Dr. Xin Tao
group of Prof. G. Erker
Corrensstr. 40
48149 Münster
Lab. No.: 2.31
Phone: +49 251 83-33224
Email:taox@uni-muenster.de
Member of the group since: 03/2015
Research interest:
Radical "Frustrated Lewis Pair" chemistry and Borane mediated Allene Chemistry
PhD degree thesis:
"New Metallocene Catalysts: Synthesis, Characterization and Catalytic Performance for Olefin Polymerization", Jilin University, Changchun, China 06/2014.
Publications:
"Halogenoborane mediated allene cyclooligomerization", X. Tao, C. Wölke, C. G. Daniliuc, G. Kehr, G. Erker, Chem. Sci. 2019, 10, 2478-2482. doi: 10.1039/c8sc04790a.
“Borane Induced Dimerization of Arylallene”, X. Tao, C. G. Daniliuc, G. Kehr, G. Erker, Angew. Chem. Int. Ed. 2018, 57, 13922-13926. doi: 10.1002/anie.201808436
"The Borole Route to Reactive Pentafluorophenyl-substituted Diboranes(4)", F. Ge,+ X. Tao,+ C. G. Daniliuc, G. Kehr, G. Erker, Angew. Chem. Int. Ed. 2018, 57, 14570-14574. doi: 10.1002/anie.201807743
"The Special Role of B(C6F5)3 in the Single Electron Reduction of Quinones by Radicals", X. Tao, C. G. Daniliuc, R. Knitsch, M. R. Hansen, H. Eckert, M. Lübbesmeyer, A. Studer, G. Kehr, G. Erker, Chem. Sci. 2018, 9, 8011-8018. doi: 10.1039/C8SC03005G
"Unusual 1,1-Hydroboration Route to a Reactive Unsaturated Vicinal Frustrated Phosphane/Borane Lewis Pair", A. Ueno, X. Tao, C. G. Daniliuc, G. Kehr, G. Erker, Organometallics 2018, 37, 2665-2668. doi: 10.1021/acs.organomet.8b00481
"Reduction of Dioxygen by Radical/B(p-C6F4X)3 Pairs to Give Isolable Bis(borane)superoxide Compounds", X. Tao, G. Kehr, C. G. Daniliuc, G. Erker, Angew. Chem. Int. Ed. 2017. doi: 10.1002/anie.201709309. Angew. Chem. 2017. doi: 10.1002/ange.201709309
"Selective Metal-free HB(C6F5)2 Catalyzed Allene Cyclotrimerization: Formation of 1,3,5-Trimethylenecyclohexane and Its Trishydroboration Product", X. Tao, G. Kehr, C. G. Daniliuc, G. Erker, Angew. Chem. Int. Ed. 2017, 56, 1376-1380. doi: 10.1002/anie.201610530. Angew. Chem. 2017, 129, 1396-1400. doi: 10.1002/ange.201610530
“Rapid Dihydrogen Cleavage by Persistent Nitroxide Radicals under Frustrated Lewis Pair Conditions", X. Tao, G. Kehr, X. Wang, C. G. Daniliuc, S. Grimme, G. Erker, Chem. Eur. J. 2016, 22, 9504-9507. doi: 10.1002/chem.201602058
“Pentamethylcyclopentadienyltitanium aryl(pyridyl)amide complexes: Synthesis, characterization and catalytic performance for olefin polymerization”, Q. Zhang, X. Tao*, T. Song, Y. Mu*, J. Organomet. Chem. 2016, 804, 18-25.
“New Titanium(IV) Complexes with 2-Cyclopentadienylbenzylamido Ligands: Synthesis, Characterization, and Catalytic Properties for Ethylene Polymerization and Copolymerization with 1-Hexene”, Xin Tao, Qiaolin Wu, Hang Huo, Wei Gao, and Ying Mu, Organometallics 2013, 32, 4815.
“Achiral Cs-Symmetric Half-Sandwich Scandium(III) Complexes with Imine-Cyclopentadienyl Ligands Catalyze Isotactic Polymerization of 1-Hexene”, Xin Tao, Wei Gao, Hang Huo, and Ying Mu, Organometallics 2013, 32, 1287.
“New Chromium(III) Complexes with Imine-Cyclopentadienyl Ligands: Synthesis, Characterization, and Catalytic Properties for Ethylene Polymerization”, Lei Zhang, Wei Gao, Xin Tao, Qiaolin Wu, Ying Mu, and Ling Ye, Organometallics 2011, 30, 433.