PLACKE, Dr. Tobias


Tobias PlackeMEET - Münster Electrochemical Energy Technology
Raum: L.2.017
Corrensstraße 46
D-48149 Münster

Tel.: +49 251 83-36826
tobias.placke@uni-muenster.de

Position: Bereichsleiter Selected Materials

Forschungsschwerpunkte: Anodenmaterialien für Lithium-Ionen Batterien (Kohlenstoffe; Graphite; Silizium-, Zinn- und Germanium-basierte Anodenmaterialien; Konversionsmaterialien), Oberflächenmodifikationen von Anodenmaterialien, Untersuchung der "Solid Electrolyte Interphase", Dual-Ionen/Dual-Graphit Zellen und Anionen Interkalation in graphitische Kohlenstoffe

Dissertationsthema: DONOR- AND ACCEPTOR-TYPE GRAPHITE INTERCALATION COMPOUNDS FOR ELECTROCHEMICAL ENERGY STORAGE SYSTEMS - Surface Modifications of Graphite as Negative Electrode for Lithium Ion Intercalation in Lithium-ion Secondary Batteries and Study of Anion Intercalation into Graphite for Dual-ion Cells

  • Patentanmeldungen


    • M. Winter, S. Passerini, S. F. Lux, P. Bieker, T. Placke, H.-W. Meyer, "Electrochemical Cell"; application number: DE20111054119 20110930; priority number: DE20111054119 20110930; international publication number: WO 2013/045561 A1
    • M. Winter, S. Passerini, S. F. Lux, P. Bieker, T. Placke, H.-W. Meyer, "Electrochemical Cell"; application number: WO2012EP69103 20120927; priority number: DE20111054119 20110930; also published as: DE102011054119 (A1)
 
  • Publikationen

    • Fromm O, Heckmann A, Rodehorst U, Frerichs J, Becker D, Winter M, Placke T. . ‘Carbons from Biomass Precursors as Anode Materials for Lithium Ion Batteries: New Insights into Carbonization and Graphitization Behavior and into their Correlation to Electrochemical Performance.’ Carbon 128: 147-163. doi: 10.1016/j.carbon.2017.11.065.
    • Beltrop K, Qi X, Hering T, Röser S, Winter M, Placke T. . ‘Enabling Bis(fluorosulfonyl) Imide-Based Ionic Liquid Electrolytes for Application in Dual-Ion Batteries.’ Journal of Power Sources 373: 193–202. doi: 10.1016/j.jpowsour.2017.11.010.

    • Placke T, Kloepsch R, Dühnen S, Winter M. . ‘Lithium-Ion, Lithium Metal and Alternative Rechargeable Battery Technologies: The Odyssey for High Energy Density.’ Journal of Solid State Electrochemistry 21, Nr. 7: 1939-1964. doi: 10.1007/s10008-017-3610-7.
    • Meister P, Qi X, Kloepsch R, Krämer E, Streipert B, Winter M, Placke T. . ‘Anodic Behavior of the Aluminum Current Collector in Imide Based Electrolytes - Influence of the Solvent, the Operating Temperature and the Native Oxide Layer Thickness.’ ChemSusChem 10, Nr. 4: 804-814. doi: 10.1002/cssc.201601636.
    • Huesker J, Froböse L, Kwade A, Winter M, Placke T. . ‘In Situ Dilatometric Study of the Binder Influence on the Electrochemical Intercalation of Bis(trifluoromethanesulfonyl) imide Anions into Graphite.’ Electrochimica Acta 257: 423-435. doi: 10.1016/j.electacta.2017.10.042.
    • Holtstiege F, Wilken A, Winter M, Placke T. . ‘Running out of Lithium? A Route to Differentiate between Capacity Losses and Active Lithium Losses in Lithium-Ion Batteries.’ Physical Chemistry Chemical Physics 19: 25905-25918. doi: 10.1039/C7CP05405J.
    • Kasnatscheew J, Placke T, Streipert B, Rothermel S, Wagner R, Meister P, Cekic-Laskovic I, Winter M. . ‘A Tutorial into Practical Capacity and Mass Balancing of Lithium Ion Batteries.’ Journal of The Electrochemical Society 164, Nr. 12: A2479-A2486. doi: 10.1149/2.0961712jes.
    • Beltrop K, Beuker S, Heckmann A, Winter M, Placke T. . ‘Alternative Electrochemical Energy Storage: Potassium-Based Dual-Graphite Batteries.’ Energy & Environmental Science 10: 2090-2094. doi: 10.1039/C7EE01535F.
    • Zhou D, Jia H, Rana J, Placke T, Scherb T, Kloepsch R, Schumacher G, Winter M, Banhart J. . ‘Local structural changes of nano-crystalline ZnFe2O4 during lithiation and de-lithiation studied by X-ray absorption spectroscopy.’ Electrochimica Acta 246: 699–706. doi: 10.1016/j.electacta.2017.06.098.
    • Reyes Jiménez A, Klöpsch R, Wagner R, Rodehorst U, Kolek M, Nölle R, Winter M, Placke T. . ‘A Step Towards High Energy Silicon-Based Thin Film Lithium Ion Batteries.’ ACS Nano 11, Nr. 5: 4731-4744. doi: 10.1021/acsnano.7b00922.
    • Placke T, Rothermel S, Meister P, Bar A, Winter M, von Wedel W. . „Elektromobilität – Was uns jetzt und künftig antreibt: Batterie-, Brennstoffzellen- und Hybridantrieb.“ BINE Informationsdienst: Themeninfo I/2017.
    • Meister P, Fromm O, Rothermel S, Kasnatscheew J, Winter M, Placke T. . ‘Sodium-Based vs. Lithium-Based Dual-Ion Cells: Electrochemical Study of Anion Intercalation/De-Intercalation into/from Graphite and Metal Plating/Dissolution Behavior.’ Electrochimica Acta 228: 18–27. doi: 10.1016/j.electacta.2017.01.034.
    • Streipert B, Janßen P, Cao X, Kasnatscheew J, Wagner R, Cekic-Laskovic I, Winter M, Placke T. . ‘Evaluation of allylboronic acid pinacol ester as effective shutdown overcharge additive for lithium ion cells.’ Journal of The Electrochemical Society 164, Nr. 2: A168-A172. doi: 10.1149/2.0711702jes.
    • Heckmann A, Krott M, Streipert B, Uhlenbruck S, Winter M, Placke T. . ‘Suppression of Aluminum Current Collector Dissolution by Protective Ceramic Coatings for Better High-Voltage Battery Performance.’ ChemPhysChem 18: 156-163. doi: 10.1002/cphc.201601095.

    • Beltrop K, Meister P, Klein S, Heckmann A, Grünebaum M, Wiemhöfer HD, Winter M, Placke T. . ‘Does Size really Matter? New Insights into the Intercalation Behavior of Anions into a Graphite-Based Positive Electrode for Dual-Ion Batteries.’ Electrochimica Acta 209: 44-55. doi: 10.1016/j.electacta.2016.05.012.
    • Meister P, Jia H, Li J, Klöpsch R, Winter M, Placke T. . ‘Best Practice: Performance and Cost Evaluation of Lithium Ion Battery Active Materials with Special Emphasis on Energy Efficiency.’ Chemistry of Materials 28: 7203-7217. doi: 10.1021/acs.chemmater.6b02895.
    • Meister P, Schmuelling G, Winter M, Placke T. . ‘New Insights into the Uptake/Release of FTFSI- Anions into Graphite by Means of in situ Powder X-Ray Diffraction.’ Electrochemistry Communications 71: 52-55. doi: 10.1016/j.elecom.2016.08.003.
    • Zhou D, Jia H, Rana J, Placke T, Kloepsch R, Schumacher G, Winter M, Banhart J. . ‘Investigation of a porous NiSi2/Si composite anode material used for lithium-ion batteries by X-ray absorption spectroscopy.’ Journal of Power Sources 324: 830-835. doi: 10.1016/j.jpowsour.2016.05.137.
    • Schmuelling G, Oehl N, Fromm O, Knipper M, Kolny-Olesiak J, Plaggenborg T, Parisi J, Winter M, Placke T. . ‘Synthesis and electrochemical characterization of nano-sized Ag4Sn particles as anode material for lithium-ion batteries.’ Electrochimica Acta 196: 597-602. doi: 10.1016/j.electacta.2016.03.019.
    • Jia H, Kloepsch R, He X, Evertz M, Nowak S, Li J, Winter M, Placke T. . ‘Nanostructured ZnFe2O4 as Anode Material for Lithium Ion Batteries: Ionic Liquid-Assisted Synthesis and Performance Evaluation with Special Emphasis on Comparative Metal Dissolution.’ Acta Chimica Slovenica 63, Nr. 3: 470-483. doi: 10.17344/acsi.2016.2243.

    • Oehl N, Schmuelling G, Knipper M, Kloepsch R, Placke T, Kolny-Olesiak J, Plaggenborg T, Winter M, Parisi J. . ‘In situ X-ray diffraction study on the formation of α-Sn in nanocrystalline Sn-based electrodes for lithium-ion batteries.’ CrystEngComm 17: 8500 - 8504. doi: 10.1039/C5CE01841B.
    • Huesker J, Winter M, Placke T. . ‘Dilatometric Study of the Electrochemical Intercalation of Bis(trifluoromethanesulfonyl) imide and Hexafluorophosphate Anions into Carbon-Based Positive Electrodes.’ ECS Transactions 69: 9-21. doi: 10.1149/06922.0009ecst.
    • Vogl US, Lux SF, Das P, Weber A, Placke T, Kostecki R, Winter M. . ‘The mechanism of SEI formation on single crystal Si(100), Si(110) and Si(111) electrodes.’ Journal of the Electrochemical Society 162, Nr. 12: A2281-A2288. doi: 10.1149/2.0361512jes.
    • Schmuelling G, Winter M, Placke T. . ‘Investigating the Mg-Si binary system via combinatorial sputter deposition as high energy density anodes for lithium ion batteries.’ ACS Applied Materials & Interfaces 7, Nr. 36: 20124-20133. doi: 10.1021/acsami.5b05382.
    • Heckmann A, Meister P, Meyer HW, Rohrbach A, Winter M, Placke T. . ‘Synthesis of Spherical Graphite Particles and Their Application as Cathode Material in Dual-Ion Cells.’ ECS Transactions 66, Nr. 11: 1-12. doi: 10.1149/06611.0001ecst.
    • Placke T, Siozios V, Rothermel S, Meister P, Colle C, Winter M. . ‘Assessment of Surface Heterogeneity: A Route to Correlate and Quantify the 1st Cycle Irreversible Capacity Caused by SEI Formation to the Various Surfaces of Graphite Anodes for Lithium Ion Cells.’ Zeitschrift für Physikalische Chemie 229, Nr. 9: 1451-1469. doi: 10.1515/zpch-2015-0584.
    • Placke T, Winter M. . „Batterien für medizinische Anwendungen.“ Zeitschrift für Herz-, Thorax- und Gefäßchirurgie 29, Nr. 2: 139-149. doi: 10.1007/s00398-014-1129-0.
    • Jia H, Stock C, Kloepsch R, He X, Badillo JP, Fromm O, Vortmann B, Winter M, Placke T. . ‘Facile Synthesis and Lithium Storage Properties of a Porous NiSi2/Si/Carbon Composite Anode Material for Lithium-Ion Batteries.’ ACS Applied Materials & Interfaces 7, Nr. 3: 1508-1515. doi: 10.1021/am506486w.
    • Qi X, Blizanac B, DuPasquier A, Lal A, Niehoff P, Placke T, Oljaca M, Li J, Winter M. . ‘Influence of thermal treated carbon black conductive additive on the performance of high voltage spinel Cr-doped LiNi0.5Mn1.5O4 composite cathode electrode.’ Journal of the Electrochemical Society 162, Nr. 3: A339-A343. doi: 10.1149/2.0401503jes.

    • Jia H, Kloepsch R, He X, Badillo JP, Gao P, Fromm O, Placke T, Winter M. . ‘Reversible Storage of Lithium in Three-Dimensional Macro-Porous Germanium.’ Chemistry of Materials 26, Nr. 19: 5683-5688. doi: 10.1021/cm5025124.
    • Qi X, Blizanac B, DuPasquier A, Placke T, Meister P, Oljaca M, Li J, Winter M. . ‘Investigation of PF6- and TFSI- anion intercalation into graphitized carbon blacks and its influence on high voltage lithium ion batteries.’ Physical Chemistry Chemical Physics 16: 25306-25313. doi: 10.1039/C4CP04113E.
    • Rothermel S, Meister P, Schmuelling G, Fromm O, Meyer HW, Nowak S, Winter M, Placke T. . ‘Dual-Graphite Cells based on the Reversible Intercalation of Bis(trifluoromethanesulfonyl) imide Anions from an Ionic Liquid Electrolyte.’ Energy & Environmental Science 7, Nr. 10: 3412-3423. doi: 10.1039/C4EE01873G.
    • Jia H, Kloepsch R, He X, Badillo JP, Winter M, Placke T. . ‘One-Step Synthesis of Novel Mesoporous Three-Dimensional GeO2 and Its Lithium Storage Properties.’ Journal of Material Chemistry A 2, Nr. 41: 17545-17550. doi: 10.1039/C4TA03933E.
    • Schmuelling G, Oehl N, Knipper M, Kolny-Olesiak J, Plaggenborg T, Meyer HW, Placke T, Parisi J, Winter M. . ‘Synthesis and electrochemical performance of surface modified nano-sized core/shell tin particles for lithium ion batteries.’ Nanotechnology 25, Nr. 35: 355401-355411. doi: 10.1088/0957-4484/25/35/355401.
    • Placke T, Schmuelling G, Kloepsch R, Meister P, Fromm O, Hilbig P, Meyer HW, Winter M. . ‘In situ X-ray Diffraction Studies of Cation and Anion Intercalation into Graphitic Carbons for Electrochemical Energy Storage Applications.’ Zeitschrift für Anorganische und Allgemeine Chemie 640, Nr. 10: 1996-2006. doi: 10.1002/zaac.201400181.
    • Meister P, Siozios V, Reiter J, Klamor S, Rothermel S, Fromm O, Meyer HW, Winter M, Placke T. . ‘Dual-Ion Cells based on the Electrochemical Intercalation of Asymmetric Fluorosulfonyl-(trifluoromethanesulfonyl) imide Anions into Graphite.’ Electrochimica Acta 130: 625-633. doi: 10.1016/j.electacta.2014.03.070.
    • Fromm O, Meister P, Qi X, Rothermel S, Huesker J, Meyer HW, Winter M, Placke T. . ‘Study of the Electrochemical Intercalation of Different Anions from non-aqueous Electrolytes into a Graphite-based Cathode.’ ECS Transactions 58, Nr. 14: 55-65. doi: 10.1149/05814.0055ecst.
    • Rothermel S, Meister P, Fromm O, Huesker J, Meyer HW, Winter M, Placke T. . ‘Study of the Electrochemical Behavior of Dual-Graphite Cells using Ionic Liquid-based Electrolytes.’ ECS Transactions 58, Nr. 14: 15-25. doi: 10.1149/05814.0015ecst.

    • Placke T, Rothermel S, Fromm O, Meister P, Lux SF, Huesker J, Meyer HW, Winter M. . ‘Influence of Graphite Characteristics on the Electrochemical Intercalation of Bis(trifluoromethanesulfonyl) imide Anions into a Graphite-based Cathode.’ Journal of the Electrochemical Society 160, Nr. 11: A1979-A1991. doi: 10.1149/2.027311jes.
    • Placke T, Fromm O, Rothermel S, Schmuelling G, Meister P, Meyer HW, Passerini S, Winter M. . ‘Electrochemical Intercalation of Bis(trifluoromethanesulfonyl) imide Anion into Various Graphites for Dual-ion Cells.’ ECS Transactions 50, Nr. 24: 59-68. doi: 10.1149/05024.0059ecst.
    • Lux SF, Terborg L, Hachmöller O, Placke T, Meyer HW, Passerini S, Winter M, Nowak S. . ‘LiTFSI Stability in Water and Its Possible Use in Aqueous Lithium-Ion Batteries: pH Dependency, Electrochemical Window and Temperature Stability.’ Journal of the Electrochemical Society 160, Nr. 10: A1694-A1700. doi: 10.1149/2.039310jes.
    • Schmuelling G, Placke T, Kloepsch R, Fromm O, Meyer HW, Passerini S, Winter M. . ‘X-ray diffraction studies of the electrochemical intercalation of bis(trifluoromethanesulfonyl)imide anions into graphite for dual-ion cells.’ Journal of Power Sources 239: 563-571. doi: 10.1016/j.jpowsour.2013.03.064.

    • Lux SF, Placke T, Engelhardt C, Nowak S, Bieker P, Wirth KE, Passerini S, Winter M, Meyer HW. . ‘Enhanced Electrochemical Performance of Graphite Anodes for Lithium-Ion Batteries by Dry Coating with Hydrophobic Fumed Silica.’ Journal of the Electrochemical Society 159, Nr. 11: A1849-A1855. doi: 10.1149/2.070211jes.
    • Placke T, Fromm O, Lux SF, Bieker P, Rothermel S, Meyer HW, Passerini S, Winter M. . ‘Reversible Intercalation of Bis(trifluoromethanesulfonyl)imide Anions from an Ionic Liquid Electrolyte into Graphite for High Performance Dual-Ion Cells.’ Journal of the Electrochemical Society 159, Nr. 11: A1755-A1765. doi: 10.1149/2.011211jes.
    • Placke T, Bieker P, Lux SF, Fromm O, Meyer HW, Passerini S, Winter M. . ‘Dual-ion cells based on anion intercalation into graphite from ionic liquid-based electrolytes.’ Zeitschrift für Physikalische Chemie 226: 391-407. doi: 10.1524/zpch.2012.0222.
    • Boeckenfeld N, Placke T, Winter M, Passerini S, Balducci A. . ‘The influence of activated carbon on the performance of lithium iron phosphate based electrodes.’ Electrochimica Acta 76: 130-136. doi: 10.1016/j.electacta.2012.04.152.
    • Placke T, Siozios V, Schmitz R, Lux SF, Bieker P, Colle C, Meyer HW, Passerini S, Winter M. . ‘Influence of graphite surface modifications on the ratio of basal plane to “non-basal plane” surface area and on the anode performance in lithium ion batteries.’ Journal of Power Sources 200: 83-91. doi: 10.1016/j.jpowsour.2011.10.085.
  • Vorträge

    • Placke, Tobias (): "Batterietechnologien für die Elektromobilität: Aktueller Stand und Perspektiven". Kolloquium am Institut für Solarenergieforschung Hameln/Emmerthal (ISFH), Emmerthal, .
    • Placke Tobias (): "Jenseits der klassischen Lithium-Ionen-Technologie: Auf Anionen-Interkalation basierende Dual-Ionen Energiespeicher". Batterietag NRW 2017, Aachen, .
    • Placke, Tobias (): "Lithium-Ionen-Technologie und Batteriesysteme der nächsten Generation". Vortragsveranstaltung „Batterietechnik – Stand der Technik und Anwendungserfahrungen“ im Rahmen des AIW-Arbeitskreises, Bocholt, .
    • Placke, Tobias (): "Lithium-Ionen Batterien und Batteriesysteme der nächsten Generation". DPG-Lehrerfortbildung „Energiespeicher“, Bad Honnef, .
    • Placke, Tobias (): "Binder und Leitruße". Batterieforum Deutschland, Berlin, Deutschland, .
    • Placke, Tobias (): "Cation vs. Anion Intercalation into Carbonaceous Materials for Electrochemical Energy Storage". 6th International Conference on Carbon for Energy Storage/Conversion and Environment Protection (CESEP 2015), Poznan (Poland), .
    • Placke, Tobias (): "Facile Synthesis Procedure and Lithium Storage Characteristics of a Porous NiSi2/Si/Carbon Composite Anode Material for Lithium-Ion Batteries". 227th ECS Meeting, Chicago (USA), .
    • Placke, Tobias (): "Carbonaceous Materials for Electrochemical Energy Storage: Cation vs. Anion Intercalation". Symposium: Nanomaterials for Energy Conversion and Storage, NanoEnergie TechnikZentrum, Duisburg (Duisburg), .
    • Placke, Tobias (): "How do the graphite characteristics influence the anion intercalation into a graphite-based cathode in dual-ion cells?" 224th ECS Meeting, The Hilton San Francisco Hotel, San Francisco (USA), .
    • Placke, Tobias (): "Anion intercalation into graphitic carbon from ionic liquid based electrolytes for high performance dual-ion batteries". 222th ECS Meeting - Prime 2012, Honolulu, Hawaii, Hawaii Convention Center and the Hilton Hawaiian Village, .
    • Placke, Tobias (): "Anion Intercalation into graphite from ionic liquid based electrolytes for dual-ion cells". Electrochemistry 2012, Technische Universität München, München (Germany), .
    • Placke, Tobias (): "Influence of surface modifications on graphite surface properties and their impact on the anode performance in lithium-ion batteries". 220th ECS Meeting, Boston MA (USA), .