Roman Kleinmans, M.Sc.

Roman Kleinmans
© Roman Kleinmans
Roman Kleinmans
PhD Student
Room 414, OC/BC I
Corrensstraße 36
48149 Münster
T: +49 251 8335319
F: +49 251 8339772
r_klei12@uni-muenster.de
External Profiles:
  • Curriculum Vitae

    since 12/2019 PhD thesis in the group of Prof. Dr. Frank Glorius, Westfälische Wilhelms-Universität Münster
    04/2019 - 09/2019 Master thesis in the group of Prof. Dr. Frank Glorius, Westfälische Wilhelms-Universität Münster
    09/2018 - 02/2019 Research stay in the group of Prof. Dr. Keary M. Engle, Scripps Research, La Jolla, CA, USA
    02/2018 - 03/2018 Research stay in the group of Prof. Dr. Yoshiaki Nakao, Kyoto University, Japan
    since 10/2017 MSc studies of Chemistry, Westfälische Wilhelms-Universität Münster, Germany
    06/2017 - 08/2017 Bachelor thesis in the group of Prof. Dr. Frank Glorius, Westfälische Wilhelms-Universität Münster, Germany
    10/2014 - 09/2017 BSc Studies of Chemistry at Westfälische Wilhelms-Universität Münster, Germany
    08/2011 - 06/2014 Technisches Gymnasium at the Berufskolleg Krefeld-Uerdingen (BKU) with Final School Examination (Abitur), Germany
  • Awards and Scholarships

    07/2020 - 06/2022 Kekulé-Scholarship of the Fonds der Chemischen Industrie
    09/2018 - 11/2018 PROMOS Scholarship
    10/2015 - 09/2019 ProTalent Scholarship, Westfälische Wilhelms-Universität Münster (Deutschlandstipendium/Almuth Klemer-Stipendium)
  • Publications

    R. Kleinmans,§ S. Dutta,§ K. Ozols, H. Shao, F. Schäfer, R. E. Thielemann, H. T. Chan, C. G. Daniliuc, K. N. Houk,* F. Glorius,*
    ortho-Selective Dearomative [2π + 2σ]-Photocycloadditions of Bicyclic Aza-Arenes,
    J. Am. Chem. Soc. 2023, 145, 12324-12332.
    § These authors contributed equally

    G. Tan, M. Das, R. Kleinmans, F. Katzenburg, C. Daniliuc, F. Glorius,
    Energy Transfer-Enabled Unsymmetrical Diamination Using Bifunctional Nitrogen-Radical Precursors,
    Nat. Catal. 2022, 5, 1120-1130.

    Y. Liang, R. Kleinmans, C. G. Daniliuc, F. Glorius,
    Synthesis of Polysubstituted 2-Oxabicyclo[2.1.1]hexanes via Visible-Light-Induced Energy Transfer,
    J. Am. Chem. Soc. 2022, 144, 20207-20213.

    F. Schäfers,§ S. Dutta,§ R. Kleinmans, C. Mück-Lichtenfeld, F. Glorius,
    Asymmetric Addition of Allylsilanes to Aldehydes – A Cr/Photoredox Dual Catalytic Approach Complementing the Hosomi–Sakurai Reaction,
    ACS Catal. 2022, 12, 12281-12290. DOI
    § These authors contributed equally
     

    R. Kleinmans,§ T. Pinkert,§ S. Dutta, T. O. Paulisch, H. Keum, C. G. Daniliuc, F. Glorius,
    Intermolecular [2π+2σ]-photocycloaddition enabled by triplet energy transfer,
    Nature 2022, 605, 477-482.

    § These authors contributed equally

    R. Kleinmans,§ O. Apolinar,§ J. Derosa, M. K. Karunananda, Z.-Q. Li, V. T. Tran, S. R. Wisniewski, K. M. Engle*,
    Ni-Catalyzed 1,2-Diarylation of Alkenyl Ketones: A Comparative Study of Carbonyl-Directed Reaction Systems,
    Org. Lett. 2021, 23, 5311–5316.
    § Both authors contributed equally.

    R. Kleinmans, L. E. Will, J. L. Schwarz, F. Glorius,
    Photoredox-enabled 1,2-dialkylation of α-substituted acrylates via Ireland–Claisen rearrangement,
    Chem. Sci. 2021, 12, 2816-2822.

    R. Wethman, J. Derosa, V. T. Tran, T. Kang, O. Apolinar, A. Abraham, R. Kleinmans, S. R. Wisniewski*, J. R. Coombs*, K. M. Engle,*
    An Under-Appreciated Source of Reproducibility Issues in Cross-Coupling: Solid-State Decomposition of Primary Sodium Alkoxides in Air,
    ACS Catal. 2021, 11, 502-508.

    J. L. Schwarz,§ R. Kleinmans,§ T. O. Paulisch, F. Glorius,
    1,2-Amino Alcohols via Cr/Photoredox Dual-Catalyzed Addition of α‑Amino Carbanion Equivalents to Carbonyls,
    J. Am. Chem. Soc. 2020, 142, 2168-2174.
    § Both authors contributed equally.

    J. Derosa, R. Kleinmans,§ V. T. Tran,§ M. K. Karunananda, S. R. Wisniewski, M. D. Eastgate, K. M. Engle,*
    Nickel-Catalyzed 1,2-Diarylation of Simple Alkenyl Amides,
    J. Am. Chem. Soc. 2018, 140, 17878−17883.
    § Both authors contributed equally.

    M. Teders, C. Henkel, L. Anhäuser, F. Strieth-Kalthoff, A. Goméz-Suárez, R. Kleinmans, A. Kahnt, A. Rentmeister, D. M. Guldi,* F. Glorius,*
    The energy-transfer-enabled biocompatible disulfide–ene reaction,
    Nat. Chem. 2018, 10, 981-988.