2021

T. Lübbering, P. D. Dutschke, A. Hepp, F. E. Hahn
Reactivity of Ruthenium(II) Complexes Bearing Bis-NHC Ligands
Organometallics 2021, 40, 3775–3784.

S. Termühlen, L. F. B. Wilm, P. D. Dutschke, A. Hepp, F. E. Hahn
Synthesis of Heterobimetallic Complexes through Chemoselective 2,4-Metalation of a Thiazolium Salt
Organometallics 2021, 40, 1565–1570.

A. Gutiérrez-Blanco, C. Dobbe, A. Hepp, C. G. Daniliuc, M. Poyatos, F. E. Hahn, E. Peris
"Synthesis and Characterization of Poly-NHC-Derived Silver (I) Assemblies and Their Transformation into Poly-Imidazolium Macrocycles"
Eur. J. Inorg. Chem. 2021, 2442-2451.

A. Herve, M. C. Jahnke, F. E. Hahn
"Synthesis of NHC Complexes with an N-(2-Oxopropyl) Group"
Z. Anorg. Allg. Chem. 2021, 647, 1145–1150.

M. D. Böhme, L. F. B. Wilm, A. Hepp, F. E. Hahn
"Regioselective Double Oxidative Addition of Bis-NHC Precursors"
Eur. J. Inorg. Chem. 2021, 1971-1975.

D. Belotti, F. Kampert, M. C. Jahnke, F. E. Hahn
"Oxidative addition of a 8-bromotheobromine derivative to d10 metals"
Z. Naturforsch. 2021, 76b, 227-235.

M. C. Jahnke, R. M. C. Pichl, F. E. Hahn
"Oxidative Addition von 2-Halogenopyridines and 2-Chloroquinoline to Zero-Valent Group 10 Metals"
Z. Anorg. Allg. Chem. 2021, 647, 448-455.

V. Tegethoff, T. Lübbering, C. Schulte to Brinke, B. Schirmer, J. Neugebauer, F. E. Hahn
"Synthesis of Ruthenium(II) Complexes Bearing Macrocyclic [11]ane-P2CNHC Ligands by a Template-Controlled Domino Reaction"
Organometallics 2021, 40, 606-617.

S. Bai, L.-L. Ma, T. Yang, F. Wang, L.-F. Wang, F. E. Hahn, Y.-Y. Wang, Y.-F. Han
"Supramolecular-induced regiocontrol over the photochemical [4 + 4] cyclodimerization of NHC or azole-substituted anthracenes"
Chem. Sci. 2021, 12, 2165-2171.

S. Termühlen, J. Blumenberg, A. Hepp, C. G. Daniliuc, F. E. Hahn
"Preparation of Complexes Bearing N-Alkylated, Anionic or Protic CAACs Through Oxidative Addition of 2-Halogenoindole Derivatives"
Angew. Chem. 2021, 133, 2631-2634; Angew. Chem. Int. Ed. 2021, 60, 2599-2602.

M. C. Jahnke, A. Herve, F. Kampert, F. E. Hahn
"Synthesis of palladium complexes with anionic N,NR- or neutral NH,NR-theophylline-derived NHC ligands"
Inorg. Chim. Acta 2021, 515, 120055.

2020

P. D. Dutschke, S. Bente, C. G. Daniliuc, J. Kinas, A. Hepp, F. E. Hahn
"Chemoselective synthesis of heterobimetallic bis-NHC complexes"
Dalton Trans. 2020, 49, 14388-14392.

C. B. Dobbe, A. Gutierrez-Blanco, T. T. Y. Tan, A. Hepp, M. Poyatos, E. Peris, F. E. Hahn
"Template-Controlled Synthesis of Polyimidazolium Salts by Multiple [2+2] Cycloaddition Reactions"
Chem. Eur. J. 2020, 26, 11565-11570.

J. Blumenberg, F. Kampert, A. Hepp, F. E. Hahn
"Synthesis of Ir^III Hydrido Complexes by Oxidative Addition of Halogenated Theophylline and Adenine Derivatives"
ACS Omega 2020, 5, 16951-16958.

Y. Li, Y.-Y. An, J.-Z. Fan, X.-X. Liu, X. Li, F. E. Hahn, Y.-Y. Wang, Y.-F. Han
"Strategy for the Construction of Diverse Poly-NHC-Derived Assemblies and Their Photoinduced Transformations"
Angew. Chem. 2020, 132, 10159–10166; Angew. Chem. Int. Ed. 2020, 59, 10073–10080.

J. Blumenberg, L. F. B. Wilm, F. E. Hahn
"Synthesis of Pd^II Complexes Bearing pNHC Ligands by Oxidative Addition of 8‑Halogenotheophyllines and 8‑Bromoadenine to Pd⁰"
Organometallics 2020, 39, 1281−1287.

R. N. Osorio Yáñez, A. Hepp, T. T. Y. Tan, F. E. Hahn
"Synthesis of Rh^III and Ir^III Complexes Bearing Chelating Di-NHC Ligands Obtained from N9-Imidazolium-Substituted Adenine"
Organometallics 2020, 39, 344−352.

2019

A. Gutierrez-Blanco, S. Iba´n~ez, F. E. Hahn, M. Poyatos, E. Peris
"A Twisted Tetragold Cyclophane from a Fused Bis-Imidazolindiylidene"
Organometallics 2019, 38, 4565-4569.

R. Das, J. Blumenberg, C. G. Daniliuc, D. Schnieders, J. Neugebauer, Y.-F. Han, F. E. Hahn
"Regioselective N- and C‑Metalation of Neutral 2‑Halogenobenzimidazole Derivatives"
Organometallics 2019, 38, 3278−3285.

L.-Y. Sun, T. Feng, R. Das, F. E. Hahn, Y.-F. Han
"Synthesis, Characterization, and Properties of Tetraphenylethylene-Based Tetrakis-NHC Ligands and Their Metal Complexes"
Chem. Eur. J. 2019, 25, 9764–9770.

L. Zhang, R. Das, C.-T. Li, Y.-Y. Wang, F. E. Hahn, K. Hua, L.-Y. Sun, Y.-F. Han
"C3-Symmetric Assemblies from Trigonal Polycarbene Ligands and MI Ions for the Synthesis of Three-Dimensional Polyimidazolium Cations"
Angew. Chem. 2019, 131, 13494–13498; Angew. Chem. Int. Ed. 2019, 58, 13360–13364.

C. Mühlen, J. Linde, L. Rakers, T. T. Y. Tan, F. Kampert, F. Glorius, F. E. Hahn
"Synthesis of Iron(0) Complexes Bearing Protic NHC Ligands: Synthesis and Catalytic Activity"
Organometallics 2019, 38, 2417−2421.

T. T. Y. Tan, F. E. Hahn
"Synthesis of Iridium(III) and Rhodium(III) Complexes Bearing C8-Metalated Theophylline Ligands by Directed C–H Activation"
Organometallics 2019, 38, 2250–2258.

M. Böhmer, G. Guisado-Barrios, F. Kampert, F. Roelfes, T. T. Y. Tan, E. Peris, F. E. Hahn
"Synthesis and Catalytic Applications of Heterobimetallic Carbene Complexes Obtained via Sequential Metalation of Two Bisazolium Salts"
Organometallics 2019, 38, 2120–2131.

S. Cepa, M. Böhmer, F. Roelfes, T. T. Y. Tan, F. Dielmann, F. E. Hahn
"Homo- and Heterodinuclear Head-to-Head or Head-to-Tail Complexes of Rhodium(I) and Iridium(I) with C2,N3 or C8,N9 Bridging Azolato Ligands"
Organometallics 2019, 38, 1982–1990.

W.-L. Shan, Y.-J. Lin, F. E. Hahn, G.-X. Jin
"Highly Selective Synthesis of Iridium(III) Metalla[2]​catenanes through Component Pre-​Orientation by π···π Stacking"
Angew. Chem. 2019, 131, 5941–5946; Angew. Chem. Int. Ed. 2019, 58, 5882-5886.

L.-L. Ma, Y.-Y. An, L.-Y. Sun, Y.-Y. Wang, F. E. Hahn, Y.-F. Han
"Supramolecular Control of Photocycloadditions in Solution: In Situ Stereoselective Synthesis and Release of Cyclobutanes"
Angew. Chem. 2019, 131, 4026–4031; Angew. Chem. Int. Ed. 2019, 58, 3986–3991.

L. Gök Pezük, B. Şen, F. E. Hahn, H. Türkmen
"Heterobimetallic Complexes Bridged by Imidazol{[4,5‑f][1,10]-phenanthrolin}-2-ylidene: Synthesis and Catalytic Activity in Tandem Reactions"
Organometallics 2019, 38, 593−601.

T. T. Y. Tan, S. Schick, F. E. Hahn
"Synthesis and Reactivity of Ir^III Complexes Bearing C‑Metalated Pyrazolato Ligands"
Organometallics 2019, 38, 567−574.

2018

Y.-S. Wang, T. Feng, Y.-Y. Wang, F. E. Hahn, Y.-F. Han
"Homo- and Heteroligand Poly-NHC Metal Assemblies: Synthesis by Narcissistic and Social Self-Sorting"
Angew. Chem. 2018, 130, 15993–15997; Angew. Chem. Int. Ed. 2018, 57, 15767–15771.

F. Kampert, D. Brackemeyer, T. T. Y. Tan, F. E. Hahn
"Selective C8-Metalation of Purine Nucleosides via Oxidative Addition"
Organometallics 2018, 37, 4181–4185.

S. Bente, F. Kampert, T. T. Y. Tan, F. E. Hahn
"Site-selective metallation of dicarbene precursors"
Chem. Commun. 2018, 54, 12887–12890.

M. Böhmer, F. Kampert, T. T. Y. Tan, G. Guisado-Barrios, E. Peris, F. E. Hahn
"Ir^III/Au^I and Rh^III/Au^I Heterobimetallic Complexes as Catalysts for the Coupling of Nitrobenzene and Benzylic Alcohol"
Organometallics 2018, 37, 4092−4099.

F. Aznarez, W.-X. Gao, Y.-J. Lin, F. E. Hahn, G.-X. Jin
"Preparation of polynuclear NHC complexes by post-synthetic modification of half-sandwich rhodium and iridium complexes bearing C-azolato ligands"
Dalton Trans. 2018, 47, 9442–9452.

M. Tegethoff, F. Roelfes, C. Schulte to Brinke, T. T. Y. Tan, F. Kampert, G.-X. Jin, F. E. Hahn
"Synthesis of Heterobimetallic Complexes by Coordination of Rhodium(III) and Iridium(III) Poly-N,O-NHC Complexes to Silver(I), Copper(II), and Zinc(II)"
Organometallics 2018, 37, 1801−1812.

L.-Y. Sun, N. Sinha, T. Yan, Y.-S. Wang, T. T. Y. Tan, L. Yu, Y.-F. Han, F. E. Hahn
"Template Synthesis of Three-Dimensional Hexakisimidazolium Cages"
Angew. Chem. 2018, 130, 5256–5261; Angew. Chem. Int. Ed. 2018, 57, 5161–5165

Q.-J. Fan, Y.-J. Lin, F. E. Hahn, G.-X. Jin
"Host–guest capability of a three-dimensional heterometallic macrocycle"
Dalton Trans. 2018, 47, 2240–2246

K. Y. Wan, F. Roelfes, A. J. Lough, F. E. Hahn, R. H. Morris
"Iridium and Rhodium Complexes Containing Enantiopure Primary Amine-Tethered N‑Heterocyclic Carbenes: Synthesis, Characterization, Reactivity, and Catalytic Asymmetric Hydrogenation of Ketones"
Organometallics 2018, 37, 491–504.

2017

K. Sato, T. T. Y. Tan, F. Schäfers, F. E. Hahn, D. W. Stephan
"Imidazole-stabilized, electron-deficient boron cations"
Dalton Trans. 2017, 47, 16404–16407.

N. Sinha, T. T. Y. Tan, E. Peris, F. E. Hahn
"High-Fidelity, Narcissistic Self-Sorting in the Synthesis of Organometallic Assemblies from Poly-NHC Ligands"
Angew. Chem. 2017, 129, 7499–7503; Angew. Chem. Int. Ed. 2017, 56, 7393–7397.

H. Jin, P. Kluth, F. E. Hahn
"Synthesis of Complexes with Protic NH,NR-NHC Ligands by Oxidative Addition of N-Alkyl-2-iodoimidazoles to [M(PPh₃)₄] (M = Pd, Pt) Complexes"
Eur. J. Inorg. Chem. 2017, 2774-2781.

H. Jin, C. Mück-Lichtenfeld, A. Hepp, D. W. Stephan, F. E. Hahn
"Small Molecule Activation with N,NR-MIC Platinum Complexes"
Chem. Eur. J. 2017, 23, 5943–5947.

N. Sinha, F. Roelfes, A. Hepp, F. E. Hahn
"Single-Step Synthesis of Organometallic Molecular Squares from NR,NR',NR'',NR'''-Substituted Benzobiscarbenes"
Chem. Eur. J. 2017, 23, 5939–5942.

D. Brackemeyer, C. Schulte to Brinke, F. Roelfes, F. E. Hahn
"Regioselective C8-metalation of N-phosphine tethered adenine derivatives via C8–H activation"
Dalton Trans. 2017, 46, 4510–4513.

D. Paul, F. Heins, S. Krupski, A. Hepp, C. G. Daniliuc, K. Klahr, J. Neugebauer, F. Glorius, F. E. Hahn
"Synthesis and Reactivity of Intramolecularly NHC-Stabilized Germylenes and Stannylenes"
Organometallics 2017, 36, 1001–1008.

N. Sinha, L. Stegemann, T. T. Y. Tan, N. L. Doltsinis, C. A. Strassert, F. E. Hahn
"Turn-On Fluorescence in Tetra-NHC Ligands by Rigidification through Metal Complexation: An Alternative to Aggregation-Induced Emission"
Angew. Chem. 2017, 129, 2829–2833; Angew. Chem. Int. Ed. 2017, 56, 2785–2789. 

M. Meier, T. T. Y. Tan, F. E. Hahn, H. V. Huynh
"Donor Strength Determination of Benzoxazolin-2-ylidene, Benzobisoxazolin-2-ylidene, and Their Isocyanide Precursors by ¹³C NMR Spectroscopy of Their Pd^II and Au^I Complexes"
Organometallics 2017, 36, 275-284.

2016

R. M. C. Branzan, J. Kösters, M. C. Jahnke, F. E. Hahn
"Oxidative addition of N-ether-functionalized 2-chlorobenzimidazole to d¹⁰ metals"
Z. Naturforsch. 2016, 71b, 1077-1085.

F. Aznarez, M. Iglesias, A. Hepp, B. Veit, P. J. Sanz Miguel, L. A. Oro, G.-X. Jin, F. E. Hahn
"Iridium(III) Complexes Bearing Chelating Bis-NHC Ligands and Their Application in the Catalytic Reduction of Imines"
Eur. J. Inorg. Chem. 2016, 4598–4603.

W. Wang, L. Zhao, H. Lv, G. Zhang, C. Xia, F. E. Hahn, F. Li
"Modular “Click” Preparation of Bifunctional Polymeric Heterometallic Catalysts"
Angew. Chem. 2016, 127, 7795−7800; Angew. Chem. Int. Ed. 2016, 55, 7665−7670.

R. A. Khan, F. Dielmann, X. Liu, F. E. Hahn, K. Al-Farhan, A. Alsalme, J. Reedijk
"Tetrahedrally coordinated luminescent copper(I) compounds containing halide, phosphane and norharmane ligands"
Polyhedron 2016, 111, 173−178.

F. Aznarez, P. J. Sanz Miguel, T. T. Y. Tan, F. E. Hahn
"Preparation of Rhodium(III) Di-NHC Chelate Complexes Featuring Two Different NHC Donors via a Mild NaOAc-Assisted C−H Activation"
Organometallics 2016, 35, 410−419.

M. Jaafar, X. Liu, F. Dielmann, F. E. Hahn, K. Al-Farhan, A. Alsalme, J. Reedijk
"Synthesis, structure and spectroscopic properties of bis(triphenylphosphane)iminium (chlorido) cyanido)argentates(I)"
Inorg. Chim. Acta 2016, 443, 45−50.

2015

S. Cepa, C. Schulte to Brinke, F. Roelfes, F. E. Hahn
"Hydrogen Activation by an Iridium(III) Complex Bearing a Bidentate Protic NH,NR-NHC^Phosphine Ligand"
Organometallics 2015, 34, 5454-5460.

H. Jin, T. T. Y. Tan, F. E. Hahn
"Synthesis of Complexes with Abnormal "Protic" N-Heterocyclic Carbenes"
Angew. Chem. 2015, 127, 14016–14020; Angew. Chem. Int. Ed. 2015, 54, 13811–13815.

C. Schulte to Brinke, F. E. Hahn
"Synthesis of a flexible macrocyclic tetraimidazolium salt–precursor for a tetracarbene ligand with metal dependent coordination modes"
Dalton Trans. 2015, 44, 14315–14322.

D. Lewing, H. Koppetz, F. E. Hahn
"Reversible Formation and Transmetalation of Schiff-Base Complexes in Subcomponent Self-Assembly Reactions"
Inorg. Chem. 2015, 54, 7653–7659.

C. Schulte to Brinke, F. E. Hahn
"Trinuclear Heterobimetallic Complexes by Stepwise Metalation of a Macrocyclic Tetraimidazolium Salt"
Eur. J. Inorg. Chem. 2015, 3227–3231.

L. Zhang, T. Yan, Y.-F. Han, F. E. Hahn, G.-X. Jin  
"Synthesis of a new type of alkene metal complex using face-capping thione-alkene ligands"
Dalton Trans. 2015, 44, 8797–8800

Y.-F. Han, G.-X. Jin, C. G. Daniliuc, F. E. Hahn
"Reversible Photochemical Modifications in Dicarbene-Derived Metallacycles with Coumarin Pendants"
Angew. Chem. 2015, 127, 5042–5046; Angew. Chem. Int. Ed. 2015, 54, 4958–4962.

S. Krupski, C. Schulte to Brinke, H. Koppetz, A. Hepp, F. E. Hahn
"Protic N-Heterocyclic Germylenes and Stannylenes: Synthesis and Reactivity"
Organometallics 2015, 34, 2624–2631.

A. Alsalme, M. Jaafar, X. Liu, F. Dielmann, F. E. Hahn, K. Al-farhan, J. Reedijk
"Synthesis, structure and spectroscopic properties of bis(triphenylphosphane)iminium (phenylacetylido)(cyanido)aurate(I) monoacetone monohydrate, (PPN)[Au(CΞN)(CΞC-C₆H₅)]·H₂O·(CH₃)₂CO and bis(triphenylphosphane)iminium (t-butylacetylido)(cyanido)aurate(I) monohydrate, (PPN)[Au(CΞN)(CΞC-C₄H₉)]·H₂O"
Polyhedron 2015, 88, 1–5.