2020

74. D. G. Piekarski, P. Steinforth, M. Gómez-Martínez, J. Bamberger, F. Ostler, M. Schönhoff, O. García Mancheño, “Insight into the Folding and Cooperative Multi-Recognition Mechanism in Supramolecular Anion-Binding Catalysis“, Chem. Eur. J. 2020, 26, 17598-17603. DOI: 10.1002/chem.202003994

 73. L. Schifferer, O. García Mancheño, “Metal and Solvent-Free, One-pot Synthesis of 3-Unsubstituted Benzoindolizines“, Eur. J. Org. Chem. 2020, 7176-7183. DOI: 10.1002/ejoc.202001245

72. M. Gómez-Martínez, O. García Mancheño, “Fe-Catalyzed C−H Activation/Functionalization” In Catalytic Science Series: Metal Catalyzed C-H Activation. (Ed.: G. Hutchings, Guest Ed: J. M. Palomo), World Scientific.  

71. S. Joseph, G. Khassenova, O. García Mancheño, “Catalytic Enantioselective Reactions with (Benzo)Pyrylium Salts“, CHIMIA 2020,  74 ,  857-865. Special issue 'Innovative Tools in Organic / Organometallic Chemistry'  

https://www.ingentaconnect.com/content/scs/chimia/2020/00000074/00000011

2019

 70. J. Bamberger, F. Ostler, O. García Mancheño, "Frontiers in Halogen and Chalcogen-Bond Donor Organocatalysis", ChemCatChem 2019, 11, 5198-5211. DOI: 10.1002/cctc.201901215   

 69. T. Brandhofer, A. Gini, S. Stockerl, D. G. Piekarski, O. García Mancheño, "Direct C-H Bond Imidation with Benzoyl Peroxide as Both Mild Oxidant and Reagent", J. Org. Chem. 2019, 84,  12992-13002. DOI: 10.1021/acs.joc.9b01765

68. T. Brandhofer, O. García Mancheño, "Versatile Ru-Photoredox-Catalyzed Functionalization of Dehydro-Amino Acids and Peptides", ChemCatChem 2019, 11, 3797-3801.  DOI: 10.1002/cctc.201900446

67. S. Stockerl, T. Danelzik, D. G. Piekarski, O. García Mancheño, "Mild, Metal-free Oxidative Ring Expansion Approach for the Synthesis of Benzo[d]azepines", Org. Lett. 2019, 21, 4535-4539. DOI: 10.1021/acs.orglett.9b01433 

66. A. Gini, T. Rigotti, R. Pérez-Ruiz, M. Uygur, R. Mas-Ballesté, I. Corral, L. Martínez-Fernández, V. A. de la Peña O'Shea, O. García Mancheño,* J. Alemán,* "Mesityl or Imide Acridinium PhotoCatalysts: Accessible versus not Accesible Charge-Transfer State in Photoredox Catalysis", ChemPhotoChem. 2019, 3, 609-612. DOI: 10.1002/cptc.201900116

65. M. Uygur, O. García Mancheño, "Visible Ligth-Mediated Organophotocatalyzed C-H Bond Functionalization Reactions", Org. Biomol. Chem. 2019, 17, 5475-5489. DOI: 10.1039/C9OB00834A

64.- Q.-N. Duong, L. Schifferer, O. García Mancheño, "Nucleophile Screening in Anion-Binding Reissert-type Reactions of Quinolines with Chiral TetrakisTriazole Catalysts", Eur. J. Org. Chem. 2019, 5452-5461. DOI: org/10.1002/ejoc.201900566

63.- A. Casado-Sánchez, M. Uygur, D. González-Muñoz, F. Aguilar-Galindo, J. L. Nova-Fernández, J. Arranz-Plaza, S. Díaz-Tendero, S. Cabrera, O. García Mancheño,* J. Alemán,* "8-Mercaptoquinoline as Ligand for Enhancing the Photocatalytic Activity of Pt(II) Coordination Complexes: Reactions and Mechanistic Insights", J. Org. Chem. 2019, 84, 6437-6447. DOI: 10.1021/acs.joc.9b00520

 62.- M. Uygur, T. Danelzik, O. García Mancheño, "Metal-Free Desilylative C-C Bond Formation by Visible Light Photoredox Catalysis" Chem. Commun. 2019, 55, 2980-2983. DOI: 10.1039/C8CC10239B

 61.- T. Brandhofer, A. Özdemir, A. Gini, O. García Mancheño, Double Cu-Catalyzed Direct Csp³-H Azidation/CuAAC Reaction: A Direct Approach Towards Demanding Triazole Conjugates, Chem. Eur. J. 2019, 25, 4077-4086.  DOI: 10.1002/chem.201806288

HOT PAPER (selected for the Cover Feature.... 2019, Issue 25, pp. 3964)

60.- T. Fischer, J. Bamberger, M. Gómez-Martínez, D. Piekarski, O. García Mancheño, Helical Multi-Coordination Anion-Binding Catalysts Enable Highly Enantioselective Dearomatization of Pyrylium Derivatives, Angew. Chem. Int. Ed. 2019, 58, 3217-3221. DOI: 10.1002/anie.201812031

2018

59.- T. Brandhofer, O. García Mancheño, Site-selective C-H Bond Activation/Functionalization on Alpha-Amino Acids and Peptide-like Derivatives, Eur. J. Org. Chem. 2018, 6050-6067.  https://doi.org/10.1002/ejoc.201800896

 Cover Feature: https://onlinelibrary.wiley.com/doi/10.1002/ejoc.201801629

 The Cover Feature shows the versatile modern C‐H functionalization approach of peptides towards unnatural derivatives with improved or unusual applications. Similar to the metamorphosis of caterpillars into butterflies, peptides can be transformed into important new structures by site selective modification of different C‐H bonds. Depending on the method, C‐H cleavage at various positions of the amino acid units, can provide an easy access to novel pharmaceuticals and materials, as well as to molecular recognition applications. More information can be found in the Microreview by O. García Mancheño et al.

.

58.- A. Gini, M. Uygur, T. Rigotti, J. Alemán, O. García Mancheño, Novel Oxidative Ugi-Reaction for the Synthesis of Highly Active Visible Light Imide-Acridinium OrganoPhotocatalysts, Chem. Eur. J. 2018, 24, 12509-12514.  

http://dx.doi.org/10.1002/chem.201802830

Highlighted in Synfacts 2018; 14, 1133.  DOI: 10.1055/s-0037-1611291

 

2017

57.- T. Fischer, Q.-N. Duong, O. García Mancheño, Triazole-based Anion-binding Catalysis for the Enantioselective Dearomatization of N-Heteroarenes with P-Nucleophiles, Chem. Eur. J. 2017, 23, 5983-5987. DOI: 10.1002/chem.201605660

56.- D. Kellner, M. Weger, A. Gini, O. García Mancheño, Pd(OAc)₂/Ph₃P-catalyzed dimerization of isoprene and synthesis of monoterpenic heterocycles, Beilstein J. Org. Chem. 2017, 13, 1807-1815.

 55.- A. Gini, T. Brandhofer, O. García Mancheño,* “Recent progress on mild oxidative Csp3-H bond functionalization”. Org. Biomol. Chem. 2017, 15, 1294-1312. DOI: 10.1039/c6ob02474b

 54.- M. Zurro, O. García Mancheño,* “1,2,3-Triazole-Based Catalysts: From Asymmetric Metal Catalysis to Anion-Binding Organocatalysis”. Chem. Rec. 2017, 17, 485-498. DOI: 10.1002/tcr.201600104.

 53.- S. Stockerl, D. Gutiérrez, O. García Mancheño,* “Click-BINOL-Phosphoric Acid Catalysts in Intramolecular enantioselective Oxidative C-H-Bond Functionalization”. J. Mol. Catal. A: Chem. 2017, 426, Part B, 572-585.

2016

 52.- A. Gini, J. Bamberger, J. Luis-Barrera, M. Zurro, R. Mas-Ballesté, J. Alemán,* García Mancheño,* “Synthesis of 3-Benzazepines by Metal-free Oxidative C–H Bond Functionalization–Ring Expansion Tandem Reaction”. Adv. Synth. Catal. 2016, 358, 4049-4056.

 51.- O. García Mancheño,* “Mimicking Nature: Anion-Binding Processes for Cooperative Catalysis”.  International Innovation 2016, 202, 72-73.

 50.- T. Fischer, J. Bamberger, O. García Mancheño,* “Asymmetric Nucleophilic Dearomatization of Diazarenes by Anion-Binding Catalysis”. Org. Biomol. Chem. 2016, 14, 5794-5802. (New Talent themed issue)

49.- M. Zurro, S. Asmus, J. Bamberger, S. Beckendorf, O. García Mancheño,* “Chiral Triazoles in Anion-Binding Catalysis: New Entry to Enantioselective Reissert-Type Reactions”. Chem. Eur. J. 2016, 22, 3785-3793. (Special issue: Women in Chemistry).

 48.- S. Stockerl, O. García Mancheño,* “Non-Covalent Organocatalysis in Asymmetric Oxidative C(sp3)-H Bond Functionalization – Broadening C-H Bond Coupling Reactions”. Org. Chem. Front. 2016, 3, 277-280. (Emerging Investigators themed collection)

 47.- A. Gini, O. García Mancheño,* “Mild Radical Oxidative C(sp³)-H Functionalization: Innovative Construction of Isoxazolines and Dibenz[b,f]oxepines/azepines”. A. Gini, O. García Mancheño,* Synlett 2016, 27, 526-539.

2015

 46.- A. Gini, M. Segler, D. Kellner, O. García Mancheño,* “Dehydrogenative TEMPO-Mediated Formation of Unstable Nitrones: Easy Access to N-Carbamoyl Isoxazolines”. Chem. Eur. J. 2015, 21, 12053-12060. (HOT paper).

 45.- O. García Mancheño,* S. Asmus, M. Zurro, T. Fischer, “Highly Enantioselective Nucleophilic Dearomatization of Pyridines by Anion-Binding Catalysis”.  Angew. Chem. Int. Ed. 2015, 54, 8823-8827.

 44.- T. Stopka, L. Marzo, M. Zurro, S. Janich, E.-U. Würthwein, C. G. Daniliuc, J. Alemán,* O. García Mancheño,* “Oxidative C–H Bond Functionalization–Ring Expansion Reaction with TMSCHN2: A Novel Cu(I)-Catalyzed Approach to Dibenzoxe- and Dibenzoazepines”. Angew. Chem. Int. Ed. 2015, 54, 5049-5053.

2014

 43.- M. Zurro, S. Asmus, S. Beckendorf, C. Mück-Lichtenfeld, O. García Mancheño,* “Chiral Helical Oligotriazoles: New Class of Anion-Binding Catalysts for the Asymmetric Dearomatization of Electron-Deficient N-Heteroarenes”.  J. Am. Chem. Soc. 2014, 136, 13999-14002.
Highlighted in SYNFACTS 2014, 10, 1321
Highlighted in Nachrichten aus der Chemie 12/2014, pp 1160

 42.- S. Asmus, S. Beckendorf, M. Zurro, C. Mück-Lichtenfeld, R. Fröhlich, O. García Mancheño,* “Influence of the Substitution and Conformation of C−H Bond-Based BisTriazole Acceptors in Anion-Binding Catalysis”. Chem. Asian J. 2014, 9, 2178-2186.

2013

 41.- R. Rohlmann, C. G. Daniliuc, O. García Mancheño,* “Highly Enantioselective Synthesis of Chiral 7-Ring O- an N-Heterocycles by a One-pot Nitro-Michael/Cyclization Tandem Reaction”. Chem. Commun. 2013, 49, 11665-11667.

 40.- R. Rohlmann, T. Stopka, H. Richter, O. García Mancheño,* “Iron-Catalyzed Oxidative Tandem Reactions with TEMPO Oxoammonium Salts: Synthesis of Dihydroquinazolines and Quinolines”.  J. Org. Chem. 2013, 78, 6050-6064.

 39.- O. García Mancheño,* T. Stopka, “TEMPO Derivatives as Alternative Mild Oxidants in C–C Coupling Reactions”. Synthesis 2013, 45, 1602-1611.

 38.- “Young Career Focus: Dr. Olga García Mancheño”. SYNFORM, 2013/01, Synstories A12; DOI: 10.1055/s-0032-1317679.

 37.- S. Beckendorf, S. Asmus, C. Mück-Lichtenfeld, O. García Mancheño,* “Click-BisTriazoles as Neutral C−H···Anion Acceptor Organocatalysts”. Chem. Eur. J. 2013, 19, 1581-1585.
Highlighted in SynFacts: “Hydrogen-Bonding Catalysis using C-H··X Interactions”, Synfacts 2013, 9, 327.

 36.- R. Rohlmann, O. García Mancheño,* “Metal-Free Oxidative C(sp³)–H Bond Couplings as Valuable Synthetic Tools for C–C Bond Formations”. Synlett 2013, 24, 6-10.

2012

 35.- H. Richter, R. Fröhlich, C. G. Daniliuc, O. García Mancheño,* “Mild Metal-free Tandem α-Alkylation/Cyclization of N-Benzyl Carbamates with Simple Olefins”.  Angew. Chem. Int. Ed. 2012, 51, 8656-8660.
Highlighted in SynFacts: “Synthesis of Methopholine”, Synfacts 2012, 8, 1172.

 34.- O. García Mancheño,* M. Alcarazo,* “At the Frontiers of Knowledge in Chemistry: The 47th Bürgenstock Conference”. Angew. Chem. Int. Ed. 2012, 51, 8151-8154. (Meeting Reviews)

 33.- R. Rohlmann, O. García Mancheño,* “Sulfur Activated α-Methylene Reagents in Asymmetric Catalysis”. Current Org. Chem. 2012, 16, 2160-2191 (special issue on Active Methylene Compounds).

 32.- S. Beckendorf, O. García Mancheño,* “Click-BINOLs: New Class of Tunable Ligands for Asymmetric Catalysis”. Synthesis 2012, 44, 2162-2172 (special topic on Lewis Acid Catalysis).

 31.- S. Beckendorf, S. Asmus, O. García Mancheño,* “H-Donor Anion Acceptor Organocatalysis – The Ionic Electrophile Activation Approach”. ChemCatChem 2012, 4, 926-936 (special issue on Organocatalysis).

 30.- V. More, R. Rohlmann, O. García Mancheño,* C. Petronzi, L. Palombi, V. Intintoli, A. Massa,* “First Organocatalytic Asymmetric Synthesis of 3-Substituted Isoindolinones”. RSC Adv. 2012, 2, 3592-3595.

2011

 29.- H. Richter, O. García Mancheño,* “TEMPO Oxoammoninum Salt Mediated Dehydrogenative Povarov – Oxidation Tandem Reaction of N-Alkyl Anilines”. Org. Lett. 2011, 13, 6066-6069.

Highlighted in SynFacts: “Synthesis of Quinolines from N-Alkyl Anilines and Olefins”, Synfacts 2012, 8, 139.

28.-  H. Richter, R. Rohlmann, O. García Mancheño,* “Catalyzed Selective Direct α- and γ-Alkylation of Aldehydes with Cyclic Benzyl Ethers Using T⁺BF₄^- in the Presence of an Inexpensive Organic Acid or Anhydride”. Chem. Eur. J. 2011, 17, 11622-11627.

 27.- H. Richter, S. Beckendorf, O. García Mancheño,* “Modifiable Sulfur Tethers as Directing Groups for Aromatic C–H Acetoxylation Reactions”. Adv. Synth. Catal. 2011, 353, 295-302.

26.- O. García Mancheño,* “New Trends Towards Well-Defined Low-Valent Iron Catalysis”. Angew. Chem. Int. Ed. 2011, 50, 2216-2218.  

 25.- O. García Mancheño,* P. Tangen, R. Rohlmann, R. Fröhlich, J. Alemán,* “Synthesis of Chiral Cyclic Nitrones by Asymmetric Addition of β-Ketosulfones to Nitroalkenes followed by Reductive Cyclization”. Chem. Eur. J. 2011, 17, 984-992.

Highlighted in SynFacts: “Michael Addition of -ketosulfones to Nitroalkenes”, Synfacts 2011, 7, 218.

Before 2011

 23.- “Asymmetric Syntheses of S,S-Dialkyl-Substituted Sulfoximines and Related Heterocycles”. A. G. Pandey, M. J. McGrath, O. García Mancheño, C. Bolm,* Synthesis 2011, 3827-3838.

22.- “Synthesis of Sulfoximines and Sulfilimines with Aryl and Pyrazolylmethyl Substituents”. O. García Mancheño, J. Dallimore, A. Plant, C. Bolm,* Adv. Synth. Catal. 2010, 352, 309-316.

21.- “Iron(II) Triflate as an Efficient Catalyst for the Imination of Sulfoxides”. O. García Mancheño, J. Dallimore, A. Plant, C. Bolm,* Org. Lett. 2009, 11, 2429-2432.

20.- Book chapters:
- “N,O-Bidentate Ferrocenyl Ligands” in Chiral Ferrocenes in Asymmetric Catalysis: Synthesis and Applications. Eds: L.-X. Dai, X.-L. Hou. Wiley-VCH, Weinheim, pp. 149-174, 2009. A. Nijs, O. García Mancheño, C. Bolm.
- “Oxidations of Heteroatoms (N and S)” in Iron Catalysis in Organic Chemistry: Reactions and Applications. Ed: B. Plietker. Wiley-VCH, Weinheim, pp. 109-123, 2008. O. García Mancheño, C. Bolm.

19.- “Iron-catalyzed Carbon-Heteroatom and Heteroatom-Heteroatom Bond Forming Processes”. A. Correa, O. García Mancheño, C. Bolm,* Chem. Soc. Rev. 2008, 37, 1108-1117. (Cover picture).

18.- “Synthesis of Sulfonimidamides from Sulfinamides by Oxidation with N-Chlorosuccinimide”. O. García Mancheño, C. Bolm, Beilstein J. Org. Chem. 2007, 3, 25.

17.- “Iodinane- and Metal-free Synthesis of N-Cyano Sulfilimines: Novel and Easy Access to NH-Sulfoximines”. O. García Mancheño, O. Bistri, C. Bolm,* Org. Lett. 2007, 9, 3809-3811.

16.- “Synthesis of N-(1H)-Tetrazole Sulfoximines”. O. García Mancheño, C. Bolm,* Org. Lett. 2007, 9, 2951-2954.
Highlighted in SynFacts: “Synthesis of Tetrazole and Oxadiazole Sulfoximines”, Synfacts 2007, 1026.

15.- “Comparative Study of Metal-Catalyzed Iminations of Sulfoxides and Sulfides”. O. García Mancheño, C. Bolm,* Chem. Eur. J. 2007, 13, 6674-6681.

14.- “Iron-Catalyzed Imination of Sulfoxides and Sulfides”. O. García Mancheño, C. Bolm,* Org. Lett. 2006, 8, 2349-2352.

13.- “Catalytic Enantioselective Approach to the Stereodivergent Synthesis of (+)-Lasubines I and II”. O. García Mancheño, R. Gómez Arrayás, J. Adrio, J. C. Carretero,* J. Org. Chem. 2007, 72, 10294-10297.

12.- “Sulfenylphosphinoferrocenes: Novel Planar Chiral Ligands in Enantioselective Catalysis”. S. Cabrera, O. García Mancheño, R. Gómez Arrayás, I. Alonso, P. Mauleón, J. C. Carretero,* Pure & Appl. Chem. 2006, 78, 257-266.

11.- “Copper(I) Complexes of Fesulphos Ligands: Highly Efficient Chiral Lewis Acids for the Formal Aza Diels-Alder Reaction of N-Sulfonyl Imines”. O. García Mancheño, R. Gómez Arrayás, J. C. Carretero,* Phosphorus, Sulfur and Silicon & Related Elem. 2005, 180, 1515-1516.

10.- “Transition Metal Complexes of Fesulphos Ligands in Enantioselective Catalytic Transformations”. R. Gómez Arrayás, O. García Mancheño, S. Cabrera, J. C. Carretero,* Phosphorus, Sulfur and Silicon & Related Elem. 2005, 180, 1259-1265.

9.- “Palladium Complexes of Chiral Planar 1-Phosphino-2-sulfenylferrocenes as Efficient Catalysts in Enantioselective Diels-Alder Reactions”. O. García Mancheño, R. Gómez Arrayás, J. C. Carretero,* Organometallics 2005, 24, 557-561.

8.- “Organocatalytic Asymmetric Hydroxylation of β-Keto Esters – Metal-Free Synthesis of Optically Active anti-Diols”. Maria Rosaria Acocella, O. García Mancheño, M. Bella, K. A. Jørgensen,* J. Org. Chem. 2004, 69, 8165-8167.

7.- “Chiral Copper Complexes of Phosphino Sulfenyl Ferrocenes as Efficient Catalysts for Enantioselective Formal Aza Diels-Alder Reactions of N-Sulfonyl Imines.” O. García Mancheño, R. Gómez Arrayás, J. C. Carretero,* J. Am. Chem. Soc. 2004, 126, 456-457.

6.- “First Planar Chiral Bidentate Ligand Based on a (η⁵-cyclopentadienyl)(η⁴-cyclobutadiene) Cobalt Skeleton: High Efficiency in Enantioselective Palladium-catalyzed Allylic Substitutions”. R. Gómez Arrayás, O. García Mancheño, J. C. Carretero,* Chem. Commun. 2004, 1654-1655.

5.- “1-Phosphino-2-sulfenylferrocenes as Planar Chiral Ligands in Enantioselective Palladium-catalyzed Allylic Substitutions”. O. García Mancheño, J. Priego, S. Cabrera, R. Gómez Arrayás, T. Llamas, J. C. Carretero,* J. Org. Chem. 2003, 68, 3679-3686.

4.- “1-Phosphino-2-sulfenylferrocenes: Efficient Ligands in Enantioselective Palladium-catalyzed Allylic Substitutions and Ring Opening of 7-Oxabenzonorbornadienes”. J. Priego, O. García Mancheño, S. Cabrera, R. Gómez Arrayás, T. Llamas, J. C. Carretero,* Chem. Commun. 2002, 2512-2513.

3.- “2-Aminosubstituted 1-Sulfinylferrocenes as Chiral Ligands in the Addition of Diethylzinc to Aromatic Aldehydes”. J. Priego, O. García Mancheño, S. Cabrera, J. C. Carretero,* J. Org. Chem. 2002, 67, 1346-1353.

2.- “Aminosubstituted t-Butylsulfinylferrocenes as a New Family of Chiral Ligands: Asymmetric Addition of Diethylzinc to Aldehydes”. J. Priego, O. García Mancheño, S. Cabrera, J. C. Carretero,* Chem. Commun. 2001, 2026-2027.

1.- “The 2-(N,N-Dimethylamino)phenylsulfinil Group as an Efficient Chiral Auxiliary in Intramolecular Heck Reactions”. N. Díaz Buezo, O. García Mancheño, J. C. Carretero,* Org. Lett. 2000, 2, 1451-1452.