,
    Commun. Chem. 2019, 2, 34. DOI
    315) J. Henschel, L. Schwarz, F. Glorius, M. Winter, S. Nowak,*
    Further insights into structural diversity of phosphorus-based decomposition products in lithium ion battery electrolytes via liquid chromatographic techniques hyphenated to ion trap - time of flight mass spectrometry,
    Analytical Chemistry 2019, 91, 3980-3988.  DOI
    314) M. P. Wiesenfeldt, Z. Nairoukh, T. Dalton, F. Glorius,
    Selective Arene Hydrogenation Provides Direct Access to Saturated Carbo‐ and Heterocycles,
    Angew. Chem. Int. Ed. 2019, 58, 10460-10476; Angew. Chem. 2019, 131, 10570-10586. DOI

    Dedicated to Prof. Ryōji Noyori on the occasion of his 80th birthday
    313) K. Goossens,§ L. Rakers,§ T. J. Shin, R. Honeker, C. W. Bielawski,* F. Glorius,*
    Substituted Azolium Disposition: Examining the Effects of Alkyl Placement on Thermal Properties,
    Crystals 2019, 9, 34. DOI
    § Both authors contributed equally.
    312) T. Knecht, T. Pinkert,§ T. Dalton,§ A. Lerchen, F. Glorius,
    Cp*RhIII-Catalyzed Allyl–Aryl Coupling of Olefins and Arylboron Reagents Enabled by C(sp3)–H Activation,
    ACS Catal. 2019, 9, 1253-1257. DOI
    § Both authors contributed equally.

    311) Z. Nairoukh , M. Wollenburg, C. Schlepphorst, K. Bergander, F. Glorius,
    The formation of all-cis-(multi)fluorinated piperidines by a dearomatization–hydrogenation process,
    Nature Chem. 2019, 11, 264-270. DOI, OA Link (Springer Nature SharedIt)
    Highlighted by Synfacts 2019, 15, 0283;
    Highlighted by press release of WWU Münster (english);
    Highlighted by press release of WWU Münster (german);
    Highlighted by ChemieXtra 2019, (6), 16;
    Highlighted by press releases of EurekAlert; Informationsdienst Wissenschaft idw, Chemie.de, ScienceDaily, innovations-report, Phys.org, Research-in-Germany, Wissenschaftler.de, Analytiker.de, Tunis Daily News, Chemical Processing and World of Chemicals.

    See also the following link regarding the commercialization of the hydrogenation of fluoroarenes by Provendis GmbH.

    310) F. J. R. Klauck, H. Yoon, M. J. James, M. Lautens,* F. Glorius,*
    Visible-Light-Mediated Deaminative Three-Component Dicarbofunctionalization of Styrenes with Benzylic Radicals,
    ACS Catal. 2019, 9, 236-241. DOI
    309) M. Wollenburg,§ D. Moock,§ F. Glorius,
    Hydrogenation of Borylated Arenes,
    Angew. Chem. Int. Ed. 2019, 58, 6549-6553; Angew. Chem. 2019, 131, 6621-6625. DOI
    § Both authors contributed equally.
    308) M. Freitag,§ N. Möller,§ A. Rühling, C. A. Strassert, B. J. Ravoo,* F. Glorius,*
    Photocatalysis in the dark: Near infrared light driven photoredox catalysis by an upconversion nanoparticle/photocatalyst system,
    ChemPhotoChem. 2019, 3, 24-27. DOI
    § Both authors contributed equally.
  • 2018

    307) F. Sandfort,§ F. Strieth-Kalthoff,§ F. J. R. Klauck, M. J. James, F. Glorius,
    Deaminative Borylation of Aliphatic Amines Enabled by Visible Light Excitation of an Electron-Donor-Acceptor Complex,
    Chem. Eur. J. 2018, 24, 17210-17214. DOI
    § Both authors contributed equally.

    Paper was most accessed from 10/2018-09/2019.
    306) L. Pitzer,§ F. Sandfort,§ F. Strieth-Kalthoff, F. Glorius,
    Carbonyl-Olefin Cross-Metathesis Through a Visible-Light-Induced 1,3-Diol Formation and Fragmentation Sequence,
    Angew. Chem. Int. Ed. 2018, 57, 16219-16223; Angew. Chem. 2018, 130, 16453-16457. DOI
    § Both authors contributed equally.
    305) P. Tegeder,§ M. Freitag,§ K. M. Chepiga, S. Muratsugu, N. Möller, S. Lamping, M. Tada, F. Glorius,* B. J. Ravoo,*
    N-Heterocyclic Carbene-Modified AuPd Alloy Nanoparticles and their Application as Biomimetic and Heterogeneous Catalysts,
    Chem. Eur. J. 2018, 24, 18682-18688. DOI

    § Both authors contributed equally.
    Selected as hot paper by Chemistry - A European Journal
    304) J. L. Schwarz,§ F. Schäfers,§ A. Tlahuext-Aca, L. Lückemeier, F. Glorius,
    Diastereoselective Allylation of Aldehydes by Dual Photoredox and Chromium Catalysis,
    J. Am. Chem. Soc. 2018, 140, 12705-12709. DOI
    § Both authors contributed equally.
    303) C. Zhu,§ T. Pinkert,§ S. Greßies, F. Glorius,
    One-Pot C−H Formylation Enabled by Relay Catalysis of Manganese(I) and Iron(III),
    ACS Catal. 2018, 8, 10036-10042. DOI
    § Both authors contributed equally.
    302) A. Bakker, A. Timmer, E. Kolodzeiski, M. Freitag, H. Y. Gao, H. Mönig, S. Amirjalayer,* F. Glorius,* H. Fuchs,*
    Elucidating the binding modes of N-heterocyclic carbenes on a gold surface,
    J. Am. Chem. Soc. 2018, 140, 11889-11892. DOI
    301) A. Lerchen, T. Knecht, M. Koy, J. B. Ernst, K. Bergander, C. G. Daniliuc, F. Glorius,
    Non-Directed Cross-Dehydrogenative (Hetero)arylation of Allylic C(sp3)–H bonds enabled by C–H activation,
    Angew. Chem. Int. Ed. 2018, 57, 15248-15253; Angew. Chem. 2018, 130, 15468-15472. DOI

    Selected as Hot Paper by Angewandte Chemie;
    Highlighted in Synfacts 2018, 14, 1176.
    300) L. Rakers, F. Schäfers, F. Glorius,
    In water & under mild conditions: α-Alkylation of Ketones with Alcohols by Phase-Transfer-Assisted Borrowing Hydrogen Catalysis,
    Chem. Eur. J. 2018, 24, 15529-15532. DOI
    299) P. Tegeder, M. Marelli, M. Freitag, L. Polito, S. Lamping, R. Psaro, F. Glorius, B. J. Ravoo,* C. Evangelisti,*
    Metal vapor synthesis of ultrasmall Pd nanoparticles functionalized with N-heterocyclic carbenes,
    Dalton Trans. 2018, 47, 12647-12651. DOI
    298) F. Strieth-Kalthoff, M. J. James, M. Teders, L. Pitzer, F. Glorius,
    Energy transfer catalysis mediated by visible light: principles, applications, directions,
    Chem. Soc. Rev. 2018, 47, 7190-7202. DOI

    297) M. Teders, C. Henkel, L. Anhäuser, F. Strieth-Kalthoff, A. Goméz-Suárez, R. Kleinmans, A. Kahnt, A. Rentmeister, D. M. Guldi,* F. Glorius,*
    The energy-transfer-enabled biocompatible disulfide–ene reaction,
    Nat. Chem. 2018, 10, 981-988. DOI
    Corresponding behind the paper blog entry in the Nature Research Community

    Highlighted by press release of WWU Münster;
    Highlighted by Phys.orgChemie.de; Labo; LocalXXL; World University News; Research-in-Germany; Chemie-Link.

    296) M. J. James, J. L. Schwarz, F. Strieth-Kalthoff, B. Wibbeling, F. Glorius,
    Dearomative Cascade Photocatalysis: Divergent Synthesis through Catalyst Selective Energy Transfer,
    J. Am. Chem. Soc. 2018, 140, 8624-8628. DOI
    295) W. Li, M. Wollenburg, F. Glorius,
    Enantioselective synthesis of 2-oxazolidinones by ruthenium(II)–NHC-catalysed asymmetric hydrogenation of 2-oxazolones,
    Chem. Sci. 2018, 9, 6260-6263. DOI

    Highlighted in Synfacts 2018, 14, 1051.
    294) D. T. Nguyen,§ M. Freitag,§ M. Körsgen, S. Lamping, A. Rühling, A. H. Schäfer, M. H. Siekman, H. F. Arlinghaus, W. G. van der Wiel, F. Glorius,* B. J. Ravoo,*
    Versatile Micropatterns of N-Heterocyclic Carbenes on Gold Surfaces: Increased Thermal and Pattern Stability with Enhanced Conductivity,
    Angew. Chem. Int. Ed. 2018, 57, 11465-11469; Angew. Chem. 2018, 130, 11637-11641. DOI
    § Both authors contributed equally.
    293) S. Greßies, F. Klauck, J. H. Kim, C. Daniliuc, F. Glorius,
    Ligand-Enabled Enantioselective Csp3-H Activation of Tetrahydroquinolines and Saturated Aza-Heterocycles by Rh(I),
    Angew. Chem. Int. Ed. 2018, 57, 9950-9954; Angew. Chem. 2018, 130, 10098-10102. DOI

    Highlighted by Angewandte Chemie as very important paper.
    292) L. Rakers, L. M. Martínez-Prieto, A. M. López-Vinasco, K. Philippot, P. W. N. M. van Leeuwen, B. Chaudret,* F. Glorius,*
    Ruthenium nanoparticles ligated by cholesterol-derived NHCs and their application in the hydrogenation of arenes,
    Chem. Commun. 2018, 54, 7070-7073. DOI
    Highlighted in Organic Chemistry Portal

     

    291) M. P. Wiesenfeldt, T. Knecht, C. Schlepphorst, F. Glorius,
    Silylarene hydrogenation - a strategic approach enabling direct access to versatile silylated saturated carbo- and heterocycles,
    Angew. Chem. Int. Ed. 2018, 57, 8297-8300; Angew. Chem. 2018, 130, 8429-8432. DOI

    290) S. Mukherjee, T. Patra, F. Glorius,
    Cooperative Catalysis: A Strategy to Synthesize Trifluoromethyl-thioesters from Aldehydes,
    ACS Catal. 2018, 8, 5842-5846. DOI
    289) Q. Lu, S. Mondal, S. Cembellín, F. Glorius,
    Mn(I)/Ag(I) Relay Catalysis: Traceless Diazo-Assisted C(sp2)–H/C(sp3)–H Coupling to β-(Hetero)Aryl/Alkenyl Ketones,
    Angew. Chem. Int. Ed. 2018, 57, 10732-10736; Angew. Chem. 2018, 130, 10892-10896. DOI
    288) R. A. Garza-Sanchez, T. Patra, A. Tlahuext-Aca, F. Strieth-Kalthoff, F. Glorius,
    DMSO as switchable alkylating agent in heteroarene C–H functionalization,
    Chem. Eur. J. 2018, 24, 10064-10068. DOI
    287) L. Rakers, D. Grill, A. L. L. Matos, S. Wulff, D. Wang, J. Börgel, M. Körsgen, H. F. Arlinghaus, H.-J. Galla,* V. Gerke,* F. Glorius,*
    Addressable Cholesterol Analogs for Live Imaging of Cellular Membranes,
    Cell Chem. Biol. 2018, 25, 952-961.e12. DOI

    Highlighted by WWU Münster
    Highlighted by Cells in motion (Cluster of excellence)
    Highlighted on MTA - Das Portal
    Highlighted on PhysOrg
    Highlighted by Science Trends
    286) L. Rakers, F. Glorius,
    Flexible design of ionic liquids for membrane interactions,
    Biophys Rev. 2018, 10, 747-750. DOI
    285) S. Singha, T. Patra, C. G. Daniliuc, F. Glorius,
    Highly Enantioselective [5+2] Annulations through Cooperative NHC Organocatalysis and Palladium Catalysis,
    J. Am. Chem. Soc. 2018, 140, 3551-3554. DOI

    Highlighted in ChemistryViews
    284) X. Wang, Y. Li, T. Knecht, C. G. Daniliuc, K. Houk,* F. Glorius,*
    Unprecedented Dearomatized Spirocyclopropane in a Sequential Rh(III)-catalyzed C-H Activation and Rearrangement Reaction,
    Angew. Chem. Int. Ed. 2018, 57, 5520-5524; Angew. Chem. 2018, 130, 5618-5622. DOI
    283) A. Tlahuext-Aca, R. A. Garza-Sanchez, M. Schäfer, F. Glorius,
    Visible-Light-Mediated Synthesis of Ketones by the Oxidative Alkylation of Styrenes,
    Org. Lett. 2018, 20, 1546-1549. DOI

    Highlighted in ChemistryViews
    282) A. Lv, M. Freitag, K. M. Chepiga, A. H. Schäfer, F Glorius,* L. Chi,*
    N-Heterocyclic Carbene-Treated Gold Surfaces in Pentacene Organic Field-Effect Transistors: Improved Stability and Contact at the Interface,
    Angew. Chem. Int. Ed. 2018,
    57, 4792-4796; Angew. Chem. 2018, 130, 4883-4887. DOI
    281) M. Koy, F. Sandfort, A. Tlahuext-Aca, L. Quach, C. G. Daniliuc, F. Glorius,
    Palladium-Catalyzed Decarboxylative Heck-Type Coupling of Activated Aliphatic Carboxylic Acids Enabled by Visible Light,
    Chem. Eur. J. 2018,
    24, 4552-4555. DOI

    Paper was most accessed from 10/2018-09/2019.
    280) A. Tlahuext-Aca, L. Candish, R. A. Garza-Sanchez, F. Glorius,
    Decarboxylative Olefination of Activated Aliphatic Acids Enabled by Dual Organophotoredox/Copper Catalysis,
    ACS Catal. 2018, 8, 1715-1719. DOI
    279) X. Wang, A. Lerchen, C. G. Daniliuc, F. Glorius,
    Efficient Synthesis of Arylated Furans Enabled by a Sequential Rh-catalyzed Arylation and Cycloisomerization of Cyclopropenes,
    Angew. Chem. Int. Ed. 2018, 57, 1712-1716; Angew. Chem. 2018, 130, 1728-1732. DOI
    278) T. Gensch, M. James, T. Dalton, F. Glorius,
    Increasing Catalyst Efficiency in C−H Activation Catalysis,
    Angew. Chem. Int. Ed. 2018, 57, 2296-2306; Angew. Chem. 2018, 130, 2318-2328. DOI
    277) Q. Lu, S. Cembellín Santos, S. Greßies, S. Singha, C. Daniliuc, F. Glorius,
    Manganese(I)-Catalyzed C-H (2-indolyl)methylation: Expedient Access to Diheteroarylmethanes,
    Angew. Chem. Int. Ed. 2018,
    57, 1399-1403; Angew. Chem. 2018, 130, 1413-1417. DOI
    276) S. Vásquez-Céspedes, X. Wang, F. Glorius,
    Plausible Rh(V) Intermediates in Catalytic C−H Activation Reactions,
    ACS Catal. 2018, 8, 242-257. DOI
    275) C. Zhu, J. L. Schwarz, S. Cembellín, S. Greßies, F. Glorius,
    Highly Selective Manganese(I)/Lewis Acid Cocatalyzed Direct C−H Propargylation Using Bromoallenes,
    Angew. Chem. Int. Ed. 2018,
    57, 437-441; Angew. Chem. 2018, 130, 445-449. DOI
    274) C. Schlepphorst, M. P. Wiesenfeldt, F. Glorius,
    Enantioselective Hydrogenation of Imidazo[1,2-a]pyridines,
    Chem. Eur. J. 2018,
    24, 356-359. DOI
  • 2017

    273) S. Mukherjee, R. A. Garza-Sanchez§, A. Tlahuext-Aca§, F. Glorius,
    Alkynylation of Csp2(O)–H Bonds Enabled by Photoredox-Mediated Hydrogen-Atom Transfer,
    Angew. Chem. Int. Ed. 2017, 56, 14723-14726; Angew. Chem. 2017, 129, 14915-14919. DOI
    § Both authors contributed equally.
    272) L. Pitzer§, F. Sandfort§, F. Strieth-Kalthoff, F. Glorius,
    Intermolecular Radical Addition to Carbonyls Enabled by Visible Light Photoredox Initiated Hole Catalysis,
    J. Am. Chem. Soc. 2017, 139, 13652-13655. DOI
    § Both authors contributed equally.

    Highlighted in Synfacts 2017, 13, 1313.
    271) S. Röser, A. Lerchen, L. Ibing, X. Cao, J. Kasnatscheew, F. Glorius,* M. Winter,* R. Wagner,*
    Highly effective solid electrolyte interphase (SEI)-forming electrolyte additive enabling high voltage lithium ion batteries,
    Chem. Mater. 2017, 29, 7733-7739. DOI
    270) Q. Lu§, S. Greßies§, S. Cembellín, F. J. R. Klauck, C. G. Daniliuc, F. Glorius,
    Redox-Neutral Manganese(I)-Catalyzed C–H Activation: Traceless Directing Group Enabled Regioselective Annulation,
    Angew. Chem. Int. Ed. 2017, 56, 12778-12782; Angew. Chem. 2017, 129, 12954-12958. DOI
    § Both authors contributed equally.
    269) T. Gensch§, M. Teders§, F. Glorius,
    An Approach to Comparing the Functional Group Tolerance of Reactions,
    J. Org. Chem. 2017, 82, 9154-9159. DOI
    § Both authors contributed equally.
    Highlighted in Chemistry & Engineering News: T. Nguyen, Chem. Eng. News 2017, 95 (38), 16-18; What’s the best way to show a new chemical reaction’s scope?

    268) M. P. Wiesenfeldt, Z. Nairoukh, W. Li, F. Glorius,
    Hydrogenation of fluoroarenes: Direct access to all-cis-(multi)fluorinated cycloalkanes,
    Science 2017, 357, 908-912. DOI

    Highlighted in Chemistry World;
    Highlighted by press release of the WWU Münster;
    Highlighted by Analytik News;
    Highlighted by local newspaper Westfälische Nachrichten;
    Highlighted in Synfacts 2017, 13, 1265.

    267) F. J. R. Klauck§, M. J. James§, F. Glorius,
    Deaminative Strategy for the Visible Light-Mediated Generation of Alkyl Radicals,
    Angew. Chem. Int. Ed. 2017, 56, 12336-12339; Angew. Chem. 2017, 129, 12505-12509.  DOI
    § Both authors contributed equally.
    266) M. Fleige, F. Glorius,
    α-Unsubstituted Pyrroles by NHC-Catalyzed Three-Component Coupling - Direct Synthesis of a Versatile Atorvastatin Derivative,
    Chem. Eur. J. 2017, 23, 10773-10776. DOI

    Highlighted in Synfacts 2017, 13, 1117.
    265) F. Lied, T. Patra, F. Glorius,
    Group 9 Transition Metal-Catalyzed C-H Halogenations,
    Isr. J. Chem. 2017, 57, 945-952. DOI
    264) J. B. Ernst, C. Schwermann, G.-I. Yokota, M. Tada, S. Muratsugu,* N. L. Doltsinis,* F. Glorius,*
    Molecular Adsorbates Switch on Heterogeneous Catalysis: Induction of Reactivity by N-Heterocyclic Carbenes,
    J. Am. Chem. Soc. 2017, 139, 9144-9147. DOI
    263) D. Janssen-Müller, C. Schlepphorst, F. Glorius,
    Privileged Chiral N-Heterocyclic Carbene Ligands for Asymmetric Transition-Metal Catalysis,
    Chem. Soc. Rev. 2017, 46, 4845-4854.  DOI
    262) A. Lerchen, T. Knecht, M. Koy, C. G. Daniliuc, F. Glorius,
    A General Cp*Co(III)-Catalyzed Intramolecular C–H Activation Approach for the Efficient Total Syntheses of Aromathecin, Protoberberine and Tylophora Alkaloids,
    Chem. Eur. J. 2017, 23, 12149-12152. DOI
    261) L. M. Martínez-Prieto, L. Rakers, Á. M. López-Vinasco, I. Cano, Y. Coppel, K. Philippot, F. Glorius,* B. Chaudret,* P. W. N. M. van Leeuwen,*
    Soluble Platinum Nanoparticles ligated by Long-Chain N-Heterocyclic Carbenes as Catalysts,
    Chem. Eur. J. 2017, 23, 12779-12786. DOI
    260) L. Candish, M. Teders, F. Glorius,
    Transition-Metal-Free, Visible-Light-Enabled Decarboxylative Borylation of Aryl N‑Hydroxyphthalimide Esters,
    J. Am. Chem. Soc. 2017, 139, 7440-7443. DOI

    Highlighted in Organic Chemistry Portal

    259) R. A. Garza-Sanchez, A. Tlahuext-Aca, G. Tavakoli, F. Glorius,
    Visible-Light-Mediated Direct Decarboxylative C−H Functionalization of Heteroarenes,
    ACS Catal. 2017, 7, 4057-4061. DOI

    Please, also see our
    Correction to “Visible Light-Mediated Direct Decarboxylative C−H 2 Functionalization of Heteroarenes”,
    ACS Catal. 2022, 12, 6640. DOI

    258) M. Teders, L. Pitzer, S. Buss, F. Glorius,
    Regioselective Synthesis of 2‑Substituted Indoles from Benzotriazoles and Alkynes by Photoinitiated Denitrogenation,
    ACS Catal. 2017, 7, 4053-4056. DOI
    257) X. Wang, T. Gensch, A. Lerchen, C. G. Daniliuc, F. Glorius,
    Cp*Rh(III)/Bicyclic Olefin Cocatalyzed C−H Bond Amidation by Intramolecular Amide Transfer,
    J. Am. Chem. Soc. 2017, 139, 6506-6512. DOI
    256) C. Kutzscher, D. Janssen-Müller, A. Notzon, U. Stoeck, V. Bon, I. Senkovska, S. Kaskel*, F. Glorius*,
    Synthesis of the homochiral metal-organic framework DUT-129 based on a chiral dicarboxylate linker with 6 stereocenters,
    CrystEngComm. 2017, 19, 2494-2499. DOI
    255) Q. Lu, S. Greßies, F. J. R. Klauck, F. Glorius,
    Manganese(I)-Catalyzed Regioselective C–H Allenylation: Direct Access to 2-Allenylindoles,
    Angew. Chem. Int. Ed. 2017, 56, 6660-6664; Angew. Chem. 2017, 129, 6760-6764. DOI
    254) S. Vásquez-Céspedes, M. Holtkamp, U. Karst,* F. Glorius,*
    Reusable and magnetic Palladium and Copper Oxide catalysts in direct ortho- and meta-arylation of anilide derivatives,
    Synlett 2017, 28, 2759-2754. DOI
    Highlighted as Synfacts of the month in Synfacts 2018, 14, 0315.
    253) C. Guo,* D. Janssen-Müller, M. Fleige, A. Lerchen, C. G. Daniliuc, F. Glorius,*
    Mechanistic Studies on a Cooperative NHC Organocatalysis/Palladium Catalysis System: Uncovering Significant Lessons for Mixed Chiral Pd(NHC)(PR3) Catalyst Design,
    J. Am. Chem. Soc. 2017, 139, 4443-4451. DOI
    2017 Guo Jacs 4443
    252) L. Candish, M. Freitag, T. Gensch, F. Glorius,
    Mild, visible light-mediated decarboxylation of aryl carboxylic acids to access aryl radicals,
    Chem. Sci. 2017, 8, 3618-3622. DOI
    2017 Candish ChemSci 3618
    251) Q. Lu, F. J. R. Klauck, F. Glorius,
    Manganese-Catalyzed Allylation via Sequential C–H and C–C/C–Het Bond Activation,
    Chem. Sci. 2017, 8, 3379-3383. DOI
    2017 Lu Chemsci 3379
    250) N. Möller§, A. Rühling§, S. Lamping, T. Hellwig, C. Fallnich, B. J. Ravoo,* F. Glorius,*
    Stabilization of High Oxidation State Upconversion Nanoparticles by N-Heterocyclic Carbenes (NHCs),
    Angew. Chem. Int. Ed. 2017, 56, 4356-4360; Angew. Chem. 2017, 129, 4421-4425. DOI
    § Both authors contributed equally.
    2017 Rühling ACIE 4356
    249) D. Paul, F. Heins, S. Krupski, A. Hepp, C. G. Daniliuc, K. Klahr, J. Neugebauer, F. Glorius,* F. E. Hahn,*
    Synthesis and Reactivity of Intramolecularly NHC-Stabilized Germylenes and Stannylenes,
    Organometallics 2017, 36, 1001-1008. DOI
    2017 Paul Organomtetallics 1001
    248) W. Li, M. Wiesenfeldt, F. Glorius,
    Ruthenium−NHC−Diamine Catalyzed Enantioselective Hydrogenation of Isocoumarins,
    J. Am. Chem. Soc. 2017, 139, 2585-2588. DOI

    Highlighted in Synfacts 2017, 13, 0494.
    2017 W Li Jacs 2585
    247) A. Tlahuext-Aca, R. A. Garza-Sanchez, F. Glorius,
    Multicomponent Oxyalkylation of Styrenes Enabled by Hydrogen Bond Assisted Photoinduced Electron Transfer,
    Angew. Chem. Int. Ed. 2017, 56, 3708-3711; Angew. Chem. 2017,129, 3762-3765. DOI
    2017 Tlahuext Aca Acie 3708
    246) L. Rakers, L. Tebben,* F. Glorius*,
    co.labore – A Genuine Collaboration between Arts and Science, Reflecting Viewpoints and Merging Skills,
    Chem. Eur. J. 2017, 23, 5860-5863. DOI
    Publication is part of special issue of CEJ for the SFB 858 on “Synergetic effects in Chemistry”.
    2017 Rakers Chemeurj 5860
    245) D. Janssen-Müller,§ S. Singha,§ F. Lied, K. Gottschalk, F. Glorius,
    NHC-Organocatalyzed CAr–O Bond Cleavage: Mild access to 2 Hydroxybenzophenones,
    Angew. Chem. Int. Ed. 2017, 56, 6276-6279; Angew. Chem. 2017, 129, 6373-6376. DOI
    § Both authors contributed equally.
    Highlighted in Synfacts 2017, 13, 0651.
    2017 Janssen Mueller Acie 6276
    244) F. Lied, H. Brodnik Žugelj, S. Kress, B. Štefane, F. Glorius*, M. Lautens*,
    Employing Pd-Catalyzed C–H Arylation in Multicomponent-Multicatalyst Reactions (MC)2R: One-Pot Synthesis of Dihydrobenzoquinolines,
    ACS Catal. 2017, 7, 1378-1382. DOI
    2017 Lied Acs Catal 1378
    243) J. Zhang, C. Chang, B. Yang, N. Cao, C. Peng, H. Zhang, D.-T. D. Tang, F. Glorius, G. Erker, H. Fuchs, Q. Li,* L. Chi,*
    Step Edge Assisted Direct Linear Alkane Coupling,
    Chem. Eur. J. 2017, 23, 6185-6189. DOI
    Publication is part of special issue of CEJ for the SFB 858 on “Synergetic effects in Chemistry”.
    2017 Tang Chemeurj 6185

    242) P. Drücker, A. Rühling, D. Grill, D. Wang, A. Draeger, V. Gerke, F. Glorius,* H.-J. Galla,*
    Imidazolium Salts Mimicking the Structure of Natural Lipids Exploit Remarkable Properties Forming Lamellar Phases and Giant Vesicles,
    Langmuir 2017, 33, 1333-1342.
    DOI
    This paper was selected for the Langmuir front cover image of the issue it appears in.

    2017 Ruehling Langmuir 1333

    241) A. Rühling, D. Wang, J. B. Ernst, S. Wulff, R. Honeker, C. Richter, A. Ferry, H.-J. Galla,* F. Glorius,*
    Influence of the Headgroup of Azolium-Based Lipids on Their Biophysical Properties and Cytotoxicity,
    Chem. Eur. J. 2017, 23, 5920-5924. DOI
    Publication is part of special issue of CEJ for the SFB 858 on “Synergetic effects in Chemistry”; selected for an Inside Cover.

    2017 Ruehling Chemeurj 5920
    240) A. Rühling§, L. Rakers§, F. Glorius,
    Long alkyl chain NHC palladium complexes for the amination and hydrodehalogenation of aryl chlorides in lipophilic media,
    ChemCatChem 2017, 9, 547-550. DOI
    § Both authors contributed equally.
    Publication is part of special issue celebrating the 50th Annual Catalysis Meeting in Weimar; selected for an Inside Cover.
    2017 Ruehling Chemcatchem 547
    239) X. Wang, A. Lerchen, T. Gensch, T. Knecht, C. G. Daniliuc, F. Glorius,
    Combination of Cp*RhIII-Catalyzed C-H Activation and a Wagner–Meerwein-Type Rearrangement,
    Angew. Chem. Int. Ed. 2017, 56, 1381-1384; Angew. Chem. 2017, 129, 1401-1405. DOI
    2017 X Wang Acie 1381
    238) M. Teders, A. Gómez-Suárez§, L. Pitzer§, M. N. Hopkinson, F. Glorius,
    Diverse Visible-Light-Promoted Functionalizations of Benzotriazoles Inspired by Mechanism-Based Luminescence Screening,
    Angew. Chem. Int. Ed. 2017, 56, 902-906; Angew. Chem. 2017, 129, 921-925. DOI
    § Both authors contributed equally.
    2017 Teders Acie 902
    237) G. Wang, A. Rühling, S. Amirjalayer, M. Knor, J. B. Ernst, C. Richter, H.-J. Gao, A. Timmer, H.-Y. Gao, N. L. Doltsinis, F. Glorius,* H. Fuchs,*
    Ballbot-type motion of N-heterocyclic carbenes on gold surfaces,
    Nature Chem. 2017, 9, 152-156. DOI
    Highlighted in Chemistry World
    Highlighted in University Press Release
    Highlighted on Phys.org
    2017 Ruehling Naturechem 152
    236) Q. Lu, F. Glorius,
    Radical Enantioselective C(sp3)-H Functionalization,
    Angew. Chem. Int. Ed. 2017, 56, 49-51; Angew. Chem. 2017, 129, 49-51. DOI
    2017 Lu Acie 49
    235) J. B. Ernst, L. Rakers, F. Glorius,
    Sodium Chloride Catalyzed Regioselective Trifluoromethylthiolation of Furans,
    Synthesis 2017, 49, 260-268. DOI
    Publication is part of a special issue dedicated to Prof. Dieter Enders.
    20167 Ernst Synthesis 260
  • 2016

    234) S. Mukherjee,§ B. Maji,§ A. Tlahuext-Aca, F. Glorius,
    Visible-Light-Promoted Activation of Unactivated C(sp3)−H Bonds and Their Selective Trifluoromethylthiolation,
    J. Am. Chem. Soc. 2016, 138, 16200-16203. DOI
    § Both authors contributed equally.
    233) D. Wang, D. H. de Jong, A. Rühling, V. Lesch, K. Shimizu, S. Wulff, A. Heuer,* F. Glorius,* H.-J. Galla,*
    Imidazolium-Based Lipid Analogues and Their Interaction with Phosphatidylcholine Membranes,
    Langmuir 2016, 32, 12579–12592. DOI
    232) L. Rakers, L. Tebben, F. Glorius,
    Perspektivwechsel,
    Nachrichten aus der Chemie 2016, 64, 1188-1189. DOI
    231) F. Lied, A. Lerchen, T. Knecht, C. Mück-Lichtenfeld, F. Glorius,
    Versatile Cp*Rh(III)-Catalyzed Selective ortho-Chlorination of Arenes and Heteroarenes,
    ACS Catal. 2016, 6, 7839-7843. DOI
    2016 Lied Acs Catal 7839
    230) J. H. Kim, S. Greßies, M. Boultadakis-Arapinis, C. Daniliuc, F. Glorius,
    Rh(I)/NHC*-Catalyzed Site- and Enantioselective Functionalization of C(sp3)–H Bonds Toward Chiral Triarylmethanes,
    ACS Catal. 2016, 6, 7652-7656. DOI

    Highlighted in Synfacts 2017, 13, 0061.
    2016 Kim Acs Catal 7652
    229) A. Lerchen, T. Knecht, C. G. Daniliuc, F. Glorius,
    Unnatural Amino Acid Synthesis Enabled by the Regioselective Cobalt(III)-Catalyzed Intermolecular Carboamination of Alkenes,
    Angew. Chem. Int. Ed. 2016, 55, 15166-15170; Angew. Chem. 2016, 128, 15391-15395. DOI
    2016 Lerchen Acie 15166
    228) D. Paul, B. Beiring, M. Plois, N. Ortega, S. Kock, D. Schlüns, J. Neugebauer,* R. Wolf,* F. Glorius,*
    A Cyclometalated Ruthenium-NHC Precatalyst for the Asymmetric Hydrogenation of (Hetero)arenes and Its Activation Pathway,
    Organometallics 2016, 35, 3641-3646. DOI
    2016 Paul Organometallics 3641
    227) X. Wang, T. Gensch, F. Glorius,
    Highly selective synthesis of 6-substituted benzothiophenes by Sc(OTf)3-catalyzed intermolecular cyclization and sulfur migration,
    Org. Chem. Front. 2016, 3, 1619-1623. DOI
    2016 X Wang Orgchemfront Asap
    226) M. N. Hopkinson, A. Tlahuext-Aca, F. Glorius,
    Merging Visible Light Photoredox and Gold Catalysis,
    Acc. Chem. Res. 2016, 49, 2261-2272. DOI
    Published as part of the Accounts of Chemical Research special issue “Photoredox Catalysis in Organic Chemistry
    2016 Hopkinson Accchemres 2261
    225) J. B. Ernst, S. Muratsugu,* F. Wang, M. Tada, F. Glorius,*
    Tunable Heterogeneous Catalysis – N-Heterocyclic Carbenes as Ligands for Supported Heterogeneous Ru/K-Al2O3 Catalysts to Tune Reactivity and Selectivity,
    J. Am. Chem. Soc. 2016, 138, 10718-10721. DOI
    2016 Ernst Jacs 10718
    224) D. Janssen-Müller, S. Singha, T. Olyschläger, C. G. Daniliuc, F. Glorius,
    Annulation of o-Quinodimethanes (o-QDM) through NHC-Catalysis for the Synthesis of 1-Isochromanones,
    Org. Lett. 2016, 18, 4444-4447. DOI
    Highlighted in Synfacts 2016, 12, 1125. DOI
    2016 Janssen Mueller Orglett 4444
    223) D. Zhao, L. Candish, D. Paul, F. Glorius,
    N-Heterocyclic carbenes in asymmetric hydrogenation,
    ACS Catal. 2016,6, 5978-5988. DOI
    2016 Zhao Acs Catal 5978
    222) S. Vásquez-Céspedes, K. M. Chepiga, N. Möller, A. H. Schäfer, F. Glorius,
    Direct C–H Arylation of Heteroarenes with Copper Impregnated on Magnetite as a Reusable Catalyst: Evidence for CuO Nanoparticle Catalysis in Solution,
    ACS Catal. 2016, 6, 5954-5961. DOI
    2016 Vasquez Acs Catal 5954
    221) D. Janssen-Müller, M. Fleige, D. Schlüns, M. Wollenburg, C. G. Daniliuc, J. Neugebauer,* F. Glorius,*
    NHC-Catalyzed Enantioselective Dearomatizing Hydroacylation of Benzofurans and Benzothiophenes for the Synthesis of Spirocycles,
    ACS Catal. 2016, 6, 5735-5739. DOI
    2016 Janssen Mueller Acs Catal 5735
    220) M. Fleige,§ J. Möbus,§ T. vom Stein, F. Glorius, D. W. Stephan,*
    Lewis acid catalysis: catalytic hydroboration of alkynes initiated by Piers' borane,
    Chem. Commun. 2016, 52, 10830-10833. DOI
    § Both authors contributed equally.
    2016 Fleige Chemcommun 10830
    219) A. Tlahuext-Aca, M. N. Hopkinson, C. G. Daniliuc, F. Glorius,
    Oxidative Addition to Gold(I) by Photoredox Catalysis: Straightforward Access to Diverse (C,N)-Cyclometalated Gold(III) Complexes,
    Chem. Eur. J. 2016, 22, 11587-11592. DOI
    Highlighted as very important paper;
    highlighted by ChemistryViews
    .
    2016 Tlahuext Chemeurj 11587

    218) T. Gensch,§ F. J. R. Klauck,§ F. Glorius,
    Cobalt-Catalyzed C−H Thiolation through Dehydrogenative Cross-Coupling,

    Angew. Chem. Int. Ed. 2016, 55, 11287-11291; Angew. Chem. 2016, 128, 11457-11461. DOI
    § Both authors contributed equally.

    2016 Gensch Acie 11287
    217) C. Guo, M. Fleige, D. Janssen-Müller, C. G. Daniliuc, F. Glorius,
    Cooperative N-Heterocyclic Carbene/Palladium-Catalyzed Enantioselective Umpolung Annulations,
    J. Am. Chem. Soc. 2016, 138, 7840-7843. DOI
    2016 Guo Jacs 7840
    216) C. Schlepphorst, B. Maji, F. Glorius,
    Ruthenium-NHC Catalyzed α-Alkylation of Methylene Ketones Provides Branched Products through Borrowing Hydrogen Strategy,
    ACS Catal. 2016, 6, 4184-4188. DOI
    2016 Schlepphorst Acs Catalysis 4184
    215) L. Candish, E. A. Standley, A. Gómez-Suárez, S. Mukherjee, F. Glorius,
    Catalytic Access to Alkyl Bromides, Chlorides and Iodides via Visible Light-Promoted Decarboxylative Halogenation,
    Chem. Eur. J. 2016, 22, 9971-9974. DOI
    2016 Candish Chemeurj 9971
    214) T. Gensch, F. Glorius,
    The straight dope on the scope of chemical reactions,
    Science 2016, 352, 294-295. DOI
    2016 Gensch Science 294
    213) T. Gensch, M. N. Hopkinson, F. Glorius,* J. Wencel-Delord,*
    Mild metal-catalyzed C–H activation: examples and concepts,
    Chem. Soc. Rev. 2016, 45, 2900-2936. DOI
    2016 Gensch Chemsocrev 2900
    212) X. Wang, A. Lerchen, F. Glorius,
    A Comparative Investigation: Group 9 Cp*M(III)-catalyzed Formal [4+2] Cycloaddition as an Atom-economic Approach to Quinazolines,
    Org. Lett. 2016, 18, 2090-2093. DOI
    2016 X Wang Orglett 2090
    211) P. Lara,* L. M. Martínez-Prieto,* M. Roselló-Merino, C. Richter, F. Glorius, S. Conejero, K. Philippot, B. Chaudret, NHC-stabilized Ru nanoparticles: Synthesis and surface studies,
    Nano-Structures & Nano-Objects 2016, 6, 39-45. DOI
    2016 Richter Nanostructures 39
    210) J. H. Kim, S. Greßies, F. Glorius,
    Cooperative Lewis Acid/ Cp*Co(III)-Catalyzed C–H Bond Activation for the Synthesis of Isoquinolin-3-ones,
    Angew. Chem. Int. Ed. 2016, 55, 5577-5581; Angew. Chem. 2016, 128, 5667-5671. DOI
    2016 Kim Acie 5577
    209) A. Rühling, K. Schaepe, L. Rakers, B. Vonhören, P. Tegeder, B. J. Ravoo,* F. Glorius,*
    Modular and bidentate hybrid NHC-thioether ligands for the stabilization of palladium nanoparticles in various solvents,
    Angew. Chem. Int. Ed. 2016, 55, 5856-5860; Angew. Chem. 2016, 128, 5950-5955. DOI
    2016 Ruehling Acie 5856
    208) M. N. Hopkinson, A. Gomez-Suarez, M. Teders, B. Sahoo, F. Glorius,
    Accelerated Discovery in Photocatalysis using a Mechanism-Based Screening Method,
    Angew. Chem. Int. Ed. 2016, 55, 4361-4366; Angew. Chem. 2016, 128, 4434-4439. DOI
    This paper was selected for the Angewandte front cover image of the issue it appears in. Please, enjoy this "Catalyst Speed Dating"!
    Highlighted on the University homepage (WWU);
    Highlighted by IN THE PIPELINE;
    Highlighted by C&E News;
    Highlighted by FORBES;
    Highlighted by Chemie.de;
    Highlighted by Pharmaceutical Processing.

    2016 Hopkinson Acie 4361
    207) Q. Lu, S. Vásquez-Céspedes, T. Gensch, F. Glorius,
    Control over Organometallic Intermediate Enables Cp*Co(III) Catalyzed Switchable Cyclization to Quinolines and Indoles,
    ACS Catal. 2016, 6, 2352-2356. DOI
    2016 Lu Acscatal 2352
    206) A. Tlahuext-Aca, M. N. Hopkinson,§ R. A. Garza-Sanchez,§ F. Glorius,
    Alkyne Difunctionalization by Dual Gold/Photoredox Catalysis,
    Chem. Eur. J. 2016, 22, 5909-5913. DOI
    § Both authors contributed equally.
    2016 Tlahuext Chemeurj 5909
    205) L. M. Martínez-Prieto,§ A. Ferry,§ L. Rakers, C. Richter, P. Lecante, K. Philippot,* B. Chaudret,* F. Glorius,*
    Long-Chain NHC-stabilized RuNPs as Versatile Catalysts for One-pot Oxidation/Hydrogenation Reactions,
    Chem. Commun. 2016,
    52, 4768-4771. DOI
    2016 Ferry Chemcomm 4768
    204) L. Candish,§ L. Pitzer,§ A. Gomez-Suarez, F. Glorius,
    Visible Light-Promoted Decarboxylative Di- and Trifluoromethylthiolation of Alkyl Carboxylic Acids,
    Chem. Eur. J. 2016, 22, 4753-4756. DOI
    § Both authors contributed equally.
    2016 Candish Chemeurj 4753

    203) J. B. Ernst, A. Rühling, B. Wibbeling, F. Glorius,
    Trichloromethylthiolation of N Heterocycles - Practical and Completely Regioselective,
    Chem. Eur. J. 2016, 22, 4400-4404. DOI

    2016 Ernst Chemeurj 4400

    202) R. Honeker, R. A. Garza-Sanchez, M. N. Hopkinson,* F. Glorius,*
    Visible Light-Promoted Trifluoromethylthiolation of Styrenes via Dual Photoredox/Halide Catalysis,
    Chem. Eur. J. 2016, 22, 4395-4399. DOI
    Selected as hot paper by Chemistry - A European Journal;
    Highlighted by ChemistryViews
    .

    2016 Honeker Chemeurj 4395
    201) W. Li, C. Schlepphorst, C. Daniliuc, F. Glorius,
    Asymmetric Hydrogenation of Vinylthioethers: Access to Optically Active 1,5-Benzothiazepine Derivatives,
    Angew. Chem. Int. Ed. 2016, 55, 3300-3303; Angew. Chem. 2016, 128, 3361-3364. DOI
    2016 W Li Acie 3300
    200) A. Lerchen, S. Vásquez-Céspedes, F. Glorius,
    Cobalt(III)-catalyzed redox-neutral synthesis of unprotected indoles featuring an N–N bond cleavage,
    Angew. Chem. Int. Ed. 2016, 55, 3208-3211; Angew. Chem. 2016, 128, 3261-3265. DOI
    2016 Lerchen Acie 3208
    199) A. Tlahuext-Aca§, M. N. Hopkinson§, B. Sahoo, F. Glorius,
    Dual Gold/Photoredox-Catalyzed C(sp)−H Arylation of Terminal Alkynes with Diazonium Salts,
    Chem. Sci. 2016, 7, 89-93. DOI
    § Both authors contributed equally.
    2016 Tlahuext Chemsci 89
  • 2015

    198) D. Wang, C. Richter, A. Rühling, S. Hüwel, F. Glorius,* H.-J. Galla,*
    Anti-tumor activity and cytotoxicity in Vitro of novel 4,5-dialkylimidazolium surfactants,
    Biochem. Biophys. Res. Commun. 2015, 467, 1033-1038. DOI
    2015 D Wang Biochembiophysres 1033
    197) B. Sahoo§, M. N. Hopkinson§, F. Glorius,
    External-Photocatalyst-Free Visible-Light-Mediated Synthesis of Indolizines,
    Angew. Chem. Int. Ed. 2015, 54, 15545-15549; Angew. Chem. 2015, 127, 15766-15770. DOI
    § Both authors contributed equally.
    2015 Sahoo Acie 15545
    196) J. Wencel-Delord,* F. W. Patureau and F. Glorius,
    Rh(III) and Ir(III) catalyzed C-C bond cross couplings from C-H bonds,
    Top. Organomet. Chem. 2015, 55, 1-27. DOI
    2015 Wencel Toporganometchem 1
    195) L. M. Martínez-Prieto, A. Ferry, P. Lara, C. Richter, K. Philippot,* F. Glorius,* B. Chaudret,*
    New Route to Stabilize Ruthenium Nanoparticles with Non-Isolable Chiral N-Heterocyclic Carbenes,
    Chem. Eur. J. 2015, 21, 17495-17502. DOI
    2015 Ferry Chemeurj 17495
    194) A. Ferry,§ K. Schaepe,§ P. Tegeder, C. Richter, K. M. Chepiga, B. J. Ravoo,* F. Glorius,*
    Negatively Charged N-Heterocyclic Carbene-Stabilized Pd and Au Nanoparticles and Efficient Catalysis in Water,
    ACS Catal. 2015, 5, 5414-5420. DOI
    § Both authors contributed equally.
    2015 Ferry Acs Catal 5414
    193) D. Wang,§ C. Richter,§ A. Rühling, P. Drücker, D. Siegmund, N. Metzler-Nolte, F. Glorius,* H.-J. Galla,*
    A remarkably simple class of imidazolium-based lipids and their biological properties,
    Chem. Eur J. 2015, 21, 15123-15126. DOI
    § Both authors contributed equally.

     
    2015 Richter Chemeurj 15123

    192) C. Guo, M. Fleige, D. Janssen-Müller, C. G. Daniliuc, F. Glorius,
    Switchable selectivity in an NHC-catalysed dearomatizing annulation reaction,
    Nature Chem. 2015, 7, 842-847. DOI
    2015 Chang Nchem 842
    191) J. H. Kim, T. Gensch, D. Zhao, L. Stegemann, C. A. Strassert,* F. Glorius,*
    Rh(III)-Catalyzed C-H Activation with Pyridotriazoles: Direct Access to Fluorophores for Metal-Ion Detection,
    Angew. Chem. Int. Ed. 2015, 54, 10975–10979; Angew. Chem. 2015, 127, 11126–11130. DOI

     
    2015 Kim Acie 10975
    190) A. Rühling, H.-J. Galla, F. Glorius,
    A Remarkably Simple Hybrid Surfactant–NHC Ligand, Its Gold-Complex, and Application in Micellar Catalysis,
    Chem. Eur. J. 2015, 21, 12291-12294. DOI
    2015 Ruehling Chemeurj 12291
    189) T. Gensch,§ S. Vásquez-Céspedes,§ D.-G. Yu, F. Glorius,
    Cobalt(III)-Catalyzed Directed C−H Allylation,
    Org. Lett. 2015, 17, 3714-3717. DOI
    § Both authors contributed equally.
    2015 Gensch Orglett 3714
    188) X. Wang,§ D.-G. Yu,§ F. Glorius,
    Cp*Rh(III)-Catalyzed Arylation of sp3 C−H Bonds,
    Angew. Chem. Int. Ed. 2015, 54, 10280-10283;Angew. Chem. 2015, 127, 10419-10422. DOI
    § Both authors contributed equally.
    2015 X Wang Acie 10280
    187) B. Sahoo, J.-L. Li, and F. Glorius,
    Visible Light Photoredox Catalyzed Semipinacol-Type Rearrangement: Trifluoromethylation/Ring Expansion via a Radical-Polar Mechanism,
    Angew. Chem. Int. Ed. 2015, 54, 11577-11580; Angew. Chem. 2015, 127, 11740-11744
    . DOI
    2015 Sahoo Acie 11577

    186) J. Wysocki, C. Schlepphorst, F. Glorius,
    Asymmetric Homogeneous Hydrogenation of 2-Pyridones,
    Synlett 2015, 26, 1557-1562. DOI
    Selected for Synlett Best Paper Award 2015

    2015 Wysocki Synlett 1557
    185) S. Helten, B. Sahoo, P. Müller, D. Janßen-Müller, N. Klein, R. Grünker, V. Bon, F. Glorius, S. Kaskel, I. Senkovska,*
    Functional group tolerance in BTB-based metal–organic frameworks (BTB – benzene-1,3,5-tribenzoate),
    Microporous Mesoporous Mater. 2015, 216, 42-50. DOI
    2015 Sahoo Microporous 42
    184) R. Honeker§, J. B. Ernst§, F. Glorius,
    Transition Metal free Trifluoromethylthiolation of N-Heteroarenes,
    Chem. Eur. J. 2015, 21, 8047-8051. DOI
    § Both authors contributed equally.

    Highlighted in Org. Process Res. Dev. 2016, 20, 707-717.
    2015 Honeker Acie 8047
    183) D. Janssen-Müller, M. Schedler, M. Fleige, C. G. Daniliuc, F. Glorius,
    Enantioselective Intramolecular Hydroacylation of Unactivated Alkenes: An NHC-Catalyzed Robust and Versatile Formation of Cyclic Chiral Ketones,
    Angew. Chem. Int. Ed. 2015, 54, 12492-12496; Angew. Chem. 2015, 127, 12671-12675. DOI
    Highlighted in Synfacts 2015, 11, 0659 as Synfact of the month.

     
    2015 Janssen Mueller Acie 12492
    182) S. Vásquez-Céspedes§, A. Ferry§, L. Candish, F. Glorius,
    Heterogeneously Catalyzed Direct C-H Thiolation of Heteroarenes,
    Angew. Chem. Int. Ed. 2015, 54, 5772-5776; Angew. Chem. 2015, 127, 5864-5868. DOI
    § Both authors contributed equally.
    Selected as hot paper by Angewandte Chemie.
    2015 Vasquez Acie 5772
    181) E.-C. Fritz, C. Nimphius, A. Goez, S. Würtz, M. Peterlechner, J. Neugebauer, F. Glorius,* B. J. Ravoo,*
    Sequential Surface Modification of Au Nanoparticles: From Surface-Bound AgI Complexes to Ag0 Doping,
    Chem. Eur. J. 2015, 21, 4541-4545. DOI
    2015 Nimphius Chemeurj 4541
    180) K. D. Collins,* F. Glorius,*
    Intermolecular Reaction Screening as a Tool for Reaction Evaluation,
    Acc. Chem. Res. 2015, 48, 619-627. DOI
    (invited for a special edition on “Synthesis, Design and Molecular Function” edited by Paul A. Wender)

     
    2015 Collins Accchemres 619
    179) N. Schröder, F. Lied, F. Glorius,
    Dual role of Rh(III)-catalyst enables regioselective halogenation of (electron-rich) heterocycles,
    J. Am. Chem. Soc. 2015, 137, 1448-1451. DOI
    Highlighted in Synfacts 2015, 11, 0366 as Synfact of the month.

     
    2015 Schroeder Jacs 1448
    178) D. Zhao*§, J. H. Kim§, L. Stegemann, C. A. Strassert, F. Glorius,*
    Cobalt(III)-Catalyzed Directed CH Coupling with Diazo Compounds: Straightforward Access towards Extended π-Systems,
    Angew. Chem. Int. Ed. 2015, 54, 4508-4511; Angew. Chem. 2015, 127, 4591-4594. DOI
    § Both authors contributed equally.

     
    2015 Zhao Acie 4508
    177) K. D. Collins, R. Honeker§, S. Vásquez-Céspedes§, D.-T. D. Tang, F. Glorius,
    C–H Arylation of Triphenylene, Naphthalene and Related Arenes using Pd/C,
    Chem. Sci. 2015,
    6, 1816-1824. DOI
    § Both authors contributed equally.

     
    2015 Collins Chemsci 1816
    176) D. Zhao,§ S. Vásquez-Céspedes,§ F. Glorius,
    Rhodium(III)-Catalyzed Cyclative Capture Approach to Diverse 1-Aminoindoline Derivatives at Room Temperature,
    Angew. Chem. Int. Ed. 2015, 54, 1657-1661; Angew. Chem. 2015, 127, 1677-1681. DOI
    § Both authors contributed equally.

     
    2015 Zhao Acie 1657
    175) S. Helten§, B. Sahoo§, V. Bon, I. Senkovska, S. Kaskel,* F. Glorius,*
    Copolymerisation at work: the first example of a highly porous MOF comprising a triarylborane-based linker,
    CrystEngComm 2015, 17, 307-312. DOI
    § Both authors contributed equally.
    2014 Sahoo Crystengcomm
  • 2014

    174) D.-G. Yu, T. Gensch, F. de Azambuja, S. Vásquez-Céspedes, F. Glorius,
    Co(III)-Catalyzed C–H Activation/Formal SN-type Reactions: Selective and Efficient Cyanation, Halogenation and Allylation,
    J. Am. Chem. Soc. 2014, 136, 17722-17725. DOI
    2014 Yu Jacs 17722
    173) C. Guo, B. Sahoo, C. G. Daniliuc, F. Glorius,
    N-Heterocyclic Carbene Catalyzed Switchable Reactions of Enals with Azoalkenes: Formal [4+3] and [4+1] Annulations for the Synthesis of 1,2-Diazepines and Pyrazoles,
    J. Am. Chem. Soc. 2014, 136, 17402-17405. DOI
    Highlighted in Chem. & Eng. News 2014, 92, issue 49, p. 30. LINK    
    Highlighted in JACS Spotlights. LINK
    2014 Guo Jacs 17402

    172) M. N. Hopkinson, B. Sahoo, F. Glorius,
    Dual Photoredox and Gold Catalysis: Intermolecular Multicomponent Oxyarylation of Alkenes,
    Adv. Synth. Catal. 2014, 356, 2794-2800. DOI
    2014 Hopkinson Advsynthcat 2794
    171) K. D. Collins, T. Gensch, F. Glorius,
    Contemporary screening approaches to reaction discovery and development,
    Nat. Chem. 2014, 6, 859–871. DOI
    2014 Collins Natchem 859
    170) J.-L. Li, B. Sahoo, C.-G. Daniliuc, F. Glorius,
    Conjugate Umpolung of β,β-Disubstituted Enals by Dual Catalysis with an N-Heterocyclic Carbene and a Brønsted Acid: Facile Construction of Contiguous Quaternary Stereocenters,
    Angew. Chem. Int. Ed. 2014, 53, 10515-10519; Angew. Chem. 2014, 126, 10683-10687. DOI

     
    2014 Jli Acie 10515
    169) C. Guo, M. Schedler, C. G. Daniliuc, F. Glorius,
    N-Heterocyclic Carbene Catalyzed Formal [3+2] Annulation Reaction of Enals: An Efficient Enantioselective Access to Spiro-Heterocycles,
    Angew. Chem. Int. Ed. 2014, 53, 10232-10236; Angew. Chem. 2014, 126, 10397-10401. DOI
    Highlighted in Synfacts 2014, 10, 1207.
    2014 Guo Acie 10232
    168) M. N. Hopkinson, C. Richter, M. Schedler, F. Glorius,
    An Overview of N-Heterocyclic Carbenes,
    Nature 2014, 510, 485-496. DOI
    2014 Hopkinson Nature 485
    167) D.-G. Yu, F. de Azambuja, T. Gensch, C. G. Daniliuc, F. Glorius,
    The C-H Activation/1,3-Diyne Strategy: Highly Selective Direct Synthesis of Diverse bis-Heterocycles via RhIII-Catalysis,
    Angew. Chem. Int. Ed. 2014, 53, 9650-9654; Angew. Chem. 2014, 126, 9804-9809. DOI
    Highlighted in Synfacts 2014, 10, 1023.
    2014 Yu Acie 9650
    166) D.-G. Yu, F. de Azambuja, F. Glorius,
    Direct Functionalization with Complete and Switchable Positional Control: Free Phenol as A Role Model,
    Angew. Chem. Int. Ed. 2014, 53, 7710-7712; Angew. Chem. 2014, 126, 7842-7845. DOI
    2014 Yu Acie 7710
    165) M. Schedler, N. E. Wurz, C. G. Daniliuc, F. Glorius,
    N-Heterocyclic Carbene Catalyzed Umpolung of Styrenes: Mechanistic Elucidation and Selective Tail-to-Tail Dimerization,
    Org. Lett. 2014, 16, 3134-3137. DOI
    2014 Schedler Orglett 3134 Small
    164) M. Suri, F. Glorius,
    Synthesis of Tetrasubstituted 1H-Pyrazoles by Copper-mediated Coupling of Enaminones with Nitriles,
    Org. Synth. 2014, 91, 211-220.
    2014 Suri Orgsynth
    163) K. D. Collins, F. Lied, F. Glorius,
    Preparation of Conjugated 1,3-Enynes using Rh(III) Catalysed Alkynylation of Alkenes via C-H activation,
    Chem. Commun. 2014, 50, 4459-4461. DOI
    2014 Collins Chemcommun 4459
    162) N. Kuhl, N. Schröder, F. Glorius,
    Formal SN-type reactions in Rh(III)-catalyzed C–H bond activation,
    Adv. Synth. Catal.
    2014, 356, 1443-1460. DOI
    2014 Kuhl Advsynthcatal 1443
    161) D. Zhao, F. Lied, F. Glorius,
    Rh(III)-Catalyzed C-H Functionalization/Aromatization Cascade with 1,3-Dienes: A Redox-Neutral and Regioselective Access to Isoquinolines, Chem. Sci. 2014, 5, 2869-2873. DOI
    2014 Zhao Chemsci 2869
    160) M. Boultadakis-Arapinis, M. N. Hopkinson, F. Glorius,
    Using Rh(III)-Catalyzed C–H Activation as a Tool for the Selective Functionalization of Ketone-Containing Molecules,
    Org. Lett. 2014, 16, 1630-1633. DOI
    >
    2014 Boultadakis Orglett 1630
    159) J. Wysocki, N. Ortega, F. Glorius,
    Asymmetric Hydrogenation of Disubstituted Furans,
    Angew. Chem. Int. Ed. 2014, 53, 8751-8755; Angew. Chem. 2014, 126, 8896-8900. DOI
    Highlighted in Synfacts 2014, 10, 0949.
    2014 Wysocki Acie 8751
    158) C. Richter§, K. Schaepe§, F. Glorius,* B. J. Ravoo,*
    Tailor-made N-Heterocyclic Carbenes for Nanoparticle Stabilization,
    Chem. Commun. 2014, 50, 3204-3207. DOI
    § Both authors contributed equally.
    2014 Richter Chemcommun 3204
    157) K. D. Collins, A. Rühling, F. Glorius,
    Application of a Robustness Screen for the evaluation of synthetic organic methodology,
    Nat. Protoc. 2014, 9, 1348-1353. DOI
    2014 Collins Natprotoc 1348
    156) M. N. Hopkinson§, B. Sahoo§, J.-L. Li, F. Glorius,
    Dual Catalysis sees the Light: Combining Photoredox with Organo-, Acid and Transition Metal Catalysis,
    Chem. Eur. J. 2014, 20, 3874-3886. DOI
    § Both authors contributed equally.
    2014 Hopkinson Chemeurj 3874
    155) D.-G. Yu, F. de Azambuja, F. Glorius,
    α-MsO/TsO/Cl Ketones as Oxidized Alkyne Equivalents: Redox-Neutral Rhodium(III)-Catalyzed C–H Activation for the Synthesis of N-Heterocycles,
    Angew. Chem. Int. Ed. 2014, 53, 2754-2758. DOI
    Highlighted in Synfacts 2014, 10, 567.
    2014 Yu Acie 2754
    154) Z. Shi, M. Boultadakis-Arapinis, D. C. Koester, F. Glorius,
    Rh(III)-Catalyzed intramolecular redox-neutral cyclization of alkenes via C–H activation,
    Chem. Commun. 2014, 50, 2650-2652. DOI
    2014 Shi Chemcomm 2650
    153) D.-T. D. Tang, K. D. Collins, J. B. Ernst, F. Glorius,
    Pd/C as a Catalyst for Completely Regioselective C-H Functionalization of Thiophenes under Mild Conditions,
    Angew. Chem. Int. Ed. 2014, 53, 1809-1813; Angew. Chem. 2014, 126, 1840-1844. DOI
    Highlighted in Synfacts 2014, 10, 0367.
    2014 Tang Acie 1809
    152) K. D. Collins,* A. Rühling, F. Lied, F. Glorius,*
    Rapid Assessment of Protecting Group Stability Using a Robustness Screen,
    Chem. Eur. J. 2014, 20, 3800-3805. DOI
    2014 Collins Chemeurj 3800
  • 2013

    151) T. Dröge, F. Glorius,
    (1S,1"S,2S,2"S,5R,5"R )-5,5"-Dimethyl-2,2" -bis(1-methylethyl)-dispiro[cyclohexane-1,3'(2'H)-imidazo[5,1-b:4,3-b']bisoxazol[4]ium-7'(8' H),1"-cyclohexane]1,1,1-trifluoromethanesulfonate,
    Encyclopedia of Reagents for Organic Synthesis (e-Eros) 2013. DOI
    2013 Droege Encyclopedia
    150) D. Zhao, Z. Shi, F. Glorius,
    Indole Synthesis by Rhodium(III)-Catalyzed Hydrazine-Directed C-H Activation: Redox-Neutral and Traceless by N-N Bond Cleavage,
    Angew. Chem. Int. Ed. 2013, 52, 12426-12429; Angew. Chem. 2013, 125, 12652-12656. DOI
    2013 Zhao Acie 12426
    149) H. Wang, B. Beiring, D.-G. Yu, K. Collins, F. Glorius,
    [3]Dendralene Synthesis: Rhodium(III)-Catalyzed Alkenyl C–H Activation and Coupling Reaction with Allenyl Carbinol Carbonate,
    Angew. Chem. Int. Ed. 2013, 52, 12430-12434; Angew. Chem. 2013, 125, 12657-12661. DOI
    2013 Wang Acie 12430
    148) D. Zhao§, C. Nimphius§, M. Lindale, F. Glorius,
    Phosphoryl-Related Directing Groups in Rhodium(III) Catalysis: A General Strategy to Diverse P-Containing Frameworks,
    Org. Lett. 2013, 15, 4504-4507. DOI
    § Both authors contributed equally.
    2013 Zhao Orglett 4504
    147) Z. Shi, D. C. Koester, M. Boultadakis-Arapinis, F. Glorius,
    Rh(III)-Catalyzed Synthesis of Multisubstituted Isoquinoline and Pyridine N-Oxides from Oximes and Diazo Compounds,
    J. Am. Chem. Soc. 2013, 135, 12204-12207. DOI
    2013 Shi Jacs 12204 Small
    146) N. Kuhl§, N. Schröder§, F. Glorius,
    Rh(III)-Catalyzed Halogenation of Vinylic C–H Bonds: Rapid and General Access to Z-Halo Acrylamides,
    Org. Lett. 2013, 15, 3860-3863. DOI
    § Both authors contributed equally.
    2013 Kuhl Orglett 3860
    145) D. Zhao, F. Glorius,
    Enantioselective Hydrogenation of Isoquinolines,
    Angew. Chem. Int. Ed. 2013, 52, 9616-9618; Angew. Chem. 2013, 125, 9794-9796. DOI
    2013 Zhao Acie 9616
    144) K. D. Collins, F. Glorius,
    A Robustness Screen for the Rapid Assessment of Chemical Reactions,
    Nature Chem. 2013, 5, 597-601. DOI
    Highlighted in Nature Chem. 2013, 5, 554 - News & Views.
    Highlighted in Nachrichten aus der Chemie 2013, 61, 867.
    Highlighted in Nature Methods 2013, 10, 699. DOI
    Highlighted by the FACULTY of 1000 (F1000Prime). LINK

    2013 Collins Naturechem 597
    143) D.-G. Yu§, M. Suri§, F. Glorius,
    RhIII/CuII-Cocatalyzed Synthesis of 1H-indazoles through C–H Amidation and N–N Bond Formation,
    J. Am. Chem. Soc. 2013, 135, 8802-8805. DOI
    § Both authors contributed equally.
    2013 Yu Jacs 8802
    142) D.-T. D. Tang, K. Collins, F. Glorius,
    Completely Regioselective Direct C–H Functionalization of Benzo[b]thiophenes Using a Simple Heterogeneous Catalyst,
    J. Am. Chem. Soc. 2013, 135, 7450–7453. DOI
    Highlighted in Nature 2013, 498, 275 - Research Highlights.
    Highlighted in Synfacts 2013, 9, 0908.
    Highlighted in ChemCatChem 2013, early view. DOI
    Highlighted in Today's Science September 2013. Link
    2013 Tang Jacs 7450
    141) Z. Shi, M. Boultadakis-Arapinis, F. Glorius,
    Rh(III)-Catalyzed Dehyrogenative Alkylation of (Hetero)Arenes with Allylic Alcohols, Allowing an Aldol Condensation to Indenes,
    Chem. Commun. 2013, 49, 6489-6491. DOI
    2013 Shi Chemcomm 6489
    140) N. Ortega, D.-T. D. Tang, S. Urban, D. Zhao, F. Glorius,
    Ruthenium-NHC Catalyzed Asymmetric Hydrogenation of Indolizines: Access to Indolizidine Alkaloids,
    Angew. Chem. Int. Ed. 2013, 52, 9500-9503; Angew. Chem. 2013, 125, 9678-9681. DOI
    Highlighted in Synfacts 2013, 9, 1183.
    Highlighted in Organic Chemistry Highlights 2014, November 17.
    2013 Ortega Acie 9500
    139) D. Zhao, B. Beiring, F. Glorius,
    Ruthenium-NHC Catalyzed Asymmetric Hydrogenation of Flavones and Chromones: General Access to Enantio-enriched Flavanones, Flavanols, Chromanones and Chromanols,
    Angew. Chem. Int. Ed. 2013, 52, 8454-8458; Angew. Chem. 2013, 125, 8612-8616. DOI
    Highlighted in Synfacts 2013, 9, 1184.
    2013 Zhao Acie 8454
    138) C. Grohmann, H. Wang, F. Glorius,
    Rh[III]-catalyzed C-H Amidation using Aroyloxycarbamates to give N-Boc protected Arylamines,
    Org. Lett. 2013, 15, 3014-3017. DOI
    2013 Grohmann Orglett 3014
    137) K. D. Collins, F. Glorius,
    Employing a Robustness Screen: Rapid Assessment of Rhodium(III)-catalysed C-H Activation Reactions,
    Tetrahedron 2013, 69, 7817-7825. DOI
    2013 Collins Tetrahedron 7817
    136) B. Sahoo, M. N. Hopkinson, F. Glorius,
    Combining Gold and Photoredox Catalysis: Visible Light-Mediated Oxy- and Aminoarylation of Alkenes,
    J. Am. Chem. Soc. 2013, 135, 5505–5508. DOI
    Highlighted in Nachrichten aus der Chemie 2013, 61, 620.
    2013 Sahoo Jacs 5505
    135) Z. Shi, C. Grohmann, F. Glorius,
    Mild Rh(III)-Catalyzed Cyclization of Amides with a,ß-Unsaturated Aldehydes and Ketones to Azepinones:  Application to the Synthesis of the Homoprotoberberine Framework,
    Angew. Chem. Int. Ed. 2013, 52, 5393-5397; Angew. Chem. 2013, 125, 5503-5507. DOI
    Highlighted in Synfacts 2013, 9, 0828.
    2013 Shi Acie 5393
    134) Z. Shi§, M. Suri§, F. Glorius,
    Aerobic Synthesis of Pyrroles and Dihydropyrroles from Imines: Palladium(II)-Catalyzed Intramolecular C-H Dehydrogenative Cyclization,
    Angew. Chem. Int. Ed. 2013, 52, 4892–4896; 
    Angew. Chem. 2013, 52, 4992–4996. DOI
    § Both authors contributed equally.
    2013 Shi Acie 4892
    133) N. Ortega, C. Richter, F. Glorius,
    N-Formylation of Amines by Methanol Activation,
    Org. Lett. 2013, 15, 1776–1779. DOI
    2013 Ortega Orglett 1776
    132) J. Wencel-Delord,* F. Glorius,*
    C–H bond activation enables the rapid construction and late-stage diversification of functional molecules,
    Nature Chem. 2013, 5, 369–375. DOI
    2013 Wencel Natchem 369
    131) H. Wang, N. Schröder, F. Glorius,
    Mild Rh(III)-Catalyzed Direct C-H Allylation of Arenes with Allyl Carbonates,
    Angew. Chem. Int. Ed. 2013, 52, 5386-5389; Angew. Chem. 2013, 125, 5495-5499. DOI
    2013 Wang Acie 5386
    130) J. Hyvl,* D. Agrawal, R. Pohl, M. Suri, F. Glorius, D. Schröder,
    Electrospray Ionization Mass Spectrometry Reveals an Unexpected Coupling Product in the Copper-Promoted Synthesis of Pyrazoles,
    Organometallics 2013, 32, 807-816. DOI
    2103 Suri Organometallics 807
    129) G. Nickerl, A. Notzon, M. Heitbaum, I. Senkovska, F. Glorius,* S. Kaskel,*
    Selective Adsorption Properties of Cationic Metal–Organic Frameworks Based on Imidazolic Linker,
    Cryst. Growth Des. 2013, 13, 198–203. DOI
    2013 Notzon Cryst Growth Des 198
    128) M. Schedler, D.-S. Wang, F. Glorius,
    NHC-Catalyzed Hydroacylation of Styrenes,
    Angew. Chem. Int. Ed. 2013, 52, 2585-2589; Angew. Chem. 2013, 125, 2645-2649. DOI
    Selected as hot paper by Angewandte Chemie.
    Highlighted in Synfacts 2013, 9, 0437.

    2013 Schedler Acie 2585
    127) F. W. Patureau, T. Besset, F. Glorius, checked by T. Harada, T. Fukuyama,
    Preparation of (E)-N,N-Diethyl-2-styrylbenzamide by Rh-catalyzed C-H activation,
    Org. Synth. 2013, 90, 41-51. Link
    2013 Patureau Org Synth
    126) Z. Shi, F. Glorius,
    Synthesis of Fluorenones via Quaternary Ammonium Salt-Promoted Intramolecular Dehydrogenative Arylation of Aldehydes,
    Chem. Sci. 2013, 4, 829-833. DOI
    Highlighted in Synform 2013, 6, A71-A73. DOI
    2013 Shi Chem Sci 829
  • 2012

    125) H. Wang, C. Grohmann, C. Nimphius, F. Glorius,
    Mild Rhodium(III)-Catalyzed C–H Activation and Annulation with Alkyne MIDA Boronates: Short and Efficient Synthesis of Heterocyclic Boronic Acid Derivatives,
    J. Am. Chem. Soc. 2012, 134, 19592–19595. DOI
    Highlighted in Synfacts 2013, 9, 0261.
    2012 Hwang Jacs 19592
    124) C. Grohmann, T. Hashimoto, R. Fröhlich, Y. Ohki,* K. Tatsumi,* F. Glorius,*
    An Iron(II) Complex of Diamine-Bridged Bis-N-Heterocyclic Carbene,
    Organometallics 2012, 31, 8047–8050. DOI
    2012 Grohmann Organomet 8047
    123) H. Wang,* F. Glorius,*
    Lending Handedness to the Cyclopentadienyl Ligand,
    Science 2012, 338, 479-480. DOI
    2012 Hwang Science 479
    122) N. E. Wurz, C. G. Daniliuc, F. Glorius,
    Highly Enantioselective Intermolecular Stetter Reaction of Simple Acrylates – Synthesis of α-Chiral γ-Ketoesters,
    Chem. Eur. J. 2012, 18, 16297–16301. DOI
    2012 Wurz Chemeurj 16297
    121) J. Wencel-Delord§, C. Nimphius§, H. Wang, F. Glorius,
    Rhodium(III) and Hexabromobenzene – A Catalyst System for the Cross-Dehydrogenative Coupling of Simple Arenes and Heterocycles with Arenes Bearing Directing Groups,
    Angew. Chem. Int. Ed. 2012, 51, 13001–13005; Angew. Chem. 2012, 124, 13175-13180. DOI
    § These authors contributed equally.
    2012 Wencel Acie 13001
    120) S. Urban,§ B. Beiring,§N. Ortega, D. Paul, F. Glorius,
    Asymmetric Hydrogenation of Thiophenes and Benzothiophenes,
    J. Am. Chem. Soc. 2012, 134, 15241-15244. DOI
    § These authors contributed equally.
    Highlighted in Synfacts 2012, 8, 1327.
    2012 Urban Jacs 15241
    119) I. Piel, J. V. Dickschat, T. Pape, F. E. Hahn,* F. Glorius,*
    A planar chiral [2.2]paracyclophane derived N-heterocyclic stannylene,
    Dalton Trans. 2012, 41, 13788-13790. DOI
    2012 Piel Daltontrans 13788
    118) H. C. Hoffmann, S. Paasch, P. Müller, I. Senkovska, M. Padmanaban, F. Glorius, S. Kaskel, E. Brunner,*
    Chiral Recognition in Metal-Organic Frameworks Studied by Solid-State NMR Spectroscopy Using Chiral Solvating Agents,
    Chem. Commun. 2012, 48, 10484-10486. DOI
    2012 Padmanaban Chemcommun 10484
    117) F. W. Patureau,* J. Wencel-Delord, F. Glorius,*
    Cp*Rh-Catalyzed C–H Activations: Versatile Dehydrogenative Cross-Couplings of Csp2 C–H Positions with Olefins, Alkynes, and Arenes,
    Aldrichimica Acta 2012, 45, 31-41. Link
    2012 Patureau Aldrichimica 31
    116) F. W. Patureau,* T. Besset, R. Fröhlich, F. Glorius,*
    On the selectivity in some Rh(III) catalyzed C-H activation cross-couplings;
    De la sélectivité dans des réactions d'hétéro-couplage par C-H activation catalysées au Rh(III),

    C. R. Chim. 2012, 15, 1081-1085. DOI
    2012 Patureau Crchim 1081
    115) Z. Shi, F. Glorius,
    Efficient and Versatile Indole Synthesis from Enamines and Imines via Cross-Dehydrogenative Coupling,
    Angew. Chem. Int. Ed. 2012, 51, 9220-9222; Angew. Chem. 2012, 124, 9354-9356. DOI
    2012 Shi Acie 9220
    114) K. Nagura, S. Saito, R. Fröhlich, F. Glorius,* S. Yamaguchi,*
    N-Heterocyclic Carbene Borane as an Electron Donating and Accepting Component of π-Conjugated Systems,
    Angew. Chem. Int. Ed. 2012, 51, 7762-7766; Angew. Chem. 2012, 124, 7882-7886. DOI
    2012 Nagura Acie 7762
    113) N. Kuhl, M. N. Hopkinson, J. Wencel-Delord, F. Glorius,
    Beyond Directing Groups: Transition Metal-Catalyzed C H Activation of Simple Arenes,
    Angew. Chem. Int. Ed. 2012, 51, 10236-10254; Angew. Chem. 2012, 124, 10382-10401. DOI
    2012 Kuhl Acie 10236
    112) C. Lohre, C. Nimphius, M. Steinmetz, S. Würtz, R. Fröhlich, C. G. Daniliuc, S. Grimme, F. Glorius,
    Investigation of the complexation behavior and catalysis of IBiox-[(-)-menthyl]·HOTf,
    Tetrahedron 2012, 68, 7636-7644. DOI
    2012 Lohre Tetrahedron 7636
    111) N. Kuhl, M. N. Hopkinson, F. Glorius,
    Selective Rh(III)-Catalyzed Cross-Dehydrogenative Coupling of Furan and Thiophene Derivatives,
    Angew. Chem. Int. Ed. 2012, 51, 8230-8234; Angew. Chem. 2012, 124, 8354-8358. DOI
    2012 Kuhl Acie 8230
    110) M. Suri, T. Jousseaume, J. J. Neumann, F. Glorius,
    An efficient copper-catalyzed formation of highly substituted pyrazoles using molecular oxygen as the oxidant,
    Green Chem. 2012, 14, 2193-2196. DOI
    2012 Suri Greenchem 2193
    109) Z. Shi, N. Schröder, F. Glorius,
    Rh[III]-Catalyzed Dehydrogenative Heck Reaction (DHR) of Salicylaldehydes,
    Angew. Chem. Int. Ed. 2012, 51, 8092-8096; Angew. Chem. 2012, 124, 8216-8220.DOI
    Highlighted in Synfacts 2012, 8, 1211.

    2012 Shi Acie 8092
    108) T. Hashimoto, S. Urban, R. Hoshino, Y. Ohki,* K. Tatsumi,* F. Glorius,*
    Synthesis of Bis(N-heterocyclic carbene) Complexes of Iron(II) and Their Application in Hydrosilylation and Transfer Hydrogenation,
    Organometallics 2012, 31, 4474-4479. DOI
    2012 Hashimoto Organometallics 4474
    107) M. Schedler, R. Fröhlich, C. G. Daniliuc, F. Glorius,
    2,6-Dimethoxyphenyl-substituted N-heterocyclic carbenes (NHCs): a new family of highly electron-rich organocatalysts,
    Eur. J. Org. Chem. 2012, 4164-4171. DOI
    2012 Schedler Eurjoc 4164
    106) N. Schröder,§ J. Wencel-Delord,§ F. Glorius,
    High Yielding, Versatile and Practical [Rh(III)Cp*]-Catalyzed ortho-Bromination and Iodination of Arenes,
    J. Am. Chem. Soc. 2012, 134, 8298-8301. DOI
    § Both authors contributed equally to this work.
    2012 Schroeder Jacs 8298
    105) N. Ortega, B. Beiring, S. Urban, F. Glorius,
    Highly asymmetric synthesis of (+)-corsifuran A. Elucidation of the electronic requirements in the Ruthenium–NHC catalyzed hydrogenation of benzofurans,
    Tetrahedron 2012, 68, 5185-5192.DOI
    2012 Ortega Tetrahedron 5185
    104) H. Wang, F. Glorius,
    Mild Rh(III)-Catalyzed C-H Activation of Aromatic Amide Derivatives and Intermolecular Annulation with Allenes: Efficient Synthesis of 3,4-Dihydroisoquinolin-1(2H)-ones,
    Angew. Chem. Int. Ed. 2012,51, 7318-7322; Angew. Chem. 2012, 124, 7430-7434. DOI
    Selected as hot paper by Angewandte Chemie.
    2012 Hwang Acie 7318
    103) X. Bugaut,* F. Glorius,*
    Organocatalytic Umpolung: N-Heterocyclic Carbenes and Beyond,
    Chem. Soc. Rev. 2012, 41, 3511-3522. DOI
    2012 Bugaut Chemsocrev 3511
    102) J. Wencel-Delord, C. Nimphius, F. W. Patureau, F. Glorius,
    Undirected C-H Bond Activation of Arenes: [Rh(III)Cp*]-Catalyzed Dehydrogenative Alkene-Arene Coupling as New Pathway for the Selective Synthesis of Highly Substituted Z-Olefins,
    Chem. Asian J. 2012, 7, 1208-1212. DOI
    (Special issue celebrating 150 years of German-Japanese relations)
    2012 Wencel Chemasianj 1208
    101) J. Wencel-Delord, C. Nimphius, F. W. Patureau, F. Glorius,
    [Rh(III)Cp*]-Catalyzed Dehydrogenative Aryl-Aryl Bond Formation,
    Angew. Chem. Int. Ed. 2012, 51, 2247-2251; Angew. Chem. 2012, 124, 2290-2294. DOI
    Selected as hot paper by Angewandte Chemie.
    2012 Wencel Acie 2247
    100) N. Ortega, S. Urban, B. Beiring F. Glorius,
    Ruthenium-NHC Catalyzed Highly Asymmetric Hydrogenation of Benzofurans,
    Angew. Chem. Int. Ed. 2012, 51, 1710-1713; Angew. Chem. 2012, 124, 1742-1745. DOI
    Selected as hot paper by Angewandte Chemie.
    Highlighted in Synfacts 2012, 8, 519.
    2012 Ortega Acie 1710
    99) C. Grohmann, H. Wang, F. Glorius,
    Rh[III]-Catalyzed Direct C–H Amination Using N-Chloroamines at Room Temperature,
    Org. Lett. 2012, 14, 656-659. DOI
    2012 Grohmann Orglett 656
    98) N. Schröder, T. Besset, F. Glorius,
    Synthesis of Olefin-Oxazoline-Ligands (OlefOx) by Rhodium(III)-Catalyzed Oxidative Olefination,
    Adv. Synth. Catal.
    2012, 354, 579-583. DOI
    2012 Schroeder Advsynthcat 579
    97) C. Richter, K. V. S. Ranganath, F. Glorius,
    Enantioselective α-Arylation of Cyclic Ketones Catalyzed by a Combination of an Unmodified Cinchona Alkaloid and a Palladium Complex,
    Adv. Synth. Catal. 2012, 354, 377-382. DOI
    Highlighted in Synfacts 2012, 8, 520.
    2012 Richter Advsynthcat 377
  • 2011

    96) F. W. Patureau, C. Nimphius, F. Glorius,
    Rh Catalyzed C–H Activation and Oxidative Olefination without Chelate Assistance: On the Reactivity of Bromoarenes,
    Org. Lett. 2011, 13, 6346-6349. DOI
    2011 Patureau Orglett 6346
    95) F. Liu, X. Bugaut, M. Schedler, R. Fröhlich, F. Glorius,
    Designing N-Heterocyclic Carbenes: Simultaneous Enhancement of Reactivity and Enantioselectivity in the Asymmetric Hydroacylation of Cyclopropenes,
    Angew. Chem. Int. Ed. 2011, 50, 12626-12630;Angew. Chem. 2011, 123, 12834-12838. DOI
    2011 Liu Acie 12626
    94) M. Padmanaban, P. Müller, C. Lieder, K. Gedrich, R. Grünker, V. Bon, I. Senkovska, S. Baumgärtner, S. Opelt, S. Paasch, E. Brunner, F. Glorius,* E. Klemm,* S. Kaskel,*
    Application of a Chiral Metal–organic Framework in Enantioselective Separation,
    Chem. Commun. 2011, 47, 12089-12091. Advance Article. DOI
    2011 Padmanaban Chemcommun 12089
    93) M. Padmanaban, A. T. Biju, F. Glorius,
    Efficient Synthesis of Benzofuranones: N-Heterocyclic Carbene (NHC)/Base-Catalyzed Hydroacylation–Stetter–Rearrangement Cascade,
    Org. Lett. 2011, 13, 5624-5627. DOI
    2011 Padmanaban Orglett 5624
    92) T. Dröge§, A. Notzon§, R. Fröhlich, F. Glorius,
    Palladium-catalyzed C-H bond Functionalization of a MOF: Mild, Selective and Efficient,
    Chem. Eur. J. 2011, 17, 11974-11977. DOI
    § Both authors contributed equally to this work. This paper we would like to highlight, since it represents the first metal-catalyzed C-H functionalization of a MOF. Please, check it out!
    2011 Droege Chemeurj 11974
    91) K. V. S. Ranganath, A. Schäfer, F. Glorius,
    Comparison of Superparamagnetic Fe3O4 Supported N-Heterocyclic carbene (NHC) Based Catalysts for Enantioselective Allylation,
    ChemCatChem 2011, 3,1889-1891. DOI
    2011 Ranganath Chemcatchem 1889
    90) A. T. Biju, M. Padmanaban, N. E. Wurz, F. Glorius,
    N-Heterocyclic Carbene (NHC)-Catalyzed Umpolung of Michael Acceptors for Intermolecular Reactions,
    Angew. Chem. Int. Ed. 2011, 50, 8412-8415; Angew. Chem. 2011, 123, 8562-8565. DOI
    2011 Biju Acie 8412

    89) A. T. Biju, N. Kuhl, F. Glorius,
    Extending NHC-Catalysis: Coupling Aldehydes with Unconventional Reaction Partners,
    Acc. Chem. Res. 2011, 44, 1182-1195. DOI
    2011 Biju Accchemres 1182
    88) I. Piel,§ M. D. Pawelczyk,§ K. Hirano, R. Fröhlich, F. Glorius,
    A Family of Thiazolium Salt Derived N-Heterocyclic Carbenes (NHCs) for Organocatalysis: Synthesis, Investigation and Application in Cross-Benzoin Condensation,
    Eur. J. Org. Chem. 2011, 5475-5484. DOI
    § Both authors contributed equally to this work.
    2011 Piel Eurjoc 5475
    87) X. Bugaut, F. Glorius,
    Palladium-Catalyzed Selective Dehydrogenative Cross-Coupling of Heteroarenes,
    Angew. Chem. Int. Ed. 2011, 50, 7479-7481; Angew. Chem. 2011, 123, 7618-7620. DOI
    2011 Bugaut Acie 7479
    86) J. Wencel-Delord, T. Dröge, F. Liu, F. Glorius,
    Towards Mild Metal-Catalyzed C-H Bond Activation,
    Chem. Soc. Rev. 2011, 40, 4740-4761. DOI
    2011 Wencel Chemsocrec 4740
    85) T. Besset, N. Kuhl, F. W. Patureau, F. Glorius,
    RhIII-Catalyzed Oxidative Olefination of Vinylic C-H Bonds: Efficient and Selective Access to Di-unsaturated α-Amino Acid Derivatives and other Linear 1,3-Butadienes,
    Chem. Eur. J. 2011,17, 7167-7171. DOI
    2011 Besset Chemeurj 7167
    84) J. Willwacher, S. Rakshit, F. Glorius,
    Investigating N-Methoxy-N’-Aryl Ureas in Oxidative C-H Olefination Reactions: An Unexpected Oxidation Behaviour,
    Org. Biomol. Chem. 2011, 9, 4736-4740. DOI
    2011 Willwacher Orgbiomolchem 4736
    83) K. Hirano,* I. Piel, F. Glorius,*
    Dual Activation in NHC-Organocatalysis,
    Chem. Lett. 2011, 40, 786-791. DOI
    2011 Hirano Chemlett 786
    82) X. Bugaut, F. Liu, F. Glorius,
    N-Heterocyclic Carbene (NHC)-Catalyzed Intermolecular Hydroacylation of Cyclopropenes,
    J. Am. Chem. Soc. 2011, 133, 8130-8133. DOI
    Highlighted in Synfacts 2011, 8, 902.
    2011 Bugaut Jacs 8130
    81) C. Lohre, T. Dröge, C. Wang, F. Glorius,
    Nickel-catalyzed Cross-Coupling of Aryl Bromides with Tertiary Grignard Reagents Utilizing Donor-functionalized N-Heterocyclic Carbenes (NHCs),
    Chem. Eur. J. 2011, 17, 6052-6055. DOI
    2011 Lohre Chemeurj 6052
    80) J. J. Neumann, S. Rakshit, T. Dröge, S. Würtz, F. Glorius,
    Exploring the Oxidative Cyclization of Substituted N-Aryl Enamines: Pd-catalyzed Formation of Indoles from Anilines,
    Chem. Eur. J. 2011, 17, 7298-7303.DOI
    Highlighted in Synfacts 2011, 8, 829.
    2011 Neumann Chemeurj 7298
    79) I. Piel, M. Steinmetz, K. Hirano, R. Fröhlich, S. Grimme,* F. Glorius,*
    Highly Asymmetric NHC-Catalyzed Hydroacylation of Unactivated Alkenes,
    Angew. Chem. Int. Ed. 2011, 50, 4983-4987; Angew. Chem. 2011, 123, 5087-5091. DOI
    Selected as very important paper (VIP) by Angewandte Chemie.
    Highlighted in Synfacts 2011, 7, 789.
    2011 Piel Acie 4983
    78) M. Rose, A. Notzon, M. Heitbaum, G. Nickerl, S. Paasch, E. Brunner, F. Glorius,* S. Kaskel,*
    N-Heterocyclic carbene containing element organic frameworks as heterogeneous organocatalysts,
    Chem. Commun. 2011, 47, 4814-4816. DOI
    2011 Rose Chemcommun 4814
    77) Y. Loewer, C. Weiss, A. T. Biju, R. Fröhlich, F. Glorius,
    Synthesis and Application of a Chiral Diborate,
    J. Org. Chem. 2011, 76, 2324-2327. DOI
    2011 Loewer Joc 2324
    76) S. Rakshit, C. Grohmann, T. Besset, F. Glorius,
    Rh[III]-Catalyzed Directed C-H Olefination Using an Internal Oxidant: Mild, Efficient and Versatile,
    J. Am. Chem. Soc. 2011, 133, 2350-2353. DOI
    2011 Rakshit Jacs 2350
    75) S. Urban, N. Ortega, F. Glorius,
    Ligand-Controlled Highly Regioselective and Asymmetric Hydrogenation of Quinoxalines Catalyzed by Ruthenium N-Heterocyclic Carbene Complexes,
    Angew. Chem. Int. Ed. 2011, 50, 3803-3806; Angew. Chem. 2011, 123, 3887-3890. DOI
    Selected as hot paper by Angewandte Chemie.
    Highlighted in Synfacts 2011, 6, 633.
    2011 Urban Acie 3803
    74) F. W. Patureau, T. Besset, N. Kuhl, F. Glorius,
    Diverse Strategies Towards Indenol and Fulvene Derivatives: Rh-catalyzed C-H Activation of Aryl Ketones Followed by Coupling With Internal Alkynes,
    J. Am. Chem. Soc. 2011, 133, 2154-2156.DOI
    2011 Patureau Jacs 2154
    73) F. W. Patureau,* F. Glorius,*
    Oxidizing Directing Groups Enabling Efficient and Innovative C-H Activation Reactions,
    Angew. Chem. Int. Ed. 2011, 50, 1977-1979; Angew. Chem. 2011, 123, 2021-2023. DOI
    2011 Patureau Acie 1977
    72) K. V. S. Ranganath, F. Glorius,
    Superparamagnetic Nanoparticles for Asymmetric Catalysis – A Perfect Match,
    Catalysis Science & Technology 2011, 1, 13-22 (inaugural issue). DOI
    2011 Ranganath Catscitech 13
    71) T. Jousseaume, N. E. Wurz, F. Glorius,
    Highly Enantioselective Synthesis of α-Amino Acid Derivatives by an N-Heterocyclic Carbene (NHC)-catalyzed Intermolecular Stetter Reaction,
    Angew. Chem. Int. Ed. 2011, 50, 1410-1414; Angew. Chem. 2011, 123, 1446-1450. DOI
    Highlighted twice in Synfacts 2011, 4, 446 (Methodology) and in Synfacts 2011, 5, 466 (Synthesis of Potential Drug).
    2011 Jousseaume Acie 1410
    70) F. W. Patureau, T. Besset, F. Glorius,
    Rhodium Catalyzed Oxidative Olefination of C-H Bonds in Acetophenones and Benzamides,
    Angew. Chem. Int. Ed. 2011, 50, 1064-1067; Angew. Chem. 2011, 123, 1096-1099. DOI
    2011 Patureau Acie 1064
    69) M. Padmanaban, A. T. Biju, F. Glorius,
    N-Heterocyclic Carbene-Catalyzed Cross-Coupling of Aromatic Aldehydes with Activated Alkyl Halides,
    Org. Lett. 2011, 13, 98-101. DOI
    Highlighted in Synfacts 2011, 2, 209.
    2011 Padmanaban Orglett 98
    68) N. Kuhl, F. Glorius,
    Direct and Efficient N-Heterocyclic Carbene-catalyzed Hydroxymethylation of Aldehydes,
    Chem. Commun. 2011, 47, 573-575. DOI
    Invited to and part of the "Emerging Investigators" issue of Chemical Communications.
    2011 Kuhl Chemcommun 573
    67) K. Gedrich, M. Heitbaum, A. Notzon, I. Senkovska, R. Fröhlich, J. Getzschmann, U. Mueller, F. Glorius,* S. Kaskel*,
    A New Family of Chiral Metal-Organic Frameworks,
    Chem. Eur. J. 2011, 17, 2099-2106. DOI
    2011 Heitbaum Chemeurj 2099
  • 2010

    66) A. T. Biju, F. Glorius,
    Intermolecular N-Heterocyclic Carbene-catalyzed Hydroacylation of Arynes,
    Angew. Chem. Int. Ed. 2010, 49, 9761-9764; Angew. Chem. 2010, 122, 9955-9958.DOI
    Selected as hot paper by Angewandte Chemie.
    Highlighted in Synfacts 2011, 1, 95.
    2010 Biju Acie 9761
    65) J. V. Dickschat, S. Urban, T. Pape, F. Glorius,* F. E. Hahn,*
    Sterically Demanding and Chiral N,N'-Disubstituted N-Heterocyclic Germylenes and Stannylenes,
    Dalton Trans. 2010, 39, 11519-11521. DOI
    2010 Dickschat Daltontrans 11519
    64) C. Wang,* S. Rakshit, F. Glorius,*
    Palladium-catalyzed Intermolecular Decarboxylative Coupling of 2-Phenylbenzoic Acids with Alkynes via C-H and C-C Bond Activation,
    J. Am. Chem. Soc. 2010, 120, 14006-14008. DOI
    Highlighted in Synfacts 2011, 2, 201.
    2010 C. Wang Jacs 14006
    63) J. J. Neumann, M. Suri, F. Glorius,
    Efficient Synthesis of Pyrazoles: Oxidative C-C/N-N Bond Formation Cascade,
    Angew. Chem. Int. Ed. 2010, 49, 7790-7794; Angew. Chem. 2010, 122, 7957-7961. DOI
    2010 Neumann Acie 7790
    62) K. V. S. Ranganath, J. Kloesges, A. H. Schäfer, F. Glorius,
    Asymmetric Nanocatalysis: N-Heterocyclic Carbenes as Chiral Modifiers of Fe3O4/Pd Nanoparticles,
    Angew. Chem. Int. Ed. 2010, 49, 7786-7789; Angew. Chem. 2010, 122, 7952-7956.DOI
    Highlighted in Synfacts 2011, 1, 109.
    2010 Ranganath Acie 7786
    61) F. W. Patureau, F. Glorius,
    Rh Catalyzed Olefination and Vinylation of Unactivated Acetanilides,
    J. Am. Chem. Soc.
    2010, 132, 9982-9983. DOI
    2010 Patureau Jacs 9982
    60) S. Rakshit, F. W. Patureau, F. Glorius,
    Pyrrole Synthesis via Allylic sp3 C-H Activation of Enamines Followed by Intermolecular Coupling with Unactivated Alkynes,
    J. Am. Chem. Soc. 2010, 132, 9585-9587. DOI
    Highlighted in Synfacts 2010, 6, 716.
    2010 Rakshit Jacs 9585
    59) T. Dröge, F. Glorius,
    The Measure of All Rings - N-Heterocyclic Carbenes,
    Angew. Chem. Int. Ed. 2010, 49, 6940-6952;Angew. Chem. 2010, 122, 7094-7107. DOI
    2010 Droege Acie 6940
    58) A. T. Biju, N. E. Wurz, F. Glorius,
    N-Heterocyclic Carbene-Catalyzed Cascade Reaction Involving the Hydroacylation of Unactivated Alkynes,
    J. Am. Chem. Soc. 2010, 132, 5970-5971. DOI
    Highlighted in Synfacts 2010, 6, 716.
    2010 Biju Jacs 5970
    57) B. T. Hahn, F. Tewes, R. Fröhlich, F. Glorius,
    Olefin-oxazolines (OlefOx) - Highly Modular, Easily Tunable Ligands for Asymmetric Catalysis,
    Angew. Chem. Int. Ed. 2010, 122, 1143-1146; Angew. Chem. 2010,49, 1161-1164. DOI
    Selected as hot paper by Angewandte Chemie.
    2010 Hahn Acie 1143
    56) T. Dröge, F. Glorius,
    NHC - Ligand der Ideen,
    Nachrichten aus der Chemie 2010, 58, 112-117. DOI
    The publication was selected for the cover picture of the corresponding issue.
    55) F. Glorius,
    Stereochemistry by Remote Control (News & Views),
    Nature Chem. 2010, 2, 78-80. DOI
    54) M. Heitbaum, R. Fröhlich, F. Glorius,
    Diastereoselective Hydrogenation of Substituted Quinolines to Enantiomerically Pure Decahydroquinolines,
    Adv. Synth. Catal. 2010, 352, 357-362. DOI
    Highlighted in Synfacts 2010, 05, 572.
  • 2009

    53) K. Hirano, A. T. Biju, F. Glorius,
    Copper-Catalyzed Synthesis of 2-Unsubstituted, N-Substituted Benzimidazoles,
    J. Org. Chem. 2009, 74, 9570-9572. DOI

    52) K. Hirano, A. T. Biju, I. Piel, F. Glorius,
    N-Heterocyclic Carbene-Catalyzed Hydroacylation of Unactivated Double Bonds,
    J. Am. Chem. Soc. 2009, 131, 14190. DOI
    Highlighted in Synfacts 2009, 12, 1404.

    51) A. T. Biju, K. Hirano, R. Fröhlich, F. Glorius,
    Switching the Electron-Donor Properties of N-Heterocyclic Carbenes by a Facile Deprotonation Strategy,
    Chem. Asian J. 2009, 4, 1786-1789. DOI

    50) F. Glorius, J. J. Neumann,
    Handbook of Green Chemistry - Green Catalysis (Book review),

    Angew. Chem. Int. Ed. 2009, 48, 7120-7121; Angew. Chem. 2009, 121, 7256-7257. DOI

    49) J. J. Neumann, S. Rakshit, T. Dröge, F. Glorius,
    Pd-Catalyzed Amidation of Unactivated sp3 C-H Bonds: from Anilines to Indolines,

    Angew. Chem. Int. Ed. 2009, 48, 6892-6895; Angew. Chem. 2009, 121, 7024-7027. DOI
    Selected as hot paper by Angewandte Chemie.

    48) S. Urban, M. Tursky, R. Fröhlich, F. Glorius,
    Investigation of the properties of 4,5-dialkylated N-heterocyclic carbenes,
    Dalton Trans.
    2009, 6934-6940. DOI

    47) S. Würtz, C. Lohre, R. Fröhlich, K. Bergander, F. Glorius,
    IBiox[(-)-menthyl] – a Sterically Demanding Chiral NHC Ligand,
    J. Am. Chem. Soc.
    2009, 131, 8344-8345. DOI
    Highlighted in Synfacts 2009, 9, 1011.

    46) C. Wang, F. Glorius,
    Controlled Iterative Cross-couplings: On the Way to the Automation of Organic Synthesis,
    Angew. Chemie Int. Ed. 2009, 48, 5240-5244, Angew. Chem. 2009, 121, 5342-5346. DOI

    45) C. Wang, I. Piel, F. Glorius,
    Palladium-catalyzed Intramolecular Direct Arylation of Benzoic Acids by Tandem Decarboxylation/C-H Activation,
    J. Am. Chem. Soc. 2009, 131, 4194-4195. DOI

    44) K. Hirano, S. Urban, C. Wang, F. Glorius,
    A Modular Synthesis of Highly Substituted Imidazolium Salts,
    Org. Lett. 2009, 11, 1019-1022. DOI

    43) H. Richter, H. Schwertfeger, P. R. Schreiner,* R. Fröhlich, F. Glorius,*
    Synthesis of Diamantane Derived N-Heterocyclic Carbenes (IDAd) and Applications in Catalysis,
    Synlett 2009, 193-197.

  • 2008

    42) B. T. Hahn, R. Fröhlich, K. Harms, F. Glorius,
    First Proline-catalyzed Highly Enantio- and anti-Selective Mannich Reaction of Unactivated Ketones - Synthesis of Chiral α-Amino Acids,

    Angew. Chem. Int. Ed. 2008, 47, 9985-9988; Angew. Chem. 2008, 120, 10134-10137. DOI
    Highlighted in Synfacts 2009, 2, 213.

    41) R. Lebeuf, K. Hirano, F. Glorius,
    Palladium catalyzed C-Allylation of Benzoins & an NHC-catalyzed Three Component Coupling Derived Thereof - Compatibility of NHC- and Pd-Catalysts,
    Org. Lett.
    2008, 10, 4243-4246. DOI

    40) F. Glorius,
    Asymmetric Cross-Coupling of Non-Activated Secondary Alkyl Halides,

    Angew. Chem. Int. Ed. 2008, 47, 8347-8349; Angew. Chem. 2008, 120, 8474-8476. DOI

    39) S. Würtz, S. Rakshit, J. J. Neumann, T. Dröge, F. Glorius,
    Palladium-Catalyzed Oxidative Cyclization of N-Aryl Enamines: From Anilines to Indoles,

    Angew. Chem. Int. Ed. 2008, 47, 7230-7233; Angew. Chem. 2008, 120, 7340-7343. DOI
    Selected as hot paper by Angewandte Chemie.

    38) B. Hahn, K. Schwekendiek, F. Glorius,
    Efficient Oxidative Synthesis of (-)-2-tert-butyl-(4S)-benzyl-(1,3)-oxazoline,
    Org. Synth. 2008, 85, 267-277. DOI

    37) C. Lohre, R. Fröhlich, F. Glorius,
    Thiazole-annelated Imidazolium Salts: A New Architecture for N-Hetereocyclic Carbenes,
    Synthesis 2008, 2221-2228. DOI

    36) F. Glorius, K. Hirano,
    Nucleophilic Carbenes as Organocatalysts,
    Ernst Schering Foundation Symposium Proceedings
    2008, Vol. 2, 159-181. DOI

    35) S. Würtz, F. Glorius,
    Surveying Sterically Demanding N-Heterocyclic Carbene Ligands with Restricted Flexibility for Palladium-catalyzed Cross-Coupling Reactions,
    Acc. Chem. Res. 2008, 41, 1523-1533. DOI

    34) K. Hirano, I. Piel, F. Glorius,
    Diastereoselective Synthesis of Trifluoromethylated γ-Butyrolactones via N-Heterocyclic Carbene-catalyzed Conjugated Umpolung of a,ß-unsaturated Aldehydes,
    Adv. Synth. Catal. 2008, 350, 984-988. DOI

  • 2007

    33) F. Tewes, A. Schlecker, K. Harms, F. Glorius,
    Carbohydrate-Containing N-Heterocyclic Carbene Complexes,
    J. Organomet. Chem. 2007, 692, 4593-4602. DOI

    32) K. Schuh (nee Müller), F. Glorius,
    A Domino Copper-Catalyzed C-N-/C-O-Coupling Process for the Synthesis of Oxazoles,
    Synthesis 2007, 2297-2306. DOI

    31) X. Xie, S Tschan, F. Glorius,
    Determination of the Stereochemistry of γ-Butyrolactones by DPFGSE-NOE Experiments,
    Magn. Reson. Chem. 2007, 45, 381-388. DOI

    30) W. Schrader, P. P. Handayani, C. Burstein, F. Glorius,
    Investigating Organocatalytic Reactions: Mass Spectrometric Studies of a Conjugate Umpolung Reaction,
    Chem. Commun.
    2007, 716-718. DOI

    F. Glorius (Editor),
    N-Heterocyclic Carbenes in Transition-Metal Catalysis,
    Topics in Organometallic Chemistry
    , Springer 2007. DOI

    29) F. Glorius,
    N-Heterocyclic Carbenes in Transition-Metal Catalysis,
    in Topics in Organometallic Chemistry, pp. 1-20, Springer 2007. DOI

    28) I. Escher, F. Glorius,
    Product Class 7: Polyenales,
    Science of Synthesis
    2007, 25, 711-731.

    27) I. Escher, F. Glorius,
    Product Class 8: a,ß-unsaturated Aldehydes,
    Science of Synthesis
    2007, 25, 733-777.

  • before 2007

    2006

    26) K. Schwekendiek, F. Glorius,
    Efficient Oxidative Synthesis of 2-Oxazolines,
    Synthesis
    2006, 2996-3002. DOI

    25) G. Altenhoff, S. Würtz, F. Glorius,
    The First Palladium-catalyzed Sonogashira Coupling of Unactivated Secondary Alkyl Bromides,
    Tetrahedron Lett. 2006, 47, 2925-2928. DOI

    24) C. Burstein, S. Tschan, X. Xie, F. Glorius,
    N-Heterocyclic Carbene-Catalyzed Conjugate Umpolung for the Synthesis of γ-Butyrolactones (feature article),
    Synthesis 2006, 2418-2439. DOI

    23) Y. Gnas, F. Glorius,
    Chiral Auxiliaries - Principles and Recent Applications,
    Synthesis
    2006, 1899-1930. DOI

    22) M. Heitbaum, F. Glorius, I. Escher,
    Asymmetric Heterogeneous Catalysis,

    Angew. Chem. Int. Ed. 2006, 45, 4732-4762; Angew. Chem. 2006, 118, 4850-4881. DOI

    2005

    21) F. Glorius,
    Metal-Catalyzed Cross-Coupling Reactions (Book review),
    Angew. Chem. Int. Ed. 2005, 44, 1157; Angew. Chem. 2005, 117, 1181. DOI

    20) C. Burstein, F. Glorius,
    Asymmetric Organocatalysis (Book review),
    Angew. Chem. 2005, 117, 4357-4358. DOI

    19) D. A. Evans, F. Glorius, J. D. Burch,
    Complex Aldol Reactions for the Construction of Dense Polyol Stereoarrays: Synthesis of the C33-C36 Region of Aflastatin A,
    Org. Lett.
    2005, 7, 3331-3333. DOI

    18) F. Glorius,
    Asymmetric Hydrogenation of Heteroaromatic Compounds,
    Org. Biomol. Chem.
    2005, 3, 4171-4175. DOI

    17) C. Burstein, C. W. Lehmann, F. Glorius,
    Imidazo[1,5-a]pyridine-3-ylidenes - Pyridine Derived N-Heterocyclic Carbene Ligands,
    Tetrahedron 2005, 61, 6207-6217. DOI

    2004

    16) F.Glorius,  G. Altenhoff, 
    14. International Symposium on Homogeneous Catalysis (ISHC) (conference report),
    Nachr. Chem. Tech. 2004 , 52, 948.

    15) F. Glorius,
    Chiral Reagents for Asymmetric Synthesis (Book review),
    Angew. Chem. Int. Ed. 2004, 43, 1619-1620; Angew. Chem. 2004, 116, 1647-1648. DOI

    14) F. Glorius, N. Spielkamp, S. Holle, R. Goddard, C. W. Lehmann,
    Efficient Asymmetric Hydrogenation of Pyridines,
    Angew. Chem. Int. Ed.
    2004, 43, 2850-2852; Angew. Chem. 2004, 116, 2910-2912. DOI
    The publication was selected for the cover picture of the corresponding issue.

    13) F. Glorius,
    Chiral Olefin Ligands - New "Spectators" in Asymmetric Catalysis (Highlight),
    Angew. Chem. Int. Ed. 2004, 43, 3364-3366; Angew. Chem. 2004, 116, 3444-3446. DOI

    12) B. Scheiper, F. Glorius, A. Leitner, A. Fürstner,
    Catalysis-Based Enantioselective Total Synthesis of the Macrocyclic Spermidine Alkaloid Isooncinotine,
    Proc. Natl. Acad. Sci. USA
    2004, 101, 11960-11965. DOI

    11) G. Altenhoff, F. Glorius,
    A Domino Copper-Catalyzed C-N-/C-O-coupling for the Conversion of Primary Amides into Benzoxazoles,
    Adv. Synth. Catal.
    2004, 346, 1661-1664. DOI

    10) G. Altenhoff, R. Goddard, C. W. Lehmann, F. Glorius,
    Sterically Demanding, Bioxazoline Derived N-Heterocyclic Carbene Ligands with Restricted Flexibility for Catalysis,
    J. Am. Chem. Soc. 2004, 126, 15195-15201. DOI

    9) F. Glorius, C. Burstein,
    Conjugate Umpolung of a,ß-Unsaturated Aldehydes for the Synthesis of γ-Butyrolactones,
    Angew. Chem. Int. Ed. 2004, 43, 6205-6208; Angew. Chem. 2004, 116, 6331-6334. DOI

    2003

    8) G. Altenhoff, R. Goddard, C. W. Lehmann, F. Glorius,
    An N-Heterocyclic Carbene Ligand with Flexible Steric Bulk Allows Suzuki Cross-Coupling of Sterically Hindered Aryl Chlorides at Room Temperature,
    Angew. Chem. Int. Ed. 2003, 42, 3690-3693; Angew. Chem. 2003, 115, 3818-3821. DOI  
    *See:
    Highlight on adaptable ligands: K. Burgess, Chemistry & Industry 2003, 32 (17th November). See also: Highlight on Rational Ligand Design for the Suzuki-Miyaura-Coupling: M. Miura, Angew. Chem. Int. Ed. 2004, 43, 2201; Angew. Chem. 2004, 116, 2251.

    7) F. Glorius,
    Palladium-Catalyzed Heck-Type Reaction of 2-Chloro Acetamides With Olefins,
    Tetrahedron Lett.
    2003, 44, 5751-5754. DOI

    2002

    6) F. Glorius, G. Altenhoff, R. Goddard, C. W. Lehmann,
    Oxazolines as Chiral Building Blocks for Imidazolium Salts and N-heterocyclic Carbene Ligands,
    Chem. Commun. 2002, 2704-2705. DOI

    2001

    5) F. Glorius, M. Neuburger, A. Pfaltz,
    Highly Enantio- and Regioselective Allylic Alkylations Catalyzed by Chiral [Bis(dihydrooxazole)]molybdenum Complexes,
    Helv. Chim. Acta
    2001, 84, 3178-3196. DOI

    1999

    4) U. Wörsdörfer, F. Vögtle, M. Nieger, M. Waletzke, S. Grimme, F. Glorius, A. Pfaltz,
    A New Planar Chiral Bipyridine Ligand,
    Synthesis
    1999, 597-602. DOI

    3) U. Wörsdörfer, F. Vögtle, F. Glorius, A. Pfaltz,
    A New Planar Chiral Bipyridine Ligand: Pyrid-2-yl[2](1,4)benzeno[2](5,8)quinolino-phane,
    J. Prakt. Chem.
    1999, 341, 445-448. DOI

    2) F. Glorius, A. Pfaltz,
    Enantioselective Molybdenum-Catalyzed Allylic Alkylation Using Chiral Bisoxazoline Ligands,
    Org. Lett. 1999, 1, 141-144. DOI

    1) P. A. Wender, F. Glorius, C. O. Husfeld, E. Langkopf, J. A. Love,
    Transition Metal-Catalyzed [5+2] Cycloadditions of Allenes and Vinylcyclopropanes: First Studies of Endo-Exo Selectivity, Chemoselectivity, Relative Stereochemistry, and Chirality Transfer,
    J. Am. Chem. Soc.
    1999, 121, 5348-5349. DOI