Dr. Qiu Sun
group of Prof. G. Erker
Corrensstr. 40
48149 Münster
Lab. No. 2.31
Phone: +49 251 83-33224
Email: qsun@uni-muenster.de
Member of the group since: 01/2019
Research interest: Cyclic “Frustrated Lewis Pair" chemistry and free radical chemistry
PhD degree thesis: “Synthesis and Characterization of Zirconium Complexes Supported by Amine Bridged Bis(phenolato) Ligands and Their Catalytic Behavior toward Hydroamination and Alkylation”, Soochow University, Suzhou, China, 06/2016.
Publications:
1. Sun, Q.; Daniliuc, C. G.; Bergander, K.; Kehr, G.; Erker, G."Carbon Monoxide Coupling Reactions via a Frustrated Lewis Pair-Derived η2-Formyl Borane" J. Am. Chem. Soc. 2021. 143, 14992–14997.
2. Sun, Q.; Daniliuc, C. G.; Kehr, G.; Erker, G."Reaction of carbon oxides with an ethylene-bridged PH/B Lewis pair" Dalton Trans. 2021, 50, 3523-3528.
3. Sun, Q.; Daniliuc, C. G.; Mück-Lichtenfeld, C.; Bergander, K.; Kehr, G.; Erker, G. "Reductive Cleavage of the CO Molecule by a Reactive Vicinal Frustrated PH/BH Lewis Pair", J. Am. Chem. Soc. 2020, 142, 17260-17264.
4. Sun, Q.; Chen, P.; Wang, Y.; Luo, Y.; Yuan, D.; Yao, Y. “Addition of C–H Bonds of Pyridine Derivatives to Alkenes Catalyzed by Zirconium Complexes Bearing Amine-Bridged Bis(phenolato) Ligands”, Inorg. Chem., 2018, 57, 11788-11800.
5. Sun, Q.; Zhang, Y.-Y.; Sun, J.; Han, Y.; Jia, X.; Yan C.-G. “Construction of C(sp2)−X (X = Br, Cl) Bonds through a Copper-Catalyzed Atom-Transfer Radical Process: Application for the 1,4-Difunctionalization of Isoquinolinium Salts”, Org. Lett., 2018, 20, 987−990.
6. Sun, Q.; Zhang, Y.-Y.; Sun, J.; Han, Y.; Jia, X.; Yan C.-G. “Copper-Catalyzed Selective 1,2-Dialkylation of N Heteroarenes via a Radical Addition/Reduction Process: Application for the Construction of Alkylated Dihydroazaarenes Derivatives”, J. Org. Chem., 2018, 83, 6640−6649.
7. Sun, Q.; Xie, P.; Yuan, D.; Xia, Y.; Yao, Y. “Regioselective addition of C(sp3)–H bonds of alkyl pyridines to olefins catalysed by cationic zirconium complexes”, Chem. Commun., 2017, 53, 7401-7404.
8. Sun, Q.; Wang, Y.; Yuan, D.; Yao, Y.; Shen, Q.; “Zirconium catalysed intermolecular hydroamination reactions of secondary amines with alkynes”, Chem. Commun., 2015, 51, 7633-7636.
9. Sun, Q.; Wang, Y.; Yuan, D.; Yao, Y.; Shen, Q. “Zirconium complexes stabilized by amine-bridged bis(phenolato) ligands as precatalysts for intermolecular hydroamination reactions”, Dalton trans., 2015, 44, 20352-20360.
10. Sun, Q.; Wang, Y.; Yuan, D.; Yao, Y.; Shen, Q. “Synthesis of group 4 metal complexes stabilized by an amine-bridged bis(phenolato) ligand and their catalytic behavior in intermolecular hydroamination reactions”, Organometallics, 2014, 33, 994-1001.
Miscellaneous:
Alexander von Humboldt fellowship for postdoc