Münster (upm)
Hexagonal boron nitride (red: boron atoms, blue: nitrogen atoms) with a colour centre (blue-red) illuminated with ultrafast laser pulses (green)<address>© WWU - Johann Preuß</address>
Hexagonal boron nitride (red: boron atoms, blue: nitrogen atoms) with a colour centre (blue-red) illuminated with ultrafast laser pulses (green)
© WWU - Johann Preuß

Physicists study optically induced quantum dynamics in single-photon emitters

For tomorrow’s quantum technologies: hexagonal boron nitride under the magnifying glass / findings published in ‘Optica’

Quantum technologies are a seminal field of research, especially in relation to their application in communication and computing. In particular, the so-called single-photon emitters – materials that emit single light quanta in quick sequence – are an important building block for such applications. Photons are an excellent means of transmitting data in a fast and secure manner. However, it is necessary to have a sound physical understanding of the structure of the single-photon emitter and how to control them. Therefore, a team of physicists from the University of Münster in Germany and Wrocław University of Science and Technology (Wrocław Tech) in Poland has undertaken the first systematic study of the ultrafast control of single-photon emitters in the two-dimensional material ‘hexagonal boron nitride’ (hBN) using laser pulses. Here, ‘ultrafast’ means faster than one picosecond, which is one-trillionth of a second. The work has been published in the journal ‘Optica’.

Such two-dimensional materials continue to be the focus of many scientific studies. Graphene is one prominent example and, in 2010, a Noble Prize was awarded for the discovery and the initial analysis of its properties. ‘Hexagonal boron nitride – hBN in short – is a 2D material with particularly interesting properties’, explains Dr Daniel Wigger from the Theoretical Physics Department of Wrocław Tech. ‘Among other things, hBN hosts single-photon emitters, which even work at room temperature, in contrast to many other systems that require extremely low temperatures.’  Experts are convinced, that these single-photon emitters originate from impurity atoms, that is atomic defects or colour centres within the hBN crystal.

Our scientists took a closer look at these colour centres, whose exact atomic structure is still unknown. They developed a comprehensive understanding of the dynamics within the colour centre inside the hBN crystal by combining their experiments with theoretical modelling. One of their focuses was on the detrimental impact of the environment the quantum dynamics. Microscopic systems are affected by different interactions with the environment, which manifest as external noise on varying time scales, for example, as slight colour fluctuations of the emitted photons. The quantum properties of such systems are, in particular, very sensitive to this noise. This can lead to so-called decoherence, which results in the loss of quantum information stored in the system.

The team used ultrafast laser pulses to prepare and read out the quantum state of the atomic defect. ‘In simple terms, the applied technique works like a stroboscope,’ says physicist Dr Steffen Michaelis de Vasconcellos from the Institute of Physics and the Center for Nanotechnology at the University of Münster. ‘A first pulse creates a quantum state which, after a brief delay, is read out by a second pulse. By varying the time between the two pulses, it is possible to measure the change in the quantum state and thereby the decoherence.’

In addition to this key experiment, the physicists undertook a detailed investigation into the spectrum of the emitters, that is, which light or ‘colour’ the emitter is generating. They supplemented the experiments with computer simulations, which were run with the same parameters as the experiments. Special attention was paid to phonons – sound waves in the crystal – that can have a particularly detrimental influence. ‘Experiment and theory have provided a consistent picture in our study,’ emphasises Daniel Wigger.

Our scientists have, for the first time, not only considered the dynamic character of the emitter system but also the light spectrum, in order to understand the impact of these external influences on different time scales. Based on these results, perturbations can potentially be avoided in future applications and phonons can be integrated into technological applications as an additional type of quantum excitation.


Original publication:

Johann A. Preuss, Daniel Groll, Robert Schmidt, Thilo Hahn, Paweł Machnikowski, Rudolf Bratschitsch, Tilmann Kuhn, Steffen Michaelis de Vasconcellos, and Daniel Wigger, "Resonant and phonon-assisted ultrafast coherent control of a single hBN color center," Optica 9, 522-531 (2022); DOI: 10.1364/OPTICA.448124

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