ProjectFundamental Studies on Lithium-Ion Batteries with High Specific Energy Density (2018 – 2020)Individual Granted Project: DFG - Individual Grants Programme | Project Number: LI 2916/2-1; WI 2929/14-1Publications 20202016201520142013201120102009200820072006200420032020Zhang, ., Wang, ., Li, ., Schuck, ., Winter, ., Schumacher, . and Li, ., 2020. Preferential occupation of Na in P3-type layered cathode material for sodium ion batteries: Nano Energy, xx doi: 10.1016/j.nanoen.2020.104535.2., S.F., Zhou, ., He, ., Osenberg, ., Dong, ., Chen, ., Mei, ., Hilger, ., Markoetter, ., Lu, ., Dong, ., Marathe, ., Rau, ., Hou, ., Li, ., Stan, ., Winter, ., Dominko, . and Manke, ., 2020. Morphological Reversibility of Modified Li-Based Anodes for Next-Generation Batteries: ACS Energy Letters, 5Wang, ., Li, ., He, ., Zhang, ., Yan, ., Hou, ., Du, ., Placke, ., Winter, . and Li, ., 2020. A Three-Dimensional TiO2-Graphene Architecture with Superior Li Ion and Na Ion Storage Performance: Journal of Power Sources, 461, p. 228129. doi: 10.1016/j.jpowsour.2020.228129.Guillon, O. eds., 2020. Advanced ceramics for energy conversion and storage. doi: 10.1016/B978-0-08-102726-4.00010-7.2016Risthaus, ., Wang, ., Friesen, ., Krafft, ., Kolek, . and Li, ., 2016. Synthesis of LiNi0.5Mn1.5O4 Cathode Materials with Different Additives. Effects on Structural, Morphological and Electrochemical Properties.: Journal of The Electrochemical Society, 163 doi: 10.1149/2.1231609jes.Qi, ., Tao, ., Hahn, ., Schultz, ., Gallus, ., Cao, ., Nowak, ., Röser, ., Li, ., Cekic-Laskovic, ., Rad, . and Winter, ., 2016. Lifetime limit of tris(trimethylsilyl) phosphite as electrolyte additive for high voltage lithium ion batteries: RSC Advances, 6, pp. 38342–38349. doi: 10.1039/C6RA06555D.He, ., Wang, ., Wang, ., Qiu, ., Frielinghaus, ., Niehoff, ., Liu, ., Stan, ., Paillard, ., Winter, . and Li, ., 2016. 3D Porous Li-rich cathode material with in situ modified surface for high performance lithium ion batteries with reduced voltage decay: J. Mater. Chem. A., xxxxLi, ., Liu, ., Hu, ., Wang, ., Niehoff, ., He, ., Eder, ., Winter, . and Paillard, ., 2016. Hierarchical Ternary MoO2/MoS2/Heteroatom-Doped Carbon Hybrid Material for High-Performance Lithium-Ion Storage: ChemElectroChem, xxxx doi: 10.1002/celc.201600062.Jia, ., Kloepsch, ., He, ., Evertz, ., Nowak, ., Li, ., Winter, . and Placke, ., 2016. Nanostructured ZnFe2O4 as Anode Material for Lithium Ion Batteries: Ionic Liquid-Assisted Synthesis and Performance Evaluation with Special Emphasis on Comparative Metal Dissolution: Acta Chimica Slovenica, 63(3), pp. 470–483. doi: 10.17344/acsi.2016.2243.Meister, ., Jia, ., Li, ., Klöpsch, ., Winter, . and Placke, ., 2016. Best Practice: Performance and Cost Evaluation of Lithium Ion Battery Active Materials with Special Emphasis on Energy Efficiency: Chemistry of Materials, 28, pp. 7203–7217. doi: 10.1021/acs.chemmater.6b02895.Cao, ., He, ., Wang, ., Liu, ., Röser, ., Rezaei, R.B., Evertz, ., Streiprt, ., Li, ., Wagner, ., Winter, . and Cekic-Laskovic, ., 2016. High Voltage LiNi0.5Mn1.5O4/Li4Ti5O12 Lithium Ion Cells at Elevated Temperatures: Carbonate- vs. Ionic Liquid-Based Electrolytes: ACS applied materials & interfaces, 2016 doi: 10.1021/acsami.6b07687.Liu, ., Hu, ., Wang, ., Niehoff, ., He, ., Paillard, ., Eder, ., Winter, . and Li, ., 2016. Hierarchical Ternary MoO2/MoS2/Heteroatom-Doped Carbon Hybrid Materials for High-Performance Lithium-Ion Storage: ChemElectroChem, 3, pp. 922–932. doi: 10.1002/celc.201600062.Wang, ., He, ., Zhou, ., Schappachera, ., Zhang, ., Liu, ., Stan, .C., Cao, ., Kloepsch, ., Sofya, .S., Schumacherb, . and Li, ., 2016. O3-type Na[Fe1/3Ni1/3Ti1/3]O2 cathode material for rechargeable sodium ion batteries: J. Mater. chem. A, 4, pp. 3431–3437. doi: 10.1039/C5TA10520J.Liu, ., Wang, ., Zhang, ., Zhou, ., Qi, ., Qiu, ., Fang, ., Kloepsch, ., Schumacher, ., Liu, . and Li, ., 2016. Morphological Evolution of High-Voltage Spinel LiNi0.5Mn1.5O4 Cathode Materials for Lithium-Ion Batteries: the Critical Effects of Surface Orientations and Particle Size: ACS Appl. Mater. Interfaces, 8, pp. 4661–4675. doi: 10.1021/acsami.5b11389.Rana, J., Kloepsch, R., Li, J., Stan, M., Schumacher, G., Winter, M. and Banhart, J., 2016. Structural Changes in a Li-Rich 0.5Li2MnO3*0.5LiMn0.4Ni0.4Co0.2O2 Cathode Material for Li-Ion Batteries: A Local Perspective. doi: 10.1149/2.0211606jes.2015Buchholz, D., Li, J., Passerini, S., Aquilanti, G., Wang, D. and Giorgetti, M., 2015. X‐ray Absorption Spectroscopy Investigation of Lithium‐Rich, Cobalt‐Poor Layered‐Oxide Cathode Material with High Capacity.Liu, ., Kloepsch, ., Wang, ., Winter, . and Li, ., 2015. Truncated octahedral LiNi0.5Mn1.5O4 cathode material for ultralong-life lithium-ion battery: Positive (100) surfaces in high-voltage spinel system: Journal of Power Sources, 300, p. 430. doi: 10.1016/j.jpowsour.2015.09.066.He, ., Wang, ., Jia, ., Kloepsch, ., Liu, ., Beltrop, . and Li, ., 2015. Ionic liquid-assisted solvothermal synthesis of hollow Mn2O3 anode and LiMn2O4 cathode materials for Li-ion batteries: Journal of Power Sources, 293 doi: 10.1016/j.jpowsour.2015.04.106.Qi, ., Blizanac, ., DuPasquier, ., Lal, ., Niehoff, ., Placke, ., Oljaca, ., Li, . and Winter, ., 2015. Influence of Thermal Treated Carbon Black Conductive Additive on the Performance of High Voltage Spinel Cr-Doped LiNi0.5Mn1.5O4 Composite Cathode Electrode: Journal of The Electrochemical Society, 162(3), pp. A339–A343. doi: 10.1149/2.0401503jes.Bhaskar, ., Krüger, ., Sozios, ., Li, ., Nowak, . and Winter, ., 2015. Synthesis and characterization of high-energy high-power spinel-layered composite cathode materials for lithium ion batteries: Advanced Energy Materials, 5(5) doi: 10.1002/aenm.201401156.Risthaus, ., Wang, ., Friesen, ., Wilken, ., Berghus, ., Winter, . and Li, ., 2015. Synthesis of spinel LiNi0.5Mn1.5O4 with secondary plate morphology as cathode material for lithium ion batteries: Journal of Power Sources, 293, pp. 137–142. doi: 10.1016/j.jpowsour.2015.05.056.2014Elia, G.A., Wang, J., Bresser, D., Li, J., Scrosati, B., Passerini, S. and Hassoun, J., 2014. A New, High Energy Sn–C/Li [Li0. 2Ni0. 4/3Co0. 4/3Mn1. 6/3] O2 Lithium-Ion Battery.Wang, Jun, He, Xin, Kloepsch, Richard, Wang, Sihui, Hoffmann, Bjoern, Jeong, Sangsik, Yang, Yong, Li and Jie, 2014. Increased Capacity of LiNi1/3Co1/3Mn1/3O2–Li [Li1/3Mn2/3] O2 Cathodes by MnOx‐surface Modification for Lithium‐Ion Batteries.He, ., Wang, ., Kloepsch, ., Krueger, ., Jia, ., Liu, ., Vortmann, . and Li, ., 2014. Enhanced electrochemical performance in lithium ion batteries of a hollow spherical lithium-rich cathode material synthesized by a molten salt method: Nano Research, 7(1), pp. 110–118. doi: 10.1007/s12274-013-0378-7.Qi, ., Blizanac, ., DuPasquier, ., Placke, ., Meister, ., Oljaca, ., Li, . and Winter, ., 2014. Investigation of PF6- and TFSI- anion intercalation into graphitized carbon blacks and its influence on high voltage lithium ion batteries: Physical Chemistry Chemical Physics, 16, pp. 25306–25313. doi: 10.1039/C4CP04113E.Wang, ., He, ., Kloepsch, ., Wang, ., Hoffmann, ., Jeong, ., Yang, . and Li, ., 2014. Increased Capacity of LiNi1/3Co1/3Mn1/3O2-Li[Li1/3Mn2/3]O2 Cathodes by MnOx-surface Modification for Lithium-Ion Batteries: Energy Technology, 2014(2), pp. 188–193. doi: 10.1002/ente.201300127.Rana, ., Kloepsch, ., Li, ., Scherb, ., Schumacher, ., Winter, . and John, ., 2014. On the structural integrity and electrochemical activity of 0.5Li2MnO3·0.5LiCoO2 cathode material for lithium-ion batteries: Journal of Materials Chemistry A, 2(24), pp. 9099–9110. doi: 10.1039/c4ta01161a.2013Stan Marian Cristian, K.R., Bhaskar Aiswarya, .J. and Passerini Stefano, W.M., 2013. Cu3P Binary Phosphide: Synthesis via a Wet Mechanochemical Method and Electrochemical Behavior as Negative Electrode Material for Lithium-Ion Batteries: Advanced Energy Materials, 3(2), pp. 231–238. doi: 10.1002/aenm.201200655.Dippel, ., Krüger, ., Klöpsch, ., Hoffmann, ., Nowak, ., Niehoff, ., Li, ., Passerini, . and Winter, ., 2013. Aging of Li2FeSiO4 Cathode Material in Fluorine containing organic Electrolytes for Lithium-Ion Batteries: Electrochmica Acta, 85, pp. 66–71. doi: 10.1016/j.electacta.2012.07.109.Krüger, ., Klöpsch, ., Li, ., Nowak, ., Passerini, . and Winter, ., 2013. How Do Reactions at the Anode/Electrolyte Interface Determine the Cathode Performance in Lithium-Ion Batteries?: Journal of The Electrochemical Society, 160(4), pp. A542–A548. doi: 10.1149/2.022304jes.Dippel, ., Krüger, ., Kraft, ., Nowak, ., Winter, . and Li, ., 2013. Aging Stability of Li2FeSiO4 Polymorphs in LiPF6 Containing Organic Electrolyte for Lithium-Ion Batteries: Electrochmica Acta, 105, pp. 542–546. doi: 10.1016/j.electacta.2013.05.013.Li, ., Jeong, ., Kloepsch, ., Winter, . and Passerini, ., 2013. Improved electrochemical performance of LiMO2 (M=Mn, Ni, Co)--Li2MnO3 cathode materials in ionic liquid-based electrolyte: Journal of Power Sources, 239, pp. 490–495. doi: 10.1016/j.jpowsour.2013.04.015.Rana, ., Stan, ., Kloepsch, ., Li, ., Schumacher, ., Welter, ., Zizak, ., Banhart, . and Winter, ., 2013. Structural Changes in Li2MnO3 Cathode Material for Li-Ion Batteries: Advanced Energy Materials, 4(5) doi: 10.1002/aenm.201300998.Qi, X., Blizanac, B., DuPasquier, A., Oljaca, M., Li, J. and Winter, M., 2013. Understanding the influence of conductive carbon additives surface area on the rate performance of LiFePO 4 cathodes for lithium ion batteries.Wang, Jun, He, Xin, Paillard, Elie, Liu, Haidong, Passerini, Stefano, Winter, Martin, Li and Jie, 2013. Improved rate capability of layered Li-rich cathode for lithium ion battery by electrochemical treatment.2011Li, ., Klöpsch, ., Stan, ., Nowak, ., Kunze, ., Passerini, . and Winter, ., 2011. Synthesis and electrochemical performance of the high voltage cathode material Li[Li0.2MnO0.56Ni0.16Co0.08]O2 with improved rate capability: Journal of Power Sources, 196(10), pp. 4821–4825. doi: 10.1016/j.jpowsour.2011.01.006.Li, ., Klöpsch, ., Nowak, ., Kunze, ., Winter, . and Passerini, ., 2011. Investigations on cellulose-based high voltage composite cathodes for lithium ion batteries: Journal of Power Sources, 196, pp. 7687–7691. doi: 10.1016/j.jpowsour.2011.04.030.2010He, G., Li, Y., Li, J. and Yang, Y., 2010. Spinel LiMn2− x Ti x O4 (x= 0.5, 0.8) with High Capacity and Enhanced Cycling Stability Synthesized by a Modified Sol-Gel Method.2009Yao, W., Zhang, Z., Gao, J., Li, J., Xu, J., Wang, Z. and Yang, Y., 2009. Vinyl ethylene sulfite as a new additive in propylene carbonate-based electrolyte for lithium ion batteries.2008Gong, ., Li, ., He, ., Li, . and Yang, ., 2008. Nanostructured Li2FeSiO4 electrode material synthesized through hydrothermal-assisted sol-gel process.Guo, X.-J., Li, Yi.-X., Zheng, M., Zheng, J.-M., Li, J., Gong, Z.-L. and Yang, Y., 2008. Structural and electrochemical characterization of xLi [Li 1/3 Mn 2/3] O 2·(1− x) Li [Ni 1/3 Mn 1/3 Co 1/3] O 2 (0≤ x≤ 0.9) as cathode materials for lithium ion batteries.Li, Jie, Yao, Wanhao, Meng, S, Y., Yang and Yong, 2008. Effects of vinyl ethylene carbonate additive on elevated-temperature performance of cathode material in lithium ion batteries.Zheng, ., Li, ., Zhang, ., Guo, . and Yang, ., 2008. The effects of TiO 2 coating on the electrochemical performance of Li [Li 0.2 Mn 0.54 Ni 0.13 Co 0.13] O 2 cathode material for lithium-ion battery.2007Li, J, Zheng, JM, Yang and Y, 2007. Studies on storage characteristics of LiNi0. 4Co0. 2Mn0. 4O2 as cathode materials in lithium-ion batteries.2006Jie, LI, 李劼, Jian-Ming, Zheng, 郑建明, Xiao-Jian, Guo, 郭晓健, Zheng-Liang, Gong, 龚正良, Yong, Yang and 杨勇, 2006. Preparation, characterization and electrochemical performance of LiNi0. 4Co0. 2Mn0. 4O2 as cathode materials in lithium ion battery.Li, J, Zhang, ZR, Guo, XJ, Yang and Y, 2006. The studies on structural and thermal properties of delithiated Li x Ni 1/3 Co 1/3 Mn 1/3 O 2 (0< x≤ 1) as a cathode material in lithium ion batteries.Zhang, ., Li, . and Yang, ., 2006. The effects of decomposition products of electrolytes on the thermal stability of bare and TiO 2-coated delithiated Li 1− x Ni 0.8 Co 0.2 O 2 cathode materials.2004Liu, H., Li, J., Zhang, Z., Gong, Z. and Yang, Y., 2004. Structural, electrochemical and thermal properties of LiNi 0.8− y Ti y Co 0.2 O 2 as cathode materials for lithium ion battery.2003Liu, H., Li, J., Zhang, Z., Gong, Z. and Yang, Y., 2003. The effects of sintering temperature and time on the structure and electrochemical performance of LiNi0. 8Co0. 2O2 cathode materials derived from sol-gel method.