Forschungsbericht 1995-96
	Organisch-Chemisches Institut Corrensstraße 40 D-48149 Münster Tel.: (0251) 83 - 3 32 10 Fax: (0251) 83 - 3 97 72

Forschungsschwerpunkte 1995 - 1996 Fachbereich 17 - Chemie The Organisch-Chemisches Institut Research group Dr. H. Luftmann

Research group Dr. H. Luftmann

The mass spectrometry laboratory is equipped with several mass spectrometers including double focussing magentic sector field-, ion trap- and laser desorption devices. Various ionization modes as electron impact (EI), chemical ionization (CI), field desorption (FD) and laser ionization (LDI. MALDI) and inlet systems like direct inlet (crucible, wire) gas chromatography and thermospray are available. Al- though this group serves primarily for service and educational purposes with a throughput of several thousand analyses per year, there are widespread scientific collaborations. A special point of interest is the development of laser desorption techniques and time of flight mass spectrometers. To the group belong two fulltime and a halftime technician, one chemist and additional student(s). Tel.: +049 (0)251 83 - 3 32 99, Telefax: +049 (0)251 83 - 3 97 72, email: luftman@uni-muenster.de

Publications:

Newkome, Gr., R. Guther, Cn. Moorefield, F. Cardullo, L. Echegoyen, E. Perezcordero, H. Luftmann: "Routes to Dendritic Networks: Bis Dendrimers by Coupling of Cascade Macromolecules through Metal Centers", Angew. Chem. Int.-Ed. in english 1995; 34 (18), 2023-2026.

Temme, B., G. Erker, J. Karl, H. Luftmann, R. Frohlich, S. Kotila: "Reaction of (butadiene)zirconocene with tris(pentafluorophenyl)borane: a Novel Way of Generating Methylalumoxane Free Homogeneous Ziegler Type Catalysts", Angew. Chem. Int. Ed. in english. 1995; 34 (16), 1755-1757.

Averdung, J., H. Luftmann, J. Mattay, Ku. Claus, W. Abraham: "Synthesis of 1,2-(2,3-Dihydro-1h-Azirino)-[60]Fullerene, The Parent Fullero-aziridine", Tetrahedr. Lett. 1995; 36 (17), 2957-2958.

Averdung, J., H. Luftmann, I. Schlachter, J. Mattay: "Aza dihydro[60]fullerene in the Gas Phase: a Mass Spectrometric and Quantumchemical Study", Tetrahedr. 1995; 51 (25), 6977-6982.

Averdung, J., G. Torresgarcia, H. Luftmann, I. Schlachter, J. Mattay (Reprint Author): "Progress in Fullerene Chemistry: from Exohedral Functionalization to Hetero-fullerenes", Fullerene Science And Technology 1996; 4 (4), 633-654.

Newkome, Gr., Bd. Woosley, Ef. He, Cn. Moorefield, R. Guther, Gr. Baker, Gh. Escamilla, J. Merrill, H. Luftmann: "Supramolecular Chemistry of Flexible, Dendritic Based Structures Employing Molecular Recognition", Chem. Comm. 1996; (24), 2737-2738.