Organisch-Chemisches Institut	Tel. (0251) 83-33210 Fax: (0251) 83-39772 e-mail: orgchem@uni-muenster.de www: uni-muenster.de/Chemie.oc/
Corrensstrasse 40 48149 Münster Geschäftsführender Direktor: Prof. Dr. Stefan Grimme
Forschungsschwerpunkte 2003 - 2004    zurück    weiter

Prof. Dr. Rudolf Aumann Organometallic chemistry, synthetic aspects   Organometallic chemistry, synthetic aspects: transition metal carbene complexes, reactivity of M=C bonds; template synthesis and catalysis; syntheses and chemical recycling; organometallic stereochemistry; chiral olefin complexes and chiral carbene complexes for asymmetric synthesis; 1-metalla-1,3-dienes and 1-metalla-1,3,5-trienes, structure and reactivity; photoinduced template coupling reactions; 2-azaallenyl and ketene imine complexes as "non-classical" building blocks for N-heterocycles; reactions of strained hydrocarbons with transition metals; molecular dynamics and spectroscopy; mechanistic aspects. Publications: S. Ünaldi, R. Aumann, R. Fröhlich; C-Ca Insertion: Insertion of an Alkyne into the C-C Single Bond between the Carbene-Carbon Atom and the a-Carbon Atom of a Fischer Carbene Complex by an Unprecedented Metalla(di-p-methane) Skeletal Rearrangement. Chem. Eur. J., 9, 3300 - 3309 (2003).