Group of Prof. Dr. Bernt Krebs
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Bioinorganic chemistry of iron

Research group: Dr. Sascha Baldeau, Prof. Dr. Bernt Krebs

 

 

Cooperations

Prof. Dr. S. Schindler (Universität Giessen)

Publications:

  • M. Merkel, M. Pascaly, B. Krebs, J. Astner, S. P. Foxon, S. Schindler
    "Chelate Ring Size Variations and their Effects on Coordination Chemistry and Catechol Dioxygenase Reactivity of Iron(III) complexes"
    Inorg. Chem. 2005, angenommen.

  • M. Merkel, D. Schnieders, S. M. Baldeau, B. Krebs
    Structural snapshots of a dynamic coordination sphere in model complexes for catechol 1,2-dioxygenases"
    Eur. J. Inorg. Chem. 2004, 783

  • G. V. Nizova, B. Krebs, G. Süss-Fink, S. Schindler, L. Westerheide, L. Gonzales Cuervo and G. B. Shul´pin
    "Hydroperoxidation of methane and other alkanes with H2O2 catalyzed by a dinuclear iron complex and an amino acid"
    Tetrahedron 2002, 58, 9231

  • M. Merkel, F. K. Müller, B. Krebs
    "Novel iron(III) complexes with phenolate containing tripodal tetradentate ligands as model systems for catechol 1,2-dioxygenases"
    Inorg. Chim. Acta 2002, 337, 308

  • M. Pascaly, M. Duda, F. Schweppe, F. K. Müller, K. Zurlinden u. B. Krebs
    "The systematic influence of tripodal ligands on the catechol cleaving activity of iron(III) containing model compounds for catechol 1,2-dioxygenases"
    J. Chem. Soc. Dalton Trans. 2001, 6, 828

  • L. Westerheide, F. K. Müller, J. Dietrich, R. Than, B. Krebs u. S. Schindler
    "Synthesis and Structural Characterization of Dinuclear and Tetranuclear Iron(III) Complexes and their Reactions with Hydrogen Peroxide"
    Inorg. Chem. 2001, 40, 1951

  • L. Westerheide, M. Pascaly u. B. Krebs
    "Methane Monooxygenase and Its Related Biomimetic Models"
    Curr. Opin. in Chem. Biol. 2000, 4, 235

  • M. Pascaly, C. Nazzikol, F. Schweppe, A. Wiedemann, K. Zurlinden u. B. Krebs
    "Structures and Properties of Novel Mononuclear Iron(III) Complexes with Benzimidazole Containing Tripodal Ligands"
    Z. Anorg. Allg. Chem. 2000, 626, 50

  • F. Schweppe, H. Sirges, M. Pascaly, M. Duda, C. Nazzikol, W. Steinforth u. B. Krebs
    "Transition Metal Catalyzed Oxy-Functionalization of Catechol and Flavonol Derivatives"
    in: Peroxide Chemistry; Mechanistic and Preparative Aspects of Oxygen Transfer, Wiley-VCH 2000, S. 232

  • M. Pascaly, F.Schweppe u. B. Krebs
    "Electron transfer mediated substrate activation by model compounds for catechol 1,2-dioxygenase", J. Inorg. Biochem. 1999, 74, 260

  • R. Than, A. Schrodt, L. Westerheide, R. van Eldik u. B. Krebs
    "Structural and Functional Investigations on Diiron Complexes: Catalase-like Activity and Mechanistic Studies on the Formation of (µ-Peroxo)diiron(III) Adducts "
    Eur. J. Inorg. Chem. 1999, 1537

  • M. Pascaly, M. Duda, A. Rompel, B.H. Sift, W. Meyer-Klaucke u. B. Krebs
    "Novel iron(III) complexes with imidazole containing tripodal ligands as model systems for catechol dioxygenases"
    Inorg. Chim. Acta 1999, 291, 289

  • D. Harms, R. Than, B. Krebs u. U. Karst
    " Flow injection analysis of hydrogen peroxide in disinfectants. "
    Fresenius J. Anal. Chem. 1999, 364, 184

  • R. Than, A. A. Feldmann u. B. Krebs
    " Structural and functional studies on model compounds of purple acid phosphatases and catechol oxidases."
    Coord. Chem. Rev. 1998, 182, 209

  • D. Harms, R. Than, U. Pinkernell, M. Schmidt, B. Krebs u. U. Karst
    "Selective determination of hydrogen peroxide in household products using its molecular recognition by a dinuclear iron(III) complex."
    Analyst. 1998, 123, 2323

  • M. Duda, M. Pascaly u. B. Krebs
    "A highly reactive functional model for catechol 1,2-dioxagenase: reactivity studies of iron(III)-catecholate complexes of bis((2-pyridyl)methyl)((1-methylimidazol-2-yl)-methyl) amine."
    J. Chem. Soc., Chem. Commun. 1997, 835

  • B. Krebs, F. Ahlers, B. Bremer, B. Eulering, T. Klabunde, K. Schepers, M. Schmidt, N. Sträter, R. Than u. H. Witzel
    "Crystal structure of a purple acid phosphatase. Structural and functional studies on its model compounds. "
    In: " Bioinorganic Chemistry" 1997, 413

  • B. Eulering, M. Schmidt, U. Pinkernell, U. Karst u. B. Krebs
    "Ein unsymmetrischer dinuklearer Eisen(III)-Komplex mit Peroxidaseeigenschaften"
    Angew. Chem. 1996, 108, 2102; Angew. Chem. Int. Ed. Engl. 1996, 35, 1973

  • C. Nazikkol, R. Wegner, J. Bremer u. B. Krebs
    "Tripodal Ligands: Design of Distorted Coordination Polyhedra in Biomimetic Metal Complexes. Crystal Structures of [Zn(SCN)(ntb)](SCN)·iPrpOH and [Fe(acac)(ntb)](ClO4)2·2CH2Cl2·iPrpOH, ntb = N-tris(2-benzimidazolyl-methyl)amine"
    Z. Anorg. Allg. Chem. 1996, 622, 213

  • B. Eulering, M. Schmidt, U. Pinkernell, U. Karst u. B. Krebs
    "A New Unsymmetrical Model Compound for the Uteroferrin-Arsenato Complex and Oxidation of Different Substrates by Diferric Peroxo Complexes"
    J. Inorg. Biochem. 1995, 59, 403

  • B. Eulering, F. Ahlers, F. Zippel, M. Schmidt, H.-F. Nolting u. B. Krebs
    "The First Diferric Model Compound for the Uteroferrin-Arsenato Complex"
    J. Chem. Soc. Chem. Commun. 1995, 1305


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