Olegross  

Olga Ekkert

group of Prof. G. Erker

Corrensstr. 40
48149 Münster
Lab. No.: 3.33
phone: +49 251 83-36555
email: olga.ekkert[at]uni-muenster.de
member of the group since: 11/2009  
research interest:
P/B"Frustrated Lewis-pairs" and P-C bond activation
   
diploma thesis:  
"Synthese sterisch gehinderter Phosphan-Boran-Addukte mittels 1,1-Organoborierung", Münster, 06/2010
   
oral presentations:  
"P-C Bond Activation: 1,1-Carboboration Reaction of Phosphinyl Substituted Acetylenes", 03/2011, Annual Erker- UCSB Symposium, University of California, Santa Barbara, USA.
   
poster presentations:  
"P-C Bond Activation", 05/2011, SFB 858 symposium, WWU Münster, Germany.
publications:
1) "Reaction of Strongly Electrophilic Alkenylboranes with Phosphinoalkynes: Rare Examples of Intermolecular 1,1- Alkenylboration Reactions", O. Ekkert, O. Tuschewitzki, C. G. Daniliuc, G. Kehr, G. Erker, Chem. Commun. 2013, submitted.
2) "Remarkable Coordination Behavior of Alkyl Isocyanides Toward Unsaturated Vicinal Frustrated P/B Lewis Pairs", O. Ekkert, G. González Miera, T. Wiegand, H. Eckert, B. Schirmer, J. L. Petersen, C. G. Daniliuc, R. Fröhlich, S. Grimme, G. Kehr, Gerhard Erker, Chem. Sci. 2013, 4, 2657.
3) "New Insights into Frustrated Lewis Pairs: Structural Investigations of Intramolecular Phosphane–Borane Adducts by Using Modern Solid-State NMR Techniques and DFT Calculations", T. Wiegand, H. Eckert, O. Ekkert, R. Fröhlich, G. Kehr, G. Erker, S. Grimme, J. Am. Chem. Soc. 2012, 134, 4236-4239.
4) "Phosphirenium borate zwitterion: formation in the 1,1 carboboration reaction of phosphinylalkynes", O. Ekkert, G. Kehr, R. Fröhlich, G. Erker, Chem. Commun. 2012, 47, 10482-10484.
5) "P-C Bond Activation Chemistry: Evidence for 1,1-Carboboration Reactions Proceeding with Phosphorus-Carbon Bond Cleavage", O. Ekkert, G. Kehr, R. Fröhlich, G. Erker, J. Am. Chem. Soc. 2011, 133, 4610-4616.
miscellaneous:
05/2012 - 09/2012: Research stay in the group of Prof. Douglas W. Stephan, University of Toronto, Canada.
10/2011: Research stay in the group of Prof. Andreas Pfaltz, University of Basel, Switzerland.
   

Imprint | © 2013 Organic Chemistry
Research Group Prof. Erker
Corrensstr. 40
· D-48149 Münster
Tel.: +49 251 83-33221 · Fax: +49 251 83-36503
E-Mail: erker@uni-muenster.de