Prof. Dr. Armido Studer
Professur für Organische Chemie (Prof. Studer)

Corrensstr. 40

 

  • Research Areas

    • Entwicklung von Synthesemethoden in der Organischen Chemie
    • Polymerchemie
    • Chemische Modifikation von Polymeren und Oberflächen
    • Katalyse
    • Nanostrukturierung von Oberflächen

  • Further Affiliation at the University of Münster

  • CV

    Education

    Habilitation, ETH Zürich
    Postdoc, University of Pittsburgh
    Ph.D., ETH Zürich
    Studies of Chemistry, ETH Zürich

    Positions

    Full Professor (W3) of the Institute of Organic Chemistry, Westfälische Wilhelms-Universität Münster
    Full Professor (C4) of the Institute of Organic Chemistry, Westfälische Wilhelms-Universität Münster
    Professor, Philipps Universtät Marburg

    Honors

    ERC Advanced Grant – European Research Council (ERC)
    Election as Member of the European Academy of Sciences – European Academy of Sciences (EURASC)
    Election as member of the Academia Europaea – Academia Europaea
    Election as a Member of the German National Academy of Sciences Leopoldina – German National Academy of Sciences Leopoldina
    Pedler Award – Royal Society of Chemistry
    Election as a full member of the North Rhine-Westphalian Academy of Sciences, Humanities and the Arts – North Rhine-Westphalian Academy of Sciences, Humanities and the Arts
    ERC Advanced Grant – European Research Council (ERC)
    Research prize of the University of Münster – University of Münster
    Solvias Ligand Contest – Solvias AG
    Novartis Young Investigator Award – Novartis

    Appointments

    Karlsruhe Institute of Technology
    University of Münster
    University of Marburg

  • Projects

    In Process
    Finished

  • Publications

    • Haßenberg C, Clausen F, Hoffmann G, Studer A, & Schürenkamp J. (). Investigation of phase II metabolism of 11-hydroxy-Δ-9-tetrahydrocannabinol and metabolite verification by chemical synthesis of 11-hydroxy-Δ-9-tetrahydrocannabinol-glucuronide. International Journal of Legal Medicine, 134(6).
    • Anhäuser L, Klöcker N, Muttach F, Mäsing F, Špaček P, Studer A, & Rentmeister A. (). Eine auf dem Benzophenongerüst basierende Strategie für die Photoschützung der N7‐Position des Guanosins. Angewandte Chemie, 132(8), 3186–3191. doi: 10.1002/ange.201914573.
    • Anhäuser L, Klöcker N, Muttach F, Mäsing F, Špaček P, Studer A, & Rentmeister A. (). A benzophenone‐based photocaging strategy for the N7 position of guanosine. Angewandte Chemie - International Edition, 59(8), 3161–3165. doi: 10.1002/anie.201914573.

    • Barroso Á, Landwerth S, Woerdemann M, Alpmann C, Buscher T, Becker M, Studer A, and, & Denz C. (). Optical assembly of bio-hybrid micro-robots. Biomedical Microdevices, 17. doi: 10.1007/s10544-015-9933-1.
    • Buscher T, Barroso A, Denz C, & Studer A. (). Synthesis and photo-postmodification of zeolite L based polymer brushes. Polymer Chemistry, 6, 4221–4229. doi: 10.1039/c5py00425j.
    • Á. Barroso, K. Dieckmann, C. Alpmann, T. Buscher, A. Studer and C. Denz. (). Nanoassembled dynamic optical waveguides and sensors based on zeolite L nanocontainers. Proceedings of SPIE, Vol. 9379, 93790U.
    • Knor M, Gao HY, Amirjalayer S, Studer A, Gao HJ, Du S, H., & Fuchs H. (). Stereoselective formation of coordination polymers with 1,4-diaminonaphthalene on various Cu substrates . Chemical communications, 51(54), 10854–10857. doi: 10.1039/C5CC03130C.
    • Díaz Arado O, Mönig H, Franke JH, Timmer A, Held PA, Studer A, & Fuchs H. (). On-surface reductive coupling of aldehydes on Au(111). Chemical communications, 51(23), 4887–4890. doi: 10.1039/C4CC09634G.
    • Gao HY, Wagner H, Held PA, Du S, Gao HJ, Studer A, & Fuchs H. (). In-plane Van der Waals interactions of molecular self-assembly monolayer. Applied Physics Letters, 106, 5 pp. doi: 10.1063/1.4907777.
    • Matuschek, D.; Eusterwiemann, S.; Stegemann, L.; Doerenkamp, C.; Wibbeling , B.; Daniliuc, C. G.; Doltsinis, N. L.; Strassert, C. A.; Eckert, H., & Studer A. (). Profluorescent verdazyl radicals – synthesis and characterization. Chemical science, 6, 4712–4716. doi: 10.1039/C5SC00724K.

    • Gao HY, P. Held PA, Knor M, Mück-Lichtenfeld C, Neugebauer J, Studer A, & Fuchs H. (). Decarboxylative Polymerization of 2,6-Naphthalenedicarboxylic Acid at Surfaces. Journal of the American Chemical Society, 136(27), 9658–9663. doi: 10.1021/ja5033875.
    • Gao HY, Zhong D, Mönig H, Wagner H, Held PA, Timmer A, Studer A, & Fuchs H. (). Photochemical Glaser Coupling at Metal Surfaces. Journal of Physical Chemistry C, 118(12), 6272–6277. doi: 10.1021/jp411889e.

    • Gao HY, Franke JH, Wagner H, Zhong D, Held PA, Studer A, & Fuchs H. (). Effect of Metal Surfaces in On-Surface Glaser Coupling. Journal of Physical Chemistry C, 117(36), 18595–18602. doi: 10.1021/jp406858p.
    • Díaz Arado O, Mönig H, Wagner H, Franke JH, Langewisch G, Held P, Studer A, & Fuchs H. (). On-Surface Azide-Alkyne Cycloaddition on Au(111). ACS Nano, 7(10), 8509–8515. doi: 10.1021/nn4022789.
    • Smiatek J, Heuer A, Wagner H, Studer A, Hentschel C, & Chi LF. (). Coat thickness dependent adsorption of hydrophobic molecules at polymer brushes . Journal of Chemical Physics, 138(4), (10pp). doi: 10.1063/1.4789305.
    • Hentschel C, Wagner H, Smiatek J, Heuer A, Fuchs H, Zhang X, Studer A, & Chi LF. (). AFM-based Force Spectroscopy on Polystyrene Brushes: Effect of Brush Thickness on Protein Adsorption. Langmuir, 29(6), 1850–1856. doi: 10.1021/la302212h.
    • Wagner H, Gao HY, Zhong D, Franke J, Studer A, & Fuchs H. (). Glaser Coupling at Metal Surfaces. Angewandte Chemie - International Edition, 52(14), 4024–4028. doi: 10.1002/anie.201208597.

    • Li Y, & Studer A. (). Transition-metal-free trifluoromethylaminoxylation of alkenes. Angewandte Chemie - International Edition, 51(33), 8221–4. doi: 10.1002/anie.201202623.

    • Kirchberg S, Tani S, Ueda K, Yamaguchi J, Studer A, & Itami K. (). Oxidative biaryl coupling of thiophenes and thiazoles with arylboronic acids through palladium catalysis: Otherwise difficult C4-selective C-H arylation enabled by boronic acids. Angewandte Chemie - International Edition, 50(10), 2387–2391.
    • Becker M, De Cola L, & Studer A. (). Site-specific immobilization of proteins at zeolite L crystals by nitroxide exchange reactions. Chemical communications, 47(12), 3392–3394. doi: 10.1039/c0cc05474g.
    • Wertz S, & Studer A. (). Hydroxylamine as a Source for Nitric Oxide in Metal-Free 2,2,6,6-Tetramethylpiperidine N-Oxyl Radical (TEMPO) Catalyzed Aerobic Oxidation of Alcohols. Advanced Synthesis and Catalysis, 353(1), 69–72. doi: 10.1002/adsc.201000703.
    • Li Y, Niehaus JC, Chen Y, Fuchs H, Studer A, Galla HJ, & Chi LF. (). Patterning of proteins into nanostripes on Si-wafer over large areas: A combination of Langmuir-Blodgett patterning and orthogonal surface chemistry. Soft matter (RSC), 7(3), 861–863. doi: 10.1039/c0sm00994f.
    • Möller M, Hentschel C, Chi LF, & Stunder A. (). Aggregation behaviour of peptide-polymer conjugates containing linear peptide backbones and multiple polymer side chains prepared by nitroxide-mediated radical polymerization. Organic and Biomolecular Chemistry, 9(7), 2403–2412. doi: 10.1039/C0OB01047B.

    • Maji MS, Pfeifer T, & Studer A. (). Transition-Metal-Free Synthesis of Conjugated Polymers from Bis-Grignard Reagents by Using TEMPO as Oxidant. Chemistry - A European Journal, 16(20), 5872–5875.
    • Kirchberg S, Frohlich R, & Studer A. (). 1,2,3-Trisubstituted Indanes by Highly Diastereoselective Palladium-Catalyzed Oxyarylation of Indenes with Arylboronic Acids and Nitroxides. Angewandte Chemie - International Edition, 49(38), 6877–6880. doi: 10.1002/anie.201002214.
    • Schulte B, Tsotsalas M, Becker M, Studer A, De, & Cola L. (). Dynamic Microcrystal Assembly by Nitroxide Exchange Reactions. Angewandte Chemie - International Edition, 49(38), 6881–6884. doi: 10.1002/anie.201002851.
    • De Sarkar S, & Studer A. (). NHC-Catalyzed Michael Addition to alpha,beta-Unsaturated Aldehydes by Redox Activation. Angewandte Chemie - International Edition, 49(48), 9266–9269.
    • Uehara K, Wagner CB, Vogler T, Luftmann H, & Studer A. (). Poly(vinyl ketone)s by Controlled Boron Group Transfer Polymerization (BGTP). Angewandte Chemie - International Edition, 49(17), 3073–3076. doi: 10.1002/anie.200907163.
    • Wagner CB, & Studer A. (). Oxidation of Alkylcatecholboranes with Functionalized Nitroxides for Chemical Modification of Cyclohexene, Perallylated Polyglycerol and of Poly(butadiene). European Journal of Organic Chemistry(30), 5782–5786. doi: 10.1002/ejoc.201001043.
    • Niehaus JC, Hirtz M, Brinks MK, Studer A, Fuchs H, & Chi LF. (). Patterning of Functional Compounds by Multicomponent Langmuir-Blodgett Transfer and Subsequent Chemical Modification. Langmuir, 26(19), 15388–15393. doi: 10.1021/la102881r.
    • Dickschat A, & Studer A. (). Radical Addition of Arylboronic Acids to Various Olefins under Oxidative Conditions. Organic letters, 12(18), 3972–3974. doi: 10.1021/ol101818k.
    • Maji MS, Murarka S, & Studer A. (). Transition-Metal-Free Sonogashira-Type Coupling of ortho-Substituted Aryl and Alkynyl Grignard Reagents by Using 2,2,6,6-Tetramethylpiperidine-N-oxyl Radical as an Oxidant. Organic letters, 12(17), 3878–3881. doi: 10.1021/ol1015702.
    • Bruch A, Ambrosius A, Frohlich R, Studer A, Guthrie DB, Zhang HM, & Curran DP. (). Memory of Axial Chirality in Aryl Radical Phosphanylations. Journal of the American Chemical Society, 132(33), 11452–11454. doi: 10.1021/ja105070k.
    • De Sarkar S, & Studer A. (). Oxidative Amidation and Azidation of Aldehydes by NHC Catalysis. Organic letters, 12(9), 1992–1995.
    • Lamas MC, Vaillard SE, Wibbeling B, & Studer A. (). Radical Amination with Trimethylstannylated Benzophenone Imine. Organic letters, 12(9), 2072–2075. doi: 10.1021/ol1005455.
    • Roben C, Studer A, Hemme WL, & Eckert H. (). Immobilization of TEMPO Derivatives in Saponite and Use of These Novel Hybrid Materials as Reusable Catalysts. SYNLETT(7), 1110–1114.
    • Chatterjee I, Jana CK, Steinmetz M, Grimme S, & Studer A. (). Copper-Catalyzed Enantioselective [2+2] Cycloadditions of 2-Nitrosopyridine with Ketenes. Advanced Synthesis and Catalysis, 352(6), 945–948.
    • De Sarkar S, Grimme S, & Studer A. (). NHC catalyzed oxidations of aldehydes to esters: chemoselective acylation of alcohols in presence of amines. Journal of the American Chemical Society, 132(4), 1190–1. doi: 10.1021/ja910540j.
    • Kirchberg S, Fröhlich R, & Studer A. (). Synthese von 1,2,3-trisubstituierten Indanen durch diastereoselektive Palladium-katalysierte Oxyarylierung von Indenen mit Arylboronsäuren und Nitroxiden. Angew. Chem., 122, 7029–7032.

    • Kirchberg S, Fröhlich R, & Studer A. (). Stereoselective palladium-catalyzed carboaminoxylations of indoles with arylboronic acids and TEMPO. Angewandte Chemie - International Edition, 48(23), 4235–8. doi: 10.1002/anie.200901072.
    • Jana CK, Grimme S, & Studer A. (). Enantioselective Nitroso-Diels-Alder Reaction and Its Application for the Synthesis of (-)-Peracetylated Conduramine A-1. Chemistry - A European Journal, 15(36), 9078–9084. doi: 10.1002/chem.200901331.
    • Rosenberger N, Studer A, Takatani N, Nakajima H, & Watanabe Y. (). Azurin-Poly(N-isopropylacrylamide) Conjugates by Site-Directed Mutagenesis and their Thermosensitive Behavior in Electron-Transfer Processes. Angewandte Chemie - International Edition, 48(11), 1946–1949. doi: 10.1002/anie.200804440.
    • Lindner JP, Roben C, Studer A, Stasiak M, Ronge R, Greiner A, & Wendorff HJ. (). Reusable Catalysts Based on Dendrimers Trapped in Poly(p-xylylene) Nanotubes. Angewandte Chemie - International Edition, 48(47), 8874–8877. doi: 10.1002/anie.200903448.
    • Maji MS, & Studer A. (). Transition-Metal-Free Oxidative Homocoupling of Aryl, Alkenyl, and Alkynyl Grignard Reagents with TEMPO. Synthesis(14), 2467–2470.
    • Brinks MK, & Studer A. (). Polymer Brushes by Nitroxide-Mediated Polymerization. Macromolecular Rapid Communications, 30(13), 1043–1057. doi: 10.1002/marc.200800720.
    • Wienhofer IC, Studer A, Rahman MT, Fukuyama T, & Ryu I. (). Microflow Radical Carboaminoxylations with a Novel Alkoxyamine. Organic letters, 11(11), 2457–2460. doi: 10.1021/ol900713d.
    • Hirtz M, Brinks MK, Miele S, Studer A, Fuchs H, & Chi LF. (). Structured Polymer Brushes by AFM Lithography. Small, 5(8), 919–923. doi: 10.1002/smll.200801339.
    • Miele S, Nesvadba P, & Studer A. (). 1-tert-Butyl-3,3,5,5-tetraalkyl-2-piperazinon-4-oxyls: Highly Efficient Nitroxides for Controlled Radical Polymerization. Macromolecules, 42(7), 2419–2427. doi: 10.1021/ma802600x.
    • Pouliot M, Renaud P, Schenk K, Studer A, & Vogler T. (). Oxidation von Catecholborenolaten mit TEMPO. Angewandte Chemie, 121(33), 6153––6156. doi: 10.1002/ange.200902242.
    • Lindner JP, Röben C, Studer A, Stasiak M, Ronge R, Greiner A, & Wendorff HJ. (). In Poly(p-xylylen)-Nanoröhren eingeschlossene Dendrimere als wiederverwendbare Katalysatoren. Angew. Chem., 121, 9035–9038. doi: 10.1002/ange.200903448.
    • Pouliot M, Renaud P, Schenk K, Studer A, & Vogler T. (). Oxidation of Catecholboron Enolates with TEMPO. Angew. Chem. Int. Ed., 48, 6037–6040. doi: 10.1002/ange.200902242.
    • Rosenberger N, Studer A, Takatani N, Nakajima H, & Watanabe Y. (). Azurin-poly(N-Isopropylacrylamide) Conjugates by Site Directed Mutagenesis and their Thermosensitive Behavior in Electron Transfer Processes. Angew. Chem., 121, 1979–1983. doi: 10.1002/ange.200804440.

    • Guin J, De Sarkar S, Grimme S, & Studer A. (). Biomimetic Carbene-Catalyzed Oxidations of Aldehydes Using TEMPO. Angewandte Chemie - International Edition, 47(45), 8727–8730. doi: 10.1002/anie.200802735.
    • Maji MS, Pfeifer T, & Studer A. (). Oxidative Homocoupling of Aryl, Alkenyl, and Alkynyl Grignard Reagents with TEMPO and Dioxygen. Angewandte Chemie - International Edition, 47(49), 9547–9550. doi: 10.1002/anie.200804197.
    • Guin J, Frohlich R, & Studer A. (). Thiol-catalyzed stereoselective transfer hydroamination of olefins with N-aminated dihydropyridines. Angewandte Chemie - International Edition, 47(4), 779–782. doi: 10.1002/anie.200703902.
    • Jana CK, & Studer A. (). Total synthesis of (+)-trans-dihydronarciclasine by a catalytic enantioselective regiodivergent nitroso Diels-Alder reaction. Chemistry - A European Journal, 14(21), 6326–6328. doi: 10.1002/chem.200800903.
    • Schulte B, Frohlich R, & Studer A. (). Atroposelective radical aryl migration reactions from sulfur to carbon. Tetrahedron, 64(52), 11852–11859. doi: 10.1016/j.tet.2008.08.111.
    • Kirchberg S, Vogler T, & Studer A. (). Directed Palladium-Catalyzed Oxidative C-H Arylation of (Hetero)arenes with Arylboronic Acids by Using TEMPO. SYNLETT(18), 2841–2845.
    • Vogler T, & Studer A. (). Rhodium-catalyzed oxidative homocoupling of boronic acids. Advanced Synthesis and Catalysis, 350(13), 1963–1967. doi: 10.1002/adsc.200800300.
    • Roben C, Stasiak M, Janza B, Greiner A, Wendorff JH, & Studer A. (). Immobilization of oligostyrene-prolinol conjugates into polystyrene via electrospinning and applications of these fibers in catalysis. Synthesis(14), 2163–2168.
    • Vogler T, & Studer A. (). Applications of TEMPO in synthesis. Synthesis(13), 1979–1993.
    • Maji MS, Frohlich R, & Studer A. (). Desymmetrization of metallated cyclohexadienes with chiral N-tert-butanesulfinyl imines. Organic letters, 10(9), 1847–1850. doi: 10.1021/ol800478q.
    • Brinks MK, Hirtz M, Chi LF, Fuchs H, & Studer A. (). POLY 94-Structuring of surfaces with polymer brushes through nitroxide mediated polymerization and self-organization. Abstracts of Papers of the American Chemical Society, 235.
    • Umeda R, & Studer A. (). Ag-catalyzed stereoselective cyclohexadienyl transfer: A novel entry into arylphenylmethanols. Organic letters, 10(5), 993–996. doi: 10.1021/ol703080a.
    • Vogler T, & Studer A. (). Oxidative coupling of arylboronic acids with arenes via Rh-catalyzed direct C-H arylation. Organic letters, 10(1), 129–31. doi: 10.1021/ol702659a.
    • Vaillard S, Schulte B, & Studer A. (). Radical-Based Arylation Methods. In Ackermann L (Ed.), Modern Arylation Methods (pp. 475–511). Weinheim: Wiley-VCH Verlag. doi: 10.1002/9783527627325.ch13.
    • Studer A, & Vogler T. (). Nitroxyl Radicals (Nitroxides). In Enders D, Schaumann E (Eds.), Science of Synthesis (pp. 845–853). Stuttgart, New York: Georg Thieme Verlag.
    • Maji MS, Pfeifer T, & Studer A. (). Oxidative Homokupplung von Aryl-, Alkenyl- und Alkinyl-Grignard-Reagentien mit TEMPO und Sauerstoff. Angew. Chem., 120, 9690–9692. doi: 10.1002/ange.200804197.
    • Guin J, De Sarkar S, Grimme S, & Studer A. (). Biomimetic Carbene-Catalyzed Oxidations of Aldehydes by Using TEMPO as an Oxidant. Angew. Chem., 120, 8855–8858. doi: 10.1002/anie.200802735.
    • Studer A, & Guin J. (). (2,6-Dimethoxy-1-methyl-2,5-cyclohexadien-1-yl) (1,1-dimethylethyl)dimethylsilane. In Paquette LA (Ed.), Electronic Encyclopedia of Reagents for Organic Synthesis John Wiley & Sons. doi: 10.1002/047084289X.rn00802.
    • Guin J, Fröhlich R, & Studer A. (). Thiol-Catalyzed Stereoselective Transfer Hydroamination of Olefins with an N-Aminated Dihydropyridine. Angew. Chem., 120, 791–794. doi: 10.1002/anie.200703902.

    • Brinks MK, Hirtz M, Chi LF, Fuchs H, & Studer A. (). Site-selective surface-initiated polymerization by Langmuir-Blodgett lithography. Angewandte Chemie - International Edition, 46(27), 5231–5233. doi: 10.1002/anie.200605020.
    • Vaillard SE, Muck-Lichtenfeld C, Grimme S, & Studer A. (). Homolytic substitution at phosphorus for the synthesis of alkyl and aryl phosphanes. Angewandte Chemie - International Edition, 46(34), 6533–6536. doi: 10.1002/anie.200701650.
    • Jana CK, & Studer A. (). Divergent reactions for racemates: Catalytic, enantioselective, and regiodivergent nitroso diels-alder reactions. Angewandte Chemie - International Edition, 46(34), 6542–6544. doi: 10.1002/anie.200701631.
    • Stasiak M, Studer A, Greiner A, & Wendorff JH. (). Polymer fibers as carriers for homogeneous catalysts. Chemistry - A European Journal, 13(21), 6150–6156. doi: 10.1002/chem.200601555.
    • Molawi K, & Studer A. (). Reversible switching of substrate activity of poly-N-isopropylacrylamide peptide conjugates. Chemical communications(48), 5173–5175. doi: 10.1039/b713083j.
    • Stasiak M, Roben C, Rosenberger N, Schleth F, Studer A, Greiner A, & Wendorff JH. (). Design of polymer nanofiber systems for the immobilization of homogeneous catalysts - Preparation and leaching studies. Polymer, 48(18), 5208–5218. doi: 10.1016/j.polymer.2007.07.006.
    • Umeda R, & Studer A. (). Desymmetrization of 1,4-cyclohexadienyltriisopropoxysilane using copper catalysis. Organic letters, 9(11), 2175–2178. doi: 10.1021/ol070689d.
    • Siegenthaler KO, Schafer A, & Studer A. (). Chemical surface modification via radical C-C bond-forming reactions. Journal of the American Chemical Society, 129(18), 5826. doi: 10.1021/ja0686716.
    • Guin J, Muck-Lichtenfeld C, Grimme S, & Studer A. (). Radical transfer hydroamination with aminated cyclohexadienes using polarity reversal catalysis: Scope and limitations. Journal of the American Chemical Society, 129(14), 4498–4503. doi: 10.1021/ja0692581.
    • Jiang JF, Kurnikov I, Belikova NA, Xiao JB, Zhao Q, Amoscato AA, Braslau R, Studer A, Fink MP, Greenberger JS, Wipf P, & Kagan VE. (). Structural requirements for optimized delivery, inhibition of oxidative stress, and antiapoptotic activity of targeted nitroxides. Journal of Pharmacology and Experimental Therapeutics, 320(3), 1050–1060.
    • Vaillard SE, Mück-Lichtenfeld C, Grimme S, & Studer A. (). Homolytische Substitution am Phosphor zur Synthese von Alkyl- und Arylphosphanen. Angewandte Chemie, 119(34), 6653––6656. doi: 10.1002/ange.200701650.
    • Brinks MK, Hirtz M, Chi LF, Fuchs H, & Studer A. (). Ortsselektive Polymerisationen an Oberflächen durch Langmuir-Blodgett-Lithographie. Angewandte Chemie, 119(27), 5324––5326. doi: 10.1002/ange.200605020.
    • Jana CK, & Studer A. (). Divergente Reaktionen an Racematen: katalytische, enantioselektive und regiodivergente Nitroso-Diels-Alder-Reaktionen. Angew. Chem., 119, 6662–6664. doi: 10.1002/ange.200701631.

    • Chang CC, Siegenthaler KO, & Studer A. (). A new sterically highly hindered 7-membered cyclic nitroxide for the controlled living radical polymerization. Helvetica Chimica Acta, 89(10), 2200–2210. doi: 10.1002/hlca.200690206.
    • Vogler T, & Studer A. (). The effect of additives on TEMPO-mediated alkoxyamine isomerizations: Experiments and simulations. Synthesis(24), 4257–4265.
    • Schulte B, & Studer A. (). Radical carboaminoxylation with subsequent Pd-catalyzed intramolecular allylation for the construction of five- and six-membered carbocycles. Synthesis(13), 2129–2138.
    • Chang CC, & Studer A. (). Acceleration of the styryl-TEMPO-mediated controlled radical styrene polymerization by addition of an efficient alkoxyamine. Macromolecules, 39(12), 4062–4068. doi: 10.1021/ma060068k.
    • Janza B, & Studer A. (). Isonitrile trapping reactions under thermolysis of alkoxyamines for the synthesis of quinolines. Organic letters, 8(9), 1875–1878. doi: 10.1021/ol0604421.
    • Siegenthaler KO, & Studer A. (). Nitroxide-mediated radical polymerization/increase of steric demand in nitroxides. How much is too much? Macromolecules, 39(4), 1347–1352. doi: 10.1021/ma0513463.

    • Studer A, & Schulte T. (). Nitroxide-mediated radical processes. Chemical Record, 5(1), 27–35. doi: 10.1002/tcr.20033.
    • Studer A, & Schleth F. (). Desymmetrization and diastereotopic group selection in 1,4-cyclohexadienes. SYNLETT(20), 3033–3041. doi: 10.1055/s-2005-921899.
    • Knoop CA, & Studer A. (). A new method for the generation of titanium(III) complexes and its application in pinacol coupling reactions. Advanced Synthesis and Catalysis, 347(11-13), 1542–1546. doi: 10.1002/adsc.200505180.
    • Walton JC, & Studer A. (). Evolution of functional cyclohexadiene-based synthetic reagents: The importance of becoming aromatic. Accounts of Chemical Research, 38(10), 794–802. doi: 10.1021/ar050089j.
    • Janza B, & Studer A. (). Stereoselective cyclization reactions of IBX-generated alkoxyamidyl radicals. Journal of Organic Chemistry, 70(17), 6991–6994.
    • Schulte T, Siegenthaler KO, Luftmann H, Letzel M, & Studer A. (). Nitroxide-mediated polymerization of N-isopropylacrylamide: Electrospray ionization mass spectrometry, matrix-assisted laser desorption ionization mass spectrometry, and multiple-angle laser light scattering studies on nitroxide-terminated poly-N-isopropylacrylamides. Macromolecules, 38(16), 6833–6840. doi: 10.1021/ma050343n.
    • Uenoyama Y, Tsukida M, Doi T, Ryu I, & Studer A. (). CO-trapping reaction under thermolysis of alkoxyamines: Application to the synthesis of 3,4-cyclopenta-1-tetralones. Organic letters, 7(14), 2985–2988. doi: 10.1021/ol050951n.
    • Herrera AJ, & Studer A. (). 1,3-dithiane-derived alkoxyamines as one-carbon radical precursors. Synthesis(9), 1389–1396.
    • Molawi K, Schulte T, Siegenthaler KO, Wetter C, & Studer A. (). Tin-free radical alkoxyamine addition and isomerization reactions by using the persistent radical effect: Variation of the alkoxyamine structure. Chemistry - A European Journal, 11(8), 2335–2350. doi: 10.1002/chem.200400936.
    • Kemper J, & Studer A. (). New Reagents for the Generation of N-Centered Radicals - Hydroamination of Norbornene. Angew. Chem., Int. Ed., 44, 4914–4917.
    • Kemper J, & Studer A. (). New Reagents for the Generation of N-Centered Radicals - Hydroamination of Norbornene. Angew. Chem., 117, 4993–4995.

    • Schleth F, & Studer A. (). Desymmetrization of metalated cyclohexadienes and application to the synthesis of nephrosteranic acid. Angewandte Chemie - International Edition, 43(3), 313–315. doi: 10.1002/anie.200352254.
    • Studer A. (). Tin-free radical chemistry using the persistent radical effect: alkoxyamine isomerization, addition reactions and polymerizations. Chemical Society Reviews, 33(5), 267–273. doi: 10.1039/b307652k.
    • Teichert A, Jantos K, Harms K, & Studer A. (). One-pot homolytic aromatic substitutions/HWE olefinations under microwave conditions for the formation of a small oxindole library. Organic letters, 6(20), 3477–3480. doi: 10.1021/ol048759t.
    • Blum A, Hess W, & Studer A. (). Stereocontrolled formation of vinylsilanes via homolytic substitution at silicon. Synthesis(13), 2226–2235.
    • Schleth F, Vogler T, Harms K, & Studer A. (). Stereoselective synthesis of (+)-nephrosteranic acid, (+)-trans-cognac lactone, and (+)-trans-whisky lactone using a chiral cyclohexadienyl Ti compound. Chemistry - A European Journal, 10(17), 4171–4185. doi: 10.1002/chem.200400237.
    • Schulte T, Knoop CA, & Studer A. (). Nitroxide-mediated living free-radical polymerization of styrene: A systematic study of the variation of the alkoxyamine concentration. Journal of Polymer Science Part A: Polymer Chemistry, 42(13), 3342–3351. doi: 10.1002/pola.20177.
    • Wetter C, Gierlich J, Knoop CA, Müller C, Schulte T, & Studer A. (). Steric and electronic effects in cyclic alkoxyamines - Synthesis and applications as regulators for controlled/living radical polymerization. Chemistry - A European Journal, 10(5), 1156–1166. doi: 10.1002/chem.200305427.
    • Studer A, Harms K, Knoop C, Müller C, & Schulte T. (). New sterically hindered nitroxides for the living free radical polymerization: X-ray structure of an alpha-H-bearing nitroxide. Macromolecules, 37(1), 27–34. doi: 10.1021/ma035128q.
    • Wetter C, & Studer A. (). Microwave-assisted Free Radical Chemistry using the Persistent Radical Effect. Chem. Commun, 174–175. doi: 10.1002/chin.200419134.

    • Knoop CA, & Studer A. (). Hydroxy- and silyloxy-substituted TEMPO derivatives for the living free-radical polymerization of styrene and n-butyl acrylate: synthesis, kinetics, and mechanistic studies. Journal of the American Chemical Society, 125(52), 33. doi: 10.1021/ja037948o.
    • Studer A, Amrein S, Matsubara H, Schiesser CH, Doi T, Kawamura T, Fukuyama T, & Ryu I. (). Two types of intramolecular homolytic substitution reactions at group XIV atoms: unusual radical 1,4-Sn shifts from Si to C and carbonylative S(H)i reaction at Si. Chemical communications(10), 1190–1191. doi: 10.1039/b301755a.
    • Wetter C, Jantos K, Woithe K, & Studer A. (). Intermolecular radical addition and addition/cyclization reactions of alkoxyamines onto nonactivated alkenes. Organic letters, 5(16), 2899–2902. doi: 10.1021/ol034994k.
    • Studer A, Amrein S, Schleth F, Schulte T, & Walton JC. (). Silylated cyclohexadienes as new radical chain reducing reagents: Preparative and mechanistic aspects. Journal of the American Chemical Society, 125(19), 5726–5733. doi: 10.1021/ja0341743.
    • Schulte T, & Studer A. (). New seven- and eight-membered cyclic alkoxyamines for the living free radical polymerization. Macromolecules, 36(9), 3078–3084. doi: 10.1021/ma025806t.

    • Amrein S, & Studer A. (). Intramolecular radical hydrosilylation - the first radical 5-endo-dig cyclisation. Chemical communications(15), 1592–1593. doi: 10.1039/b204879e.
    • Amrein S, & Studer A. (). Silylated cyclohexadienes in radical chain hydrosilylations. Helvetica Chimica Acta, 85(10), 3559–3574. doi: 10.1002/1522-2675(200210)85:103559::AID-HLCA3559>3.0.CO;2-6.
    • Janza B, & Studer A. (). Stereoselective electrophilic cyclisation of O-homoallyl hydroxylamine derivatives. Synthesis(14), 2117–2123.
    • Bossart M, Fassler R, Schoenberger J, & Studer A. (). Stereoselective radical aryl migration reactions from sulfur to carbon. European Journal of Organic Chemistry(16), 2742–2757. doi: 10.1002/1099-0690(200208)2002:162742::AID-EJOC2742>3.0.CO;2-R.
    • Studer A, & Amrein S. (). Tin hydride substitutes in reductive radical chain reactions. Synthesis(7), 835–849. doi: 10.1055/s-2002-28507.

    • Studer A, & Bossart M. (). Radical aryl migration reactions. Tetrahedron, 57(48), 9649–9667. doi: 10.1016/S0040-4020(01)00990-5.
    • Amrein S, Timmermann A, & Studer A. (). Radical transfer hydrosilylation/cyclization using silylated cyclohexadienes. Organic letters, 3(15), 2357–2360. doi: 10.1021/ol016160c.
    • Studer A. (). Radical Chemistry. Nachrichten aus der Chemie, 49(3), 300–305.
    • Studer A. (). The persistent radical effect in organic synthesis. Chemistry - A European Journal, 7(6), 1159–64.
    • Marque S, Fischer H, Baier E, & Studer A. (). Factors influencing the C-O bond homolysis of alkoxyamines: Effects of H-bonding and polar substituents. Journal of Organic Chemistry, 66(4), 1146–1156. doi: 10.1021/jo001190z.
    • Studer A, & Bossart M. (). Aromatic Substitution. In Renaud P, Sibi M (Eds.), Radicals in Organic Synthesis (pp. 62–80). Weinheim: Wiley-VCH Verlag. doi: 10.1002/9783527618293.ch29.

    • Studer A, & Amrein S. (). Silylated cyclohexadienes: New alternatives to tributyltin hydride in free radical chemistry. Angewandte Chemie - International Edition, 39(17), 3080–3082.
    • Studer A. (). Tin-free radical cyclization reactions using the persistent radical effect. Angewandte Chemie - International Edition, 39(6), 1108. doi: 10.1002/(SICI)1521-3773(20000317)39:61108::AID-ANIE1108>3.0.CO;2-A.
    • Amrein S, Bossart M, Vasella T, & Studer A. (). Stereoselective radical aryl migration from silicon to carbon. Journal of Organic Chemistry, 65(14), 4281–4288.
    • Studer A, Bossart M, & Vasella T. (). Synthesis of biaryls by intramolecular radical aryl migration from silicon to carbon. Organic letters, 2(7), 985–988. doi: 10.1021/ol005661f.
    • Studer A. (). Tin-Free Radical Cyclization Reactions Using the Persistent Radical Effect. Angew. Chem., 112, 1157–1160.

  • Supervised Theses

    Doctoral Studies

    Barroso-Pena, AlvaroLight-induced manipulation and assembly of functional complex micropatricles
    Zhu, HangziCrowdsourcing in the Front End of Innovation - Empirical Evidence from the Chemical Industry
    Li, YongFunctional biointerfaces and their application in the study of cell/substrate interaction
    Chatterjee, IndranilCatalytic Enantioselective Cycloaddition Reactions of Nitrosopyridine with Different Acceptors
    Bruch, Achim Hannes JoHomolytische Substitution am Phosphor: Anwendungen in der stereoselektiven Synthese und Aufbau Phosphor-haltiger n-konjugierter Materialien
    Lamas, Marie-CélineNitrogen and Phosphorus Atoms as Acceptors in Radical Chemistry
    Kirchberg, SylviaPalladium-katalysierte C-H-Arylierungen von(Hetero)-Arenen mit Arylboronsäuren und TEMPO
    Molawi, KianNeuartige Synthese von Polymer-Peptid-Konjugaten und deren Einsatz in schaltbaren Chymotrypsin-katalysierten Amidspaltungen
    Möller, MichaelUmsetzung von tertiären Amiden zu 2,2-dialkylierten Aminen durch Organocerverbindungen und Synthese von Peptid-Polymer-Konjugaten mittels Nitroxid-vermittelter Polymerisation
    Niehaus, Julia ChristinaStrukturierung und chemische Modifizierung von Silizium-oberflächen sowie Synthese von Protein-Polymer Konjugaten
    Lindner, Jean-Pierre BerkanDer Einsatz hochverzweigter, makromolekularer Strukturen zur Synthese von Bio-Hybrid-Materialien und Immobilisierung homogener Katalysatoren
    De Sarkar, SumanDerivatization of Aldehydes by NHC Catalyzed Redox Activation
    Wagner, Christine BeatrixCatecholborderivate in intermolekularen radikalischen Additionsreaktionen
    Wienhöfer, Inga ClaudiaRadikalische Carboaminoxylierung mit einem neuen Alkoxyamin Copolymerisation und massenspektrometrische Sequenzanalyse von Oligomeren Erste Studien zur Herstellung von SiO2-Partikeln und deren Einsatz in der heterogenen kooperativen Katalyse
    Hormes, Anna-ChristinaNeue Ansätze zur Totalsynthese von Prostaglandinen basierend auf der Desymmetrisierung von 1,4-Cyclohexadien
    Röben, CarenNeuartige Immobilisierungsstrategien für Organokatalysatoren
    Maji, Modhu SudanDesymmetrization of Metallated Cyclohexadienes and Transition Metal Free Oxidative Homocoupling of Grignard Reagents
    Miele, SaskiaSynthese, Strukturierung und Anwendung von Polymerbürsten
    Schulte, BirteAtropselektive radikalische [1.5]-Aryltransferreaktionen - Modifikation und Organisation von neuartigen Zeolith L-Hybridmaterialien
    Rosenberger, NadineSynthese und Anwendung neuer Protein-Polymer-Biohybride
    Jana, Chandan KumarStereoselective Nitroso Diels-Alder Reaction and Its Application in Natural Product Synthesis
    Brinks, Marion KristinaPolymerisationen und Nitroxidaustauschreaktionen an strukturierten Oberflächen
    Vogler, ThomasNeue Anwendungen von TEMPO in der organischen Synthese
    Guin, JoyramIntermolecular Radical Hydroamination
    Siegenthaler, Kai OliverAlkoxyamine - Von der kontrollierten radikalischen Polymerisation zur organisch-chemischen Modifizierung von Materialien
    Bartelt, Michael RobertChiralitätstransfer in der Radikalchemie - Untersuchungen zu stereoselektiven radikalischen Cyan- und Aryltransfer-Reaktionen
    Knoop, Christoph AlexanderSelektive Radikalerzeugung durch Bindungshomolyse Von der lebenden radikalischen Polymerisation zu niedervalenten Titankomplexen
    Janza, BirgitNeue Methoden in der radikalischen Heterocyclensynthese
    Schleth, FlorianMetallierte Cyclohexadiene in Desymmetrisierungsreaktionen und deren Anwendungen in der organischen Synthese

    Postdoctoral Study

    Über die asymmetrische Halogenierung von C-C-Mehrfachbindungen