Dr. Karel Škoch
group of Prof. G. Erker
Corrensstr. 40
48149 Münster
Lab. No.: 2.04 / 2.05
Phone: +49 251 83-33223 / 39741
Email: skochk@uni-muenster.de
Dr. Karel Škoch
Member of the group since: 10/2017
Research interest:
FLP assisted activation of small molecules
PhD degree thesis:
”Functional phosphinoferrocene ligands”, Charles University, Prague, Czech Republic 09/2016.
Publications:
"Alkyne 1,1‐Hydroboration to a Reactive Frustrated P/B‐H Lewis Pair", K. Škoch, C. G Daniliuc, G. Kehr, G. Erker, Angew. Chem. Accept. doi: 10.1002/ange.202014562; "Alkyne 1,1‐Hydroboration to a Reactive Frustrated P/B‐H Lewis Pair", K. Škoch, C. G Daniliuc, G. Kehr, G. Erker, Angew. Chem. Int. Ed. Accept. doi: 10.1002/anie.202014562
"Using the FpXylBH2 SMe2 Reagent for the Regioselective Synthesis of Cyclic Bis(alkenyl)boranes", K. Škoch, C. G Daniliuc, G. Kehr, G. Erker, Chem. Commun. 2020, 56, 12178-12181. doi: 10.1039/D0CC05230B
"Macrocycle Formation by Cooperative Selection at a Double-Sited Frustrated Lewis Pair." L. Wang, D. Deng, K. Škoch, C. G. Daniliuc, G. Kehr, G. Erker, Organometallics, 2019, 38, 1897-1902. (Cover of the issue) doi: 10.1021/acs.organomet.9b00002.
"Consecutive intermolecular 1,1-carboboration reactions of Me3Si-substituted alkynes with the halogeno-B(C6F5)2reagents", K. Škoch, C. Pauly, C. G. Daniliuc, K. Bergander, G. Kehr, G. Erker, Dalton Trans., 2019, 48, 4837-4845. doi: 10.1039/c9dt00413k.
"Selective Gold-Catalysed Synthesif of Cyanamides and 1-Substituted 1H-Tetrazol-5-Amines from Isocyanides",
"Synthesis and characterisation of palladium(II) complexes with hybrid phosphinoferrocene ligands bearing additional O-donor substituents", P. Vosáhlo, J. Schulz, K. Škoch, I. Císařová, P. Štěpnička, New. J. Chem. 2019, 43, 4463-4473. doi: 10.1039/c9nj00298g.
"Comparing the reactivity of isomeric phosphinoferrocene nitrile and isocyanide in Pd(II) complexes: synthesis of simple coordination compounds vs. preparation of P-chelated insertion products and Fischer-type carbenes",
“Phosphine-Borane Frustrated Lewis Pairs Derived from a 1,1´-Disubstituted Ferrocene Scaffold: Synthesis and Hydrogenation Catalysis”, Jian Z., Krupski S., Škoch K., Kehr G., Daniliuc C.G., Císařová I., Štěpnička P., Erker G. Organometallics 2017, 36, 2940-2946.
“Catalytic Activity of Gold(I) Complexes with Hemilabile P,N Ligands”, Michelet B., Lebœuf C., Škoch K., Horký F., Štěpnička P., Gandon V. ChemPlusChem, 2017, 82 442-448.
“Synthesis and Characterization of 1'-(Diphenylphosphino)-1-isocyanoferrocene, an Organometallic Ligand Combining Two Different Soft Donor Moieties, and its Group 11 Metal Complexes”, Škoch K., Císařová I., Schulz J., Siemeling U., Štěpnička P. Dalton Trans, 2017, 31, 10339-10354.
“Synthesis of a Polar Phosphinoferrocene Amidosulfonate Ligand and its Application in Pd-Catalyzed Cross-Coupling Reactions of Aromatic Boronic Acid and Acyl Chloride in an Aqueous Medium”, Škoch K., Císařová I., Štěpnička P. Organometallics, 2016, 35, 3378-3387.
“Synthesis and Structural Characterization of a Simple Cu(I) and an Unexpected Mixed-Valence Copper (I/II) Complex with a supporting Phosphinoferrocene Amine Ligand”, Škoch K., Císařová I., Štěpnička P. J. Organomet. Chem, 2016, 819, 248-254.
“Silver(I) Complexes with 1´-(Diphenylphosphino)-1-cyanoferrocene: The Art of Improvisation in Coordination”, Škoch K., Uhlík F., Císařová I., Štěpnička P. Dalton Trans, 2016, 45, 10655-10671.
“Synthesis and Catalytic Use of Gold(I) Complexes Containing a Hemilabile Phosphanylferrocene Nitrile Donor”, Škoch K., Císařová I., Štěpnička P. Chem. Eur. J. 2015, 21, 15998-16004.
“Phosphinoferrocene Ureas: Synthesis, Structural Characterization and Catalytic Use in Palladium-Catalyzed Cyanation of Aryl Bromides”, Škoch K., Císařová I., Štěpnička P. Organometallics, 2015, 34, 1942-1956.
“1'-(Diphenylphosphino)-1-cyanoferrocene: A Simple Ligand with Complicated Coordination Behavior Toward Copper(I)”, Škoch K., Císařová I., Štěpnička P. Inorg. Chem. 2014, 53, 567-577.
“Synthesis, Molecular Structure and Catalytic Evaluation of Centrostereogenic Ferrocenophane Phosphines”, Škoch K., Císařová I., Štěpnička P. Organometallics, 2013, 32, 623-635.