2024

149. Probing the Origin of Affinity in the GM1-Cholera Toxin Complex through Site-selective Editing with Fluorine
C. Jordan^§, T. Hayashi^§, A. Löbbert, J. Fan, C. S. Teschers, K. Siebold, M. Aufiero, F. Pape, E. Campbell, A. Axer, K. Bussmann, K. Bergander, J. Köhnke, A. D. Gossert and R. Gilmour, ACS Cent. Sci. 2024, 10, 1481–1489.

_{Highlighted in ACS Central Science: https://pubs.acs.org/doi/10.1021/acscentsci.4c01206}

148. Regioselective Fluorination of Allenes Enabled by I(I)/I(III) Catalysis
Z.-X. Wang, Y. Xu and R. Gilmour, Nature Communications 2024, 15, 5770.

147. A Fluorinated Sialic Acid Vaccine Lead Against Meningitis B and C
C. Jordan^§, K. Siebold^§, P. Priegue^§, P. H. Seeberger and R. Gilmour, J. Am. Chem. Soc. 2024, 146, 15366–15375.

146. Regio- and Stereo-Selective Isomerization of Borylated 1,3-Dienes Enabled by Selective Energy Transfer Catalysis
B. Kweon, L. Blank, J. Soika, A. Messara, C. G. Daniliuc and R. Gilmour, Angew. Chem. Int. Ed. 2024, e202404233.

145. Catalytic Ring Expanding Difluorination: An Enantioselective Platform to Access β,β-Difluorinated Carbocycles
L. Ruyet, C. Roblick, J. Häfliger, Z.-X. Wang, T. J. Stoffels, C. G. Daniliuc and R. Gilmour, Angew. Chem. Int. Ed. 2024, e202403957.

2023

144. Para-Selective Dearomatization of Phenols by I(I)/I(III) Catalysis-Based Fluorination
T. Stünkel, K. Siebold, D. Okumatsu, K. Murata, L. Ruyet, C. G. Daniliuc and R. Gilmour, Chem. Sci. 2023, 14, 13574 - 13580.

143. Regioselective, catalytic 1,1-difluorination of enynes
Z.-X. Wang, K. Livingstone, C. Hümpel, C. G. Daniliuc, C. Mück-Lichtenfeld and R. Gilmour, Nature Chemistry 2023, 10.1038/s41557-023-01344-5.

_{Highlighted by the University of Münster: https://www.uni-muenster.de/news/view.php?cmdid=13638
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142. Light Enabled Deracemization of Cyclopropanes by Al Salen Photocatalysis
C. Onneken, T. Morack, J. Soika, O. Sokolova, N. Niemeyer, C. Mück-Lichtenfeld, C. G. Daniliuc, J. Neugebauer and R. Gilmour, Nature 2023, 621, 753-759.

_{Highlighted as Synfact of the month by M. Lautens and A. Torelli: Synfacts 2023, 19, 1099. DOI: 10.1055/s-0042-1752274. https://www.thieme-connect.com/products/ejournals/html/10.1055/s-0042-1752274?device=mobile&innerWidth=980&offsetWidth=980
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Highlighted by Nature Asia: http://www.natureasia.com/ko-kr/nature/highlights/122927}

141. Integrating I(I)/I(III) Catalysis in Reaction Cascade Design Enables the Synthesis of gem-Difluorinated Tetralins from Cyclobutanols
J. Häfliger, L. Ruyet, N. Stübke, C. G. Daniliuc and R. Gilmour, Nature Communications 2023, 14, 3207.

140. Direct Observation of Triplet States in the Isomerization of Alkenylboronates by Energy Transfer Catalysis
T. J. B. Zähringer, M. Wienhold, R. Gilmour and C. Kerzig, J. Am. Chem. Soc. 2023, 145, 21576-21586.

_{Highlighted in Synfacts: B. List, K. Kryvous, Synfacts 2023, 19, 0819.}

139. Forging Medium Rings via I(I)/I(III)-Catalyzed Diene Carbofunctionalization
Y.-J. Yu, J. Häfliger, Z.-X. Wang, C. G. Daniliuc and R. Gilmour, Angew. Chem. Int. Ed. 2023, e202309789.
_{Open access}

138. Geometric Isomerisation of Bifunctional Vinyl Fluoride Linchpins: Stereodivergence in Amide and Polyene Bioisostere Synthesis
M. Wienhold, B. Kweon, C. McLaughlin, M Schmitz, T. J. B. Zähringer, C. G. Daniliuc, C. Kerzig and R. Gilmour, Angew. Chem. Int. Ed. 2023, e202304150.
_{Hot Paper
Open acces}

137. Fluorinated Carbohydrates for ¹⁸F-Positron Emission Tomography (PET)
E. Campbell, C. Jordan and R. Gilmour, Chem. Soc. Rev. 2023, 52, 3599-3626.
_{Artwork featured on the front cover}

136. Catalytic, Regioselective 1,4-Fluorodifunctionalization of Dienes
Y.-J. Yu, M. Schäfer, C. G. Daniliuc and R. Gilmour, Angew. Chem. Int. Ed. 2023, 62, e202214906.
_{Highlighted in Synfacts: B. List, M. M. Poje, Synfacts 2023, 19, 0185.
Open access}

135. Fluorine-Directed Automated Mannoside Assembly
C. Teschers and R. Gilmour, Angew. Chem. Int. Ed. 2023, 135 e202213304. DOI numbers 10.1002/anie.202213304 and 10.1002/ange.202213304.
Press release: https://www.uni-muenster.de/news/view.php?cmdid=13047&lang=en
_{Open access}

134. Fluorocyclisation of Oximes to Isoxazolines via I(I)/I(III) Catalysis
J. Neufeld, C. G. Daniliuc and R. Gilmour, Helv. Chim. Acta 2023, e202200183.
_{Invited contribution for the special issue dedicated to the memory of the late Prof. Dr. Jack D. Dunitz FRS
Open access}

2022

133. Skeletal Ring Contractions via I(I)/I(III) Catalysis: Stereoselective Synthesis of cis-α,α-Difluorocyclopropanes
K. Livingstone, K. Siebold, S. Meyer, V. Martín-Heras, C. G. Daniliuc, and R. Gilmour, ACS Catal. 2022, 12, 14507–14516.
_{Open access}

132. Organophotocatalytic N–O Bond Cleavage of Weinreb Amides: Mechanism-Guided Evolution of a PET to ConPET Platform
J. Soika, C. McLaughlin, T. Neveselý, C. G. Daniliuc, J. J. Molloy and R. Gilmour, ACS Catal. 2022, 12, 10047-10056.

Previously ChemRxiv 2022, DOI: 10.26434/chemrxiv-2022-0fz0p
_{Highlighted in Org. Proc. Res. Dev.: https://pubs.acs.org/doi/pdf/10.1021/acs.oprd.2c00309}

131. Cyclopropene Activation via I(I)/I(III) Catalysis: Proof of Principle and Application in Direct Tetrafluorination
S. Meyer, L. Göbel, K. Livingstone, C. Roblick, C. G. Daniliuc and R. Gilmour, Tetrahedron 2022, 132925.
_{open access
Invited contribution for the special edition dedicated to Prof. Dr. F. Schoenebeck.}

130. Stereocontrolled Synthesis of Fluorinated Isochromans via Iodine(I)/Iodine(III) Catalysis
J. Häfliger, O. O. Sokolova, M. Lenz, C. G. Daniliuc and R. Gilmour, Angew. Chem. Int. Ed. 2022, e202205277. DOI:10.1002/anie.202205277 and 10.1002/ange.202205277.
_{Selected as HOT PAPER}

129. Regio- and Enantioselective Intermolecular Aminofluorination of Alkenes via Iodine(I)/Iodine(III) Catalysis
M. Schäfer, T. Stünkel, C. G. Daniliuc and R. Gilmour, Angew. Chem. Int. Ed. 2022, e202205508. DOI numbers 10.1002/anie.202205508 and 10.1002/ange.202205508
_{Selected as HOT PAPER}

Previously ChemRxiv 2022 DOI: 10.26434/chemrxiv-2022-jnslk

128. Advances in the E → Z Isomerization of Alkenes using Small Molecule Photocatalysts
T. Neveselý, M. Wienhold, J. J. Molloy and R. Gilmour, Chem. Rev. 2022, 122, 2650-2694.
_{Invited contribution for the thematic issue Photochemical Catalytic Processes.}

127. Leveraging the n→π* Interaction in Alkene Isomerisation by Selective Energy Transfer Catalysis
T. Neveselý, J. J. Molloy, C. McLaughlin, L. Brüss, C. G. Daniliuc and R. Gilmour, Angew. Chem. Int. Ed. 2022, 61, e202113600.

126. Leveraging fluorine (stereoelectronic) effects in catalysis in The Chemistry of Organofluorine Compounds
J. Neufeld, K. Livingstone and R. Gilmour, in The Chemistry of Organofluorine Compounds, Patai´s Chemistry of Functional Groups (2022) (Eds. I. Marek, V. Gouverneur, M. Gandelman), Wiley-VCH Verlag GmbH & Co, Weinheim.
 

2021

125. Enantiodivergent Prenylation via Deconjugative Isomerization
T. Morack, C. Onneken, H. Nakakohara, C. Mück-Lichtenfeld and R. Gilmour, ACS Catal. 2021, 11, 11929–11937.

124. Illuminating Anti-Hydrozirconation: Controlled Geometric Isomerization of an Organometallic Species
T. Hostmann, T. Nevesely and R. Gilmour, Chem. Sci. 2021, 12, 10643 - 10648.

123. Expanding Organofluorine Chemical Space: The Design of Chiral Fluorinated Isosteres Enabled by I(I)/I(III) Catalysis
S. Meyer, J. Häfliger and R. Gilmour, Chem. Sci. 2021, 12, 10686 - 10695
_{Part of the themed collection 2021 Chemical Science HOT article Collection.}

122. An I(I)/I(III) Catalysis Route to the Heptafluoroisopropyl Group: A Privileged Module in Contemporary Agrochemistry
V. Martín-Heras, C. G. Daniliuc and R. Gilmour, Synthesis 2021, 53, 4203-4212.
_{Invited contribution for the special edition in honour of Prof. Sarah Reisman}

^{SYNTHESIS Best paper Award 2021}

121. Emerging Fluorinated Motifs: Synthesis, Properties, and Applications (book review)
J. Neufeld and R. Gilmour, Angew. Chem. Int. Ed. 2021, 60, 20592-20593.

120. Difluorination of α-(bromomethyl)styrenes via I(I)/I(III) catalysis: facile access to electrophilic linchpins for drug discovery
J. Häfliger, K. Livingstone, C. G. Daniliuc and R. Gilmour, Chem. Sci. 2021, 12, 6148–6152.

119. Trifluorinated Tetralins via I(I)/I(III)-Catalysed Ring Expansion: Programming Conformation by [CH₂CH₂] → [CF₂CHF] Isosterism
J. Neufeld, T. Stünkel, C. Mück-Lichtenfeld, C. G. Daniliuc and R. Gilmour, Angew. Chem. Int. Ed. 2021, 60, 13647-13651.

118. Oligodendroglial Glycolipids in (Re) Myelination: Implications for Multiple Sclerosis Research
L. Nowack, C. S. Teschers, S. Albrecht, R. Gilmour, Nat. Prod. Rep. 2021, 38, 890-904.
DOI: 10.1039/D0NP00093K.
_{Artwork featured on the front cover.}

117. A Chiral, Pentafluorinated Isopropyl Group via Iodine(I)/(III) Catalysis
S. Meyer, J. Häfliger, M. Schäfer, J. J. Molloy, C. G. Daniliuc, and R. Gilmour, Angew. Chem. Int. Ed. 2021, 60, 6430-6434.
_{Highlighted in Synfacts: B. List, D. Díaz-Oviedo, Synfacts 2021, 17, 0443.}

116. Coumarins by Direct Annulation: β-Borylacrylates as Ambiphilic C3-Synthons
M. Wienhold, J. J. Molloy, C. G. Daniliuc and R. Gilmour, Angew. Chem. Int. Ed. 2021, 60, 685-689.
_{Highlighted in Synfacts: P. Knochel, D. Djukanovic, Synfacts 2020, 16, 1444.}

115. Enhancing Glycan Stability via Site-Selective Fluorination: Modulating Substrate Orientation by Molecular Design
A. Axer, R. P. Jumde, S. Adam, A. Faust, M. Schäfers, M. Fobker, J. Koehnke, A. K. H. Hirsch and R. Gilmour, Chem. Sci. 2021, 12, 1286-1294.
_{First posted on Chemrxiv 2020, DOI:10.26434/chemrxiv.12656210.
Highlighted as a "hot article" by Chemical Science.}

2020

114. Boron-enabled geometric isomerization of alkenes via selective energy-transfer catalysis J. J. Molloy, M. Schäfer, M. Wienhold, T. Morack, C. G. Daniliuc and R. Gilmour, Science 2020, 369, 302-306. Abstract      Reprint     Full text Highlighted in Synform: https://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0039-1691232.pdf Highlighted by TCI America: https://www.tcichemicals.com/US/en/product/tci-topics/ProductHighlights_20200831 Highlighted in Synfacts: https://www.thieme-connect.de/products/ejournals/abstract/10.1055/s-0040-1707376 Highlighted in EurekAlert! AAAS: https://www.eurekalert.org/pub_releases/2020-07/uom-rsa071620.php Highlighted in ScienMag: https://scienmag.com/researchers-solve-a-long-standing-problem-in-organic-chemistry/ Highlighted in Phys.Org: https://phys.org/news/2020-07-chemists-bioinspired-strategy-synthesis-polyenes.html Highlighted in News Beezer: https://newsbeezer.com/chemists-are-developing-a-bio-inspired-strategy-for-the-controlled-synthesis-of-polyenes/ Highlighted in idw - News: https://idw-online.de/de/news751330 Highlighted by the WWU Münster: https://www.uni-muenster.de/news/view.php?cmdid=1114 Highlighted by the Cells in Motion Interfaculty Center at the WWU Münster: https://www.uni-muenster.de/Cells-in-Motion/de/ Highlighted in Bioengineer.org: https://bioengineer.org/researchers-solve-a-long-standing-problem-in-organic-chemistry/ Highlighted in innovations report: https://www.innovations-report.de/html/berichte/biowissenschaften-chemie/forscher-loesen-langjaehriges-raetsel-der-organischen-chemie-entwicklung-eines-bioinspirierten-wegs-polyene-zu-formen.html Highlighted in Laboratory Equipment: https://www.laboratoryequipment.com/566344-Researchers-Solve-a-Long-standing-Problem-in-Organic-Chemistry/ Highlighted in ChemEurope: https://www.chemeurope.com/en/news/1167248/long-standing-problem-in-organic-chemistry-solved.html?pk_campaign=ca0066&WT.mc_id=ca0066 Highlighted in SciTechDaily: https://scitechdaily.com/long-standing-problem-in-organic-chemistry-finally-solved-by-researchers/ Highlighted in Infosurhoy: https://infosurhoy.com/science/long-standing-problem-in-organic-chemistry-finally-solved-by-researchers/ Highlighted in ScienceDaily: https://www.sciencedaily.com/releases/2020/07/200716163041.htm Highlighted in NewsCollective: https://newscollective.co.nz/chemists-develop-bioinspired-strategy-for-the-controlled-synthesis-of-polyenes-phys-org/ Highlighted in WorldNewsEra: https://worldnewsera.com/news/science/long-standing-problem-in-organic-chemistry-finally-solved-by-researchers/   First posted on Chemrxiv 2020, DOI:10.26434/chemrxiv.11982486.

113. Cooperative Activation Modes for Catalysis-Based Total Synthesis S. Meyer and R. Gilmour, Trends Chem. 2020, 2, 959-961.

112. Flow Photocleavage for Automated Glycan Assembly (AGA) C. S. Teschers and R. Gilmour, Org. Process Res. Dev. 2020, 10, 2234–2239. Part of the special edition “Flow Chemistry Enabling Efficient Synthesis”

111. Conformational Analysis of Acyclic α-Fluoro Sulfur Motifs N. Erdeljac, C. Mück-Lichtenfeld, C. G. Daniliuc and R. Gilmour, Chem. Eur. J. 2020, 26, 13704-13715.

110. Fluorohydration of Alkynes via I(I)/I(III)-Catalysis J. Neufeld, C. G. Daniliuc and R. Gilmour, Beilstein J. Org. Chem. 2020, 16, 1627-1635. Invited contribution for the special edition on organofluorine chemistry

109. Total Chemical Syntheses of the GM3 and F-GM3 Ganglioside Epitopes and Comparative Pre-Clinical Evaluation for Non-Invasive Imaging of Oligodendrocyte Differentiation T. J. Kieser, N. Santschi, L. Nowack, A. Axer, G. Kehr, S. Albrecht and R. Gilmour, ACS Chem. Neurosci. 2020, 11, 2129-2136.

108. Validating the 1,2-Difluoro (BITE) Motif as a Hybrid Bioisostere of CF3 and Et using Matrix Metalloproteases as Structural Probes N. Erdeljac, C. Thiehoff, R. Jumde, C. Daniliuc, S. Hoeppner, A. Faust, A. Hirsch and R. Gilmour, J. Med. Chem. 2020, 63, 6225-6237.

107. Enantioselective Synthesis of 3-Fluorochromanes via I(I)/I(III) Catalysis J. C. Sarie, C. Thiehoff, J. Neufeld, C. G. Daniliuc and R. Gilmour, Angew. Chem. Int. Ed. 2020, 59, 15069-15075. Highlighted by ChemViews: https://www.chemistryviews.org/details/ezine/11253871/Enantioselective_3-Fluorochromane_Synthesis.html Selected as a VIP paper

106. Contra-Thermodynamic E→Z Isomerization of Cinnamamides via Selective Energy Transfer Catalysis M. R. Becker, T. Morack, J. Robertson, J. B. Metternich, C. Mück-Lichtenfeld, C. Daniliuc, G A. Burley and R. Gilmour, Tetrahedron 2020, 76, 131198. Invited contribution

105. Halogen-Directed Chemical Sialylation: Pseudo-Stereodivergent Access to Marine Ganglioside Epitopes T. Hayashi, A. Axer, G. Kehr, K. Bergander and R. Gilmour, Chem. Sci. 2020, 11, 6527-6531.

104. Inverting External Asymmetric Induction via Selective Energy Transfer Catalysis: A Strategy to β-Chiral Phosphonate Antipodes C. Onneken, K. Bussmann and R. Gilmour, Angew. Chem. 2020, 132, 338-342; Angew. Chem. Int. Ed. 2020, 59, 330-334.

2019

103. Light-Enabled Enantiodivergence: Stereospecific Reduction of Activated Alkenes using a Single Organocatalyst Enantiomer T. Hostmann, J. J. Molloy, K. Bussmann and R. Gilmour, Org. Lett. 2019, 21, 10164-10168.

102. Sequential Energy Transfer Catalysis: A Cascade Synthesis of Angularly-Fused Dihydrocoumarins T. Neveselý, C. G. Daniliuc and R. Gilmour, Org. Lett. 2019, 21, 9724-9728.

101. Photocatalytic E→Z Isomerization of β-Ionyl Derivatives K. Livingstone, M. Tenberge, F. Pape, C. G. Daniliuc, C. Jamieson and R. Gilmour, Org. Lett. 2019, 21, 9677-9680.

100. Geometric E→Z Isomerisation of Vinyl Silanes by Selective Energy Transfer Catalysis: Stereodivergent Synthesis of Triarylethylenes via a Formal Anti-Metallometallation S. I. Faßbender, J. J. Molloy, C. Mück-Lichtenfeld and R. Gilmour, Angew. Chem. 2019, 131, 18792-18799; Angew. Chem. Int. Ed. 2019, 58, 18619-18626.

99. Stereocontrolled Synthesis of Tetrafluoropentanols: Multi-vicinal Fluorinated Alkane Units for Drug Discovery P. Bentler, N. Erdeljac, K. Bussmann, M. Ahlqvist, L. Knerr, K. Bergander, C. Daniliuc and R. Gilmour, Org. Lett. 2019, 21, 7741-7745. Artwork featured on the front cover

98. Structural and Computational Analysis of 2-Halogeno-Glycosyl Cations in Superacid: An Expansive Platform L. Lebedel, A. Ardá, A. Martin, J. Désiré, A. Mingot, M. Aufiero, N. Aiguabella Font, R. Gilmour, J. Jiménez-Barbero, Y. Blériot, S. Thibaudeau, Angew. Chem. 2019, 131, 13896-13900; Angew. Chem. Int. Ed. 2019, 58, 13758-13762.

97. Fluorinated Analogues of the HDAC Inhibitor Vorinostat (Zolinza®): Validation of a Chiral Hybrid Bioisostere (BITE) N. Erdeljac, K. Bussmann, A. Schöller, F. Hansen and R. Gilmour, ACS Med. Chem. Lett. 2019, 10, 1336-1340. Artwork featured on the front cover

96. Catalytic Vicinal Dichlorination of Unactivated Alkenes J. C. Sarie, J. Neufeld, C. G. Daniliuc and R. Gilmour, ACS Catal. 2019, 9, 7232-7237. Highlighted in C&E News "Dichlorination catalyst eschews chlorine gas"

95. Willgerodt-type Dichloro(aryl)-λ3-Iodanes: A Structural Study J. C. Sarie, J. Neufeld, C. G. Daniliuc and R. Gilmour, Synthesis 2019, 51, 4408-4416. Invited Contribution for the special edition on halogenation (Ed. F. Schoenebeck)

94. Positional and Geometrical Isomerisation of Alkenes: The Pinnacle of Atom Economy J. J. Molloy, T. Morack and R. Gilmour, Angew. Chem. 2019, 131, 13789-13800; Angew. Chem. Int. Ed. 2019, 58, 13654-13664.

93. Inverting Small Molecule-Protein Recognition by the Fluorine Gauche Effect: Selectivity Regulated by Multiple H → F Bioisosterism P. Bentler, K. Bergander, C. G. Daniliuc, C. Mück-Lichtenfeld, R. P. Jumde, A. K. H. Hirsch and R. Gilmour, Angew. Chem. 2019, 131, 11106-11110; Angew. Chem. Int. Ed. 2019, 58, 10990-10994.

92. Stereospecific α-Sialylation by Site-Selective Fluorination T. Hayashi, G. Kehr, K. Bergander and R. Gilmour, Angew. Chem. 2019, 131, 3854-3858; Angew. Chem. Int. Ed. 2019, 58, 3814-3818.

91. Bioinspired Radical Stetter Reaction: Radical Umpolung Enabled by Ion-Pair Photocatalysis T. Morack, C. Mück-Lichtenfeld and R. Gilmour, Angew. Chem. 2019, 131, 1221-1225; Angew. Chem. Int. Ed. 2019, 58, 1208-1212. Artwork featured on the front cover Highlighted in Angewandte Chemie: X. -Yu Chen, D. Enders, Angew. Chem. Int. Ed. 2019, DOI: doi.org/10.1002/anie.201902132.

90. Flavins in Photochemistry J. B. Metternich, R. J. Mudd and R. Gilmour, Science of Synthesis: Photocatalysis in Organic Synthesis, 2019, 391-404. Invited Contribution for the special Science of Synthesis Reference Library: Photocatalysis in Organic Synthesis (Ed. B. König)

2018

88. Enantioselective, Catalytic Vicinal Difluorination of Alkenes F. Scheidt, M. Schäfer, J. C. Sarie, C. G. Daniliuc, J. J. Molloy and R. Gilmour, Angew. Chem. 2018, 130, 16669-16673; Angew. Chem. Int. Ed. 2018, 57, 16431-16435. Highlighted in Synfacts: B. List, D. Diaz-Oviedo, Synfacts 2018, 14, 1299.