Publications

Probing the Origin of Affinity in the GM1-Cholera Toxin Complex through Site-selective Editing with Fluorine
C. Jordan§, T. Hayashi§, A. Löbbert, J. Fan, C. S. Teschers, K. Siebold, M. Aufiero, F. Pape, E. Campbell, A. Axer, K. Bussmann, K. Bergander, J. Köhnke, A. D. Gossert and R. Gilmour, ACS Cent. Sci. 2024, 10, 1481–1489.

Light-Enabled Enantiodivergence: Stereospecific Reduction of Activated Alkenes using a Single Organocatalyst Enantiomer
T. Hostmann, J. J. Molloy, K. Bussmann and R. Gilmour, Org. Lett. 2019, 21, 10164-10168.

Inverting External Asymmetric Induction via Selective Energy Transfer Catalysis: A Strategy to β-Chiral Phosphonate Antipodes
C. Onneken, K. Bussmann and R. Gilmour, Angew. Chem. 2020, 132, 338-342; Angew. Chem. Int. Ed. 2020, 59, 330-334.

Stereocontrolled Synthesis of Tetrafluoropentanols: Multi-vicinal Fluorinated Alkane Units for Drug Discovery
P. Bentler, N. Erdeljac, K. Bussmann, M. Ahlqvist, L. Knerr, K. Bergander, C. Daniliuc and R. Gilmour, Org. Lett. 2019, 21, 7741-7745.

Fluorinated Analogues of the HDAC Inhibitor Vorinostat (Zolinza®): Validation of a Chiral Hybrid Bioisostere (BITE)
N. Erdeljac, K. Bussmann, A. Schöller, F. Hansen and R. Gilmour, ACS Med. Chem. Lett. 2019, 10, 1336-1340.

Indirect synthesis of a pair of formal methane activation products at a phosphane/borane frustrated Lewis pair
S. Frömel, C. G. Daniliuc, C. Bannwarth, S. Grimme, K. Bussmann, G. Kehr, G. Erker, Dalton Trans. 2015, 45, 19230.

α-CH acidity of alkyl-B(C6F5)2 compounds – the role of stabilized borata-alkene formation in frustrated Lewis pair chemistry
P. Moquist, G.-Q. Chen, C. Mück-Lichtenfeld, K. Bussmann, C. G. Daniliuc, G. Kehr, G. Erker, Chem. Sci. 2015, 6, 816-825.

Polymorphism in P,P-[3]ferrocenophanes: insights from an NMR crystallographic approach
T. Wiegand, D. Lüdeker, G. Brunklaus, K. Bussmann, G. Kehr, G. Erker, H. Eckert, Dalton Trans. 2014, 43, 12639-12647.

Indirect “No-Bond” 31P···31P Spin−Spin Couplings in P,P‑[3]Ferrocenophanes: Insights from Solid-State NMR Spectroscopy and DFT Calculations
T. Wiegand, H. Eckert, J. Ren, G. Brunklaus, R. Fröhlich, C. G. Daniliuc, G. Lübbe, K. Bussmann, G. Kehr, G. Erker, S. Grimme, J. Phys. Chem. A 2014, 118, 2316.

Ethene/Alkyne Exchange Reaction at an Intramolecular Frustrated Lewis Pairs
C. Eller, K. Bussmann, G. Kehr, B. Wibbeling, R. Fröhlich, C. G. Daniliuc, G. Erker, Chem. Commun. 2014, 50, 1980-1982.

An Enamine/HB(C6F5)2 Adduct as a Dormant State in Frustrated Lewis Pair Chemistry
B.-H. Xu, K. Bussmann, R. Fröhlich, C. G. Daniliuc, J. G. Brandenburg, S. Grimme, G. Kehr, G. Erker, Organometallics 2013, 32, 6745-6752.

Dibenzopentalenes from B(C6F5)3-Induced Cyclization Reactions of 1,2−Bis(phenylethynyl)benzenes
C. Chen, M. Harhausen, R. Liedtke, K. Bussmann, A. Fukazawa, S. Yamaguchi, J. L. Petersen, C. G. Daniliuc, R. Fröhlich, G. Kehr, G. Erker, Angew. Chem. 2013, 125, 6108-6112.

Ferrocene-Derived Bioorganometallic Chemistry: Preparation of a [3]Ferrocenophane γ-Amino Acid for Use in Peptide Synthesis
L. Tebben, K. Bussmann, M. Hegemann, G. Kehr, R. Fröhlich, G. Erker, Organometallics 2008, 27, 4269-4272.